
Overview
Background
I completed my undergraduate studies in Chemistry, History and German at the University of Sydney graduating with a University Medal, before completing a Bachelor of Laws and PhD in Chemistry at the same institution. I made extensive contributions towards university life during that time which was recognised by the award of the Convocation Medal. During the same period, I spent time on the board of the Australian Youth Orchestra and a regional Credit Union in NSW. I then spent two years on a prestigious Marie Curie Fellowship at the University of Cambridge where I was also a Director of Studies at Emmanuel College. I returned to Australia to join The University of Queensland in 2012. I became an ARC Future Fellow in 2014. I was awarded a 2015 Queensland Young Tall Poppy Award and the 2018 Malcolm McIntosh Prize for Physical Scientist of the Year. I have authored more than 200 publications including 4 book chapters, which have received over 7000 citations. I have an h-index of >42.
Availability
- Professor Jack Clegg is:
- Available for supervision
- Media expert
Qualifications
- Bachelor (Honours), University of Sydney
- Doctor of Philosophy, University of Sydney
- Bachelor of Law, University of Sydney
Research impacts
My research is in the field of metallo-supramolecular chemistry and bridges the traditional fields of organic and inorganic chemistry. I use a self-assembly approach and by combing the inherent physical and chemical properties of metals with organic (ligand) components I can design and synthesis new materials with central cavities that are capable of selectively binding smaller molecules. The resulting nanoscale structures can be either discrete or polymeric (framework) in nature. The potential applications for these compounds are diverse including drug delivery, catalysis, sequestration, separation and gas storage. Many of my compounds are characterised by X-ray diffraction methods.
Works
Search Professor Jack Clegg’s works on UQ eSpace
2022
Journal Article
Controlling the complexity and interconversion mechanisms in self‐assembled [Fe 2 L 3 ] 4+ helicates and [Fe 4 L 6 ] 8+ cages
Siddique, Rashid G., Arachchige, Kasun S. A., AL‐Fayaad, Hydar A., Thoburn, John D., McMurtrie, John C. and Clegg, Jack K. (2022). Controlling the complexity and interconversion mechanisms in self‐assembled [Fe 2 L 3 ] 4+ helicates and [Fe 4 L 6 ] 8+ cages. Angewandte Chemie, 134 (7). doi: 10.1002/ange.202115555
2022
Journal Article
Controlling the complexity and interconversion mechanisms in self‐assembled [Fe2 L3 ]4+ helicates and [Fe4 L6 ]8+ cages
Siddique, Rashid G., Arachchige, Kasun S. A., AL‐Fayaad, Hydar A., Thoburn, John D., McMurtrie, John C. and Clegg, Jack K. (2022). Controlling the complexity and interconversion mechanisms in self‐assembled [Fe2 L3 ]4+ helicates and [Fe4 L6 ]8+ cages. Angewandte Chemie International Edition, 61 (7) e202115555, 1-7. doi: 10.1002/anie.202115555
2022
Journal Article
Selective separation of planar and non-planar hydrocarbons using an aqueous Pd<sub>6</sub> interlocked cage
Chakraborty, Debsena, Saha, Rupak, Clegg, Jack K. and Mukherjee, Partha Sarathi (2022). Selective separation of planar and non-planar hydrocarbons using an aqueous Pd6 interlocked cage. Chemical Science, 13 (40), 11764-11771. doi: 10.1039/d2sc04660a
