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2018

Journal Article

Phenylnitrene radical cation rearrangements

Bégué, Didier, Dargelos, Alain and Wentrup, Curt (2018). Phenylnitrene radical cation rearrangements. Journal of Physical Chemistry A: Molecules, Spectroscopy, Kinetics, Environment and General Theory, 122 (43) acs.jpca.8b08480, 8490-8496. doi: 10.1021/acs.jpca.8b08480

Phenylnitrene radical cation rearrangements

2018

Journal Article

Triplet states of tetrazoles, nitrenes, and carbenes from matrix photolysis of tetrazoles, and phenylcyanamide as a source of phenylnitrene

Abe, Manabu, Bégué, Didier, Silva, Hugo Santos, Dargelos, Alain and Wentrup, Curt (2018). Triplet states of tetrazoles, nitrenes, and carbenes from matrix photolysis of tetrazoles, and phenylcyanamide as a source of phenylnitrene. Journal of Physical Chemistry A, 122 (37), 7276-7283. doi: 10.1021/acs.jpca.8b06960

Triplet states of tetrazoles, nitrenes, and carbenes from matrix photolysis of tetrazoles, and phenylcyanamide as a source of phenylnitrene

2018

Journal Article

Carbene und Nitrene: aktuelle Entwicklungen in der Grundlagenchemie

Wentrup, Curt (2018). Carbene und Nitrene: aktuelle Entwicklungen in der Grundlagenchemie. Angewandte Chemie, 130 (36), 11680-11693. doi: 10.1002/ange.201804863

Carbene und Nitrene: aktuelle Entwicklungen in der Grundlagenchemie

2018

Journal Article

Trimethylsilylnitrene and its surprising rearrangement to N-(Dimethylsilyl)methanimine via silaziridine and silaazomethine ylide

Wentrup, Curt, Lüerssen, Holger, Silva, Hugo Santos, Dargelos, Alain and Bégué, Didier (2018). Trimethylsilylnitrene and its surprising rearrangement to N-(Dimethylsilyl)methanimine via silaziridine and silaazomethine ylide. Chemistry: A European Journal, 24 (54), 14547-14553. doi: 10.1002/chem.201803245

Trimethylsilylnitrene and its surprising rearrangement to N-(Dimethylsilyl)methanimine via silaziridine and silaazomethine ylide

2018

Journal Article

Direct observation of an imidoylnitrene: photochemical formation of PhC(=NMe)−N and Me−N from 1-methyl-5-phenyltetrazole

Abe, Manabu, Bégué, Didier, Santos-Silva, Hugo, Dargelos, Alain and Wentrup, Curt (2018). Direct observation of an imidoylnitrene: photochemical formation of PhC(=NMe)−N and Me−N from 1-methyl-5-phenyltetrazole. Angewandte Chemie, 130 (12), 3266-3270. doi: 10.1002/ange.201712689

Direct observation of an imidoylnitrene: photochemical formation of PhC(=NMe)−N and Me−N from 1-methyl-5-phenyltetrazole

2018

Journal Article

First Direct Observation of an Imidoylnitrene. Photochemical Formation of PhC(=NMe)-N and Me-N from 1-Methyl-5-phenyltetrazole

Wentrup, Curt, Abe, Manabu, Bégué, Didier, Santos-Silva, Hugo and Dargelos, Alain (2018). First Direct Observation of an Imidoylnitrene. Photochemical Formation of PhC(=NMe)-N and Me-N from 1-Methyl-5-phenyltetrazole. Angewandte Chemie (International ed. in English), 57 (12), 3212-3216. doi: 10.1002/anie.201712689

First Direct Observation of an Imidoylnitrene. Photochemical Formation of PhC(=NMe)-N and Me-N from 1-Methyl-5-phenyltetrazole

2018

Journal Article

From dipivaloylketene to tetraoxaadamantanes

Kollenz, Gert and Wentrup, Curt (2018). From dipivaloylketene to tetraoxaadamantanes. Beilstein Journal of Organic Chemistry, 14 (1), 1-10. doi: 10.3762/bjoc.14.1