2022
Journal Article
Sterics and metal-ion radius control the self-assembly of [M<sub>2</sub>L<sub>3</sub>] helicates
Siddique, Rashid G., Arachchige, Kasun S. A., AL-Fayaad, Hydar A., McMurtrie, John C. and Clegg, Jack K. (2022). Sterics and metal-ion radius control the self-assembly of [M2L3] helicates. Dalton Transactions, 51 (33), 12704-12708. doi: 10.1039/d2dt02241a
2021
Journal Article
Expanding the repertoire of spongian-16-One derivatives in Australian nudibranchs of the genus Goniobranchus and evaluation of their anatomical distribution
Forster, Louise C., Clegg, Jack K., Cheney, Karen L. and Garson, Mary J. (2021). Expanding the repertoire of spongian-16-One derivatives in Australian nudibranchs of the genus Goniobranchus and evaluation of their anatomical distribution. Marine Drugs, 19 (12) 680, 1-14. doi: 10.3390/md19120680
2021
Journal Article
Oxygenated sesquiterpenes from the Indo-Pacific nudibranch Ardeadoris rubroannulata: structure revision of pu’ulenal
Narbutas, Patrick T., Pierens, Gregory K., Clegg, Jack K. and Garson, Mary J. (2021). Oxygenated sesquiterpenes from the Indo-Pacific nudibranch Ardeadoris rubroannulata: structure revision of pu’ulenal. Natural Product Communications, 16 (10), 1934578X2110550. doi: 10.1177/1934578x211055025
2021
Journal Article
Lewis acid activation of Weiss’ reagents ([PhI(Pyr)2]2+) with boranes and isolation of [PhI(4-DMAP)]2+
Bakro, Aseel, Sharp-Bucknall, Lachlan, Poynder, Tiffany B., Clegg, Jack K., Wilson, David J. D. and Dutton, Jason L. (2021). Lewis acid activation of Weiss’ reagents ([PhI(Pyr)2]2+) with boranes and isolation of [PhI(4-DMAP)]2+. Chemical Communications, 57 (91), 12163-12166. doi: 10.1039/d1cc04725f
2021
Journal Article
The mechanism of bending in co-crystals of caffeine and 4-chloro-3-nitrobenzoic acid
Thompson, Amy J., Price, Jason R., McMurtrie, John C. and Clegg, Jack K. (2021). The mechanism of bending in co-crystals of caffeine and 4-chloro-3-nitrobenzoic acid. Nature Communications, 12 (1) 5983, 5983. doi: 10.1038/s41467-021-26204-z
2021
Journal Article
Elastically flexible molecular crystals
Thompson, Amy J., Chamorro Orué, Analia I., Nair, Akshay Jayamohanan, Price, Jason R., McMurtrie, John and Clegg, Jack K. (2021). Elastically flexible molecular crystals. Chemical Society Reviews, 50 (21), 11725-11740. doi: 10.1039/d1cs00469g
2021
Journal Article
PhICl2 is activated by chloride ions
Tania, Poynder, Tiffany B., Kaur, Aishvaryadeep, Barwise, Lachlan, Houston, Sevan D., Nair, Akshay J., Clegg, Jack K., Wilson, David J. D. and Dutton, Jason L. (2021). PhICl2 is activated by chloride ions. Dalton Transactions, 50 (34), 11986-11991. doi: 10.1039/d1dt02565a
2021
Journal Article
Charge neutral [Cu2L2] and [Pd2L2] metallocycles: self-assembly, aggregation, and catalysis
Kołodziejski, Michał, Brock, Aidan J., Kurpik, Gracjan, Walczak, Anna, Li, Feng, Clegg, Jack K. and Stefankiewicz, Artur R. (2021). Charge neutral [Cu2L2] and [Pd2L2] metallocycles: self-assembly, aggregation, and catalysis. Inorganic Chemistry, 60 (13) acs.inorgchem.1c00967, 9673-9679. doi: 10.1021/acs.inorgchem.1c00967
2021
Journal Article
Supramolecular modulation of spin crossover in an Fe(II) dinuclear triple helicate