From dipivaloylketene to tetraoxaadamantanes

2018

Journal Article

RACI and academy of science awards 2017-18

Wentrup, Curt (2018). RACI and academy of science awards 2017-18. Australian Journal of Chemistry, 71 (10), 721-722. doi: 10.1071/CHv71n10_FO

RACI and academy of science awards 2017-18

2017

Journal Article

Pyrolysis of benzotriazoles. 1-Acyl- and 1-alkoxycarbonylbenzotriazoles: Hetero-Wolff rearrangement to N-acyl- and N-alkoxycarbonyl-fulvenimines and free radical routes to cyanocyclopentadienes

Wentrup, Curt, Freiermuth, Beat and Aylward, Nigel (2017). Pyrolysis of benzotriazoles. 1-Acyl- and 1-alkoxycarbonylbenzotriazoles: Hetero-Wolff rearrangement to N-acyl- and N-alkoxycarbonyl-fulvenimines and free radical routes to cyanocyclopentadienes. Journal of Analytical and Applied Pyrolysis, 128, 187-195. doi: 10.1016/j.jaap.2017.10.011

Pyrolysis of benzotriazoles. 1-Acyl- and 1-alkoxycarbonylbenzotriazoles: Hetero-Wolff rearrangement to N-acyl- and N-alkoxycarbonyl-fulvenimines and free radical routes to cyanocyclopentadienes

2017

Journal Article

Flash-Vakuumpyrolyse - Techniken und Reaktionen

Wentrup, Curt (2017). Flash-Vakuumpyrolyse - Techniken und Reaktionen. Angewandte Chemie, 129 (47), 15002-15031. doi: 10.1002/ange.201705118

Flash-Vakuumpyrolyse - Techniken und Reaktionen

2017

Journal Article

Celebrating RACI and Academy of Science Awards

Wentrup, Curt (2017). Celebrating RACI and Academy of Science Awards. Australian Journal of Chemistry, 70 (11), 1159-1160. doi: 10.1071/CHv70n11_FO

Celebrating RACI and Academy of Science Awards

2017

Journal Article

Imidoylnitrenes R'C(═NR)-N, Nitrile Imines, 1H-Diazirines, and Carbodiimides: Interconversions and Rearrangements, Structures, and Energies at DFT and CASPT2 Levels of Theory

Bégué, Didier, Santos-Silva, Hugo, Dargelos, Alain and Wentrup, Curt (2017). Imidoylnitrenes R'C(═NR)-N, Nitrile Imines, 1H-Diazirines, and Carbodiimides: Interconversions and Rearrangements, Structures, and Energies at DFT and CASPT2 Levels of Theory. The journal of physical chemistry. A, 121 (43), 8227-8235. doi: 10.1021/acs.jpca.7b08445

Imidoylnitrenes R'C(═NR)-N, Nitrile Imines, 1H-Diazirines, and Carbodiimides: Interconversions and Rearrangements, Structures, and Energies at DFT and CASPT2 Levels of Theory

2017

Journal Article

Iminocyclohexadienylidenes: carbenes or diradicals? the hetero-Wolff rearrangement of benzotriazoles to cyanocyclopentadienes and 1H-benzo[b]azirines

Begue, Didier, Santos-Silva, Hugo, Dargelos, Alain and Wentrup, Curt (2017). Iminocyclohexadienylidenes: carbenes or diradicals? the hetero-Wolff rearrangement of benzotriazoles to cyanocyclopentadienes and 1H-benzo[b]azirines. Journal of Physical Chemistry A, 121 (32), 5998-6003. doi: 10.1021/acs.jpca.7b05325

Iminocyclohexadienylidenes: carbenes or diradicals? the hetero-Wolff rearrangement of benzotriazoles to cyanocyclopentadienes and 1H-benzo[b]azirines

2017

Journal Article

Pyrolysis of hydrazine derivatives and related compounds with N-N single bonds

Gaber, Abdel-Aal M. and Wentrup, Curt (2017). Pyrolysis of hydrazine derivatives and related compounds with N-N single bonds. Journal of Analytical and Applied Pyrolysis, 125, 258-278. doi: 10.1016/j.jaap.2017.03.016

Pyrolysis of hydrazine derivatives and related compounds with N-N single bonds

2017

Journal Article

New, simple and efficient method for the synthesis of imidazo-azines by flash vacuum thermolysis of tert-butylimines of pyrimidine-2-, pyrazine-2-, quinoline-2-, quinoxaline-2- and isoquinoline-1-carbaldehydes

Justyna, Katarzyna , Chrostowska, Anna , Leśniak, Stanisław , Darrigan, Clovis , Baylère, Patrick , Khayar, Saïd and Wentrup, Curt (2017). New, simple and efficient method for the synthesis of imidazo-azines by flash vacuum thermolysis of tert-butylimines of pyrimidine-2-, pyrazine-2-, quinoline-2-, quinoxaline-2- and isoquinoline-1-carbaldehydes. Journal of Analytical and Applied Pyrolysis, 125, 335-346. doi: 10.1016/j.jaap.2017.02.028

New, simple and efficient method for the synthesis of imidazo-azines by flash vacuum thermolysis of tert-butylimines of pyrimidine-2-, pyrazine-2-, quinoline-2-, quinoxaline-2- and isoquinoline-1-carbaldehydes

2016

Journal Article

A thermally populated, perpendicularly twisted alkene triplet diradical

Wentrup, Curt, Regimbald-Krnel, Michèle J., Müller, Dennis and Comba, Peter (2016). A thermally populated, perpendicularly twisted alkene triplet diradical. Angewandte Chemie, 128 (47), 14820-14825. doi: 10.1002/ange.201607415

A thermally populated, perpendicularly twisted alkene triplet diradical

2016

Journal Article

A Thermally Populated, Perpendicularly Twisted Alkene Triplet Diradical

Wentrup, Curt, Regimbald-Krnel, Michele J., Müller, Dennis and Comba, Peter (2016). A Thermally Populated, Perpendicularly Twisted Alkene Triplet Diradical. Angewandte Chemie, 55 (47), 14600-14605. doi: 10.1002/anie.201607415

A Thermally Populated, Perpendicularly Twisted Alkene Triplet Diradical

2016

Journal Article

Twisted C=C double bonds with very low rotational barriers in dioxanediones and isoxazolones determined by low-temperature dynamic NMR spectroscopy and computational chemistry

Wentrup, Curt, Koch, Rainer and Kleinpeter, Erich (2016). Twisted C=C double bonds with very low rotational barriers in dioxanediones and isoxazolones determined by low-temperature dynamic NMR spectroscopy and computational chemistry. European Journal of Organic Chemistry, 2016 (29), 4985-4990. doi: 10.1002/ejoc.201600931

Twisted C=C double bonds with very low rotational barriers in dioxanediones and isoxazolones determined by low-temperature dynamic NMR spectroscopy and computational chemistry

2016

Journal Article

Azulene–naphthalene-type rearrangements in Benz[a]azulene and Cyclohepta[b]indole

Wentrup, Curt and Becker, Jürgen (2016). Azulene–naphthalene-type rearrangements in Benz[a]azulene and Cyclohepta[b]indole. Chemistry - A European Journal, 22 (39), 13835-13839. doi: 10.1002/chem.201603389

Azulene–naphthalene-type rearrangements in Benz[a]azulene and Cyclohepta[b]indole

2016

Journal Article

Nitrene–nitrene rearrangement under thermal, photochemical, and electron-impact conditions: the 2-azidopyridines/tetrazolo[1,5-a]pyridines

Wentrup, Curt, Braybrook, Carl, Liu, Shanshan, Tzschucke, C. Christoph, Dargelos, Alain and Bégué, Didier (2016). Nitrene–nitrene rearrangement under thermal, photochemical, and electron-impact conditions: the 2-azidopyridines/tetrazolo[1,5-a]pyridines. European Journal of Organic Chemistry, 2016 (24), 4200-4206. doi: 10.1002/ejoc.201600655

Nitrene–nitrene rearrangement under thermal, photochemical, and electron-impact conditions: the 2-azidopyridines/tetrazolo[1,5-a]pyridines