Craze, Alexander R., Zenno, Hikaru, Pfrunder, Michael C., McMurtrie, John C., Hayami, Shinya, Clegg, Jack K. and Li, Feng (2021). Supramolecular modulation of spin crossover in an Fe(II) dinuclear triple helicate. Inorganic Chemistry, 60 (9), 6731-6738. doi: 10.1021/acs.inorgchem.1c00553
2021
Journal Article
Hierarchical spin-crossover cooperativity in hybrid 1D chains of FeII-1,2,4-triazole trimers linked by [Au(CN)2]− bridges
Ezzedinloo, Lida, Zenere, Katrina A., Xie, Zixi, Ahmed, Manan, Scottwell, SynØve, Bhadbhade, Mohan, Brand, Helen E. A., Clegg, Jack K., Hua, Carol, Sciortino, Natasha F., Parker, Lachlan C., Powell, Benjamin J., Kepert, Cameron J. and Neville, Suzanne M. (2021). Hierarchical spin-crossover cooperativity in hybrid 1D chains of FeII-1,2,4-triazole trimers linked by [Au(CN)2]− bridges. Chemistry - A European Journal, 27 (16), 5136-5141. doi: 10.1002/chem.202100358
2021
Journal Article
Crystallization of CsPbBr3 single crystals in water for X-ray detection
Peng, Jiali, Xia, Chelsea Q., Xu, Yalun, Li, Ruiming, Cui, Lihao, Clegg, Jack K., Herz, Laura M., Johnston, Michael B. and Lin, Qianqian (2021). Crystallization of CsPbBr3 single crystals in water for X-ray detection. Nature Communications, 12 (1) 1531, 1-10. doi: 10.1038/s41467-021-21805-0
2021
Journal Article
Three distinct spin-crossover pathways in halogen-appended 2D Hofmann frameworks
Brennan, Ashley T., Zenere, Katrina A., Kepert, Cameron J., Clegg, Jack K. and Neville, Suzanne M. (2021). Three distinct spin-crossover pathways in halogen-appended 2D Hofmann frameworks. Inorganic Chemistry, 60 (6) acs.inorgchem.0c03651, 3871-3878. doi: 10.1021/acs.inorgchem.0c03651
2021
Journal Article
Dual-supramolecular contacts induce extreme Hofmann framework distortion and multi-stepped spin-crossover
Ahmed, Manan, Brand, Helen E. A., Peterson, Vanessa K., Clegg, Jack K., Kepert, Cameron J., Price, Jason R., Powell, Benjamin J. and Neville, Suzanne M. (2021). Dual-supramolecular contacts induce extreme Hofmann framework distortion and multi-stepped spin-crossover. Dalton Transactions, 50 (4), 1434-1442. doi: 10.1039/d0dt04007j
2021
Journal Article
Determining the mechanisms of deformation in flexible crystals using micro-focus X-ray diffraction
Thompson, Amy J., Worthy, Anna, Grosjean, Arnaud, Price, Jason R., McMurtrie, John C. and Clegg, Jack K. (2021). Determining the mechanisms of deformation in flexible crystals using micro-focus X-ray diffraction. CrystEngComm, 23 (34), 5731-5737. doi: 10.1039/d1ce00401h
2021
Journal Article
Dinuclear triple stranded phenyl-spaced 1,3-bis-β-diketonato lanthanide(iii) complexes: synthesis, structures and spectroscopy
Brock, A. J., Etchells, I. M., Moore, E. G. and Clegg, J. K. (2021). Dinuclear triple stranded phenyl-spaced 1,3-bis-β-diketonato lanthanide(iii) complexes: synthesis, structures and spectroscopy. Dalton Transactions, 50 (14), 4874-4879. doi: 10.1039/d1dt00393c
2021
Journal Article
Comment on “Trimorphs of 4-bromophenyl 4-bromobenzoate. Elastic, brittle, plastic” by S. Saha and G. R. Desiraju, Chem. Commun., 2018, 54, 6348
Whittaker, Jacob J., Brock, Aidan J., Grosjean, Arnaud, Pfrunder, Michael C., McMurtrie, John C. and Clegg, Jack K. (2021). Comment on “Trimorphs of 4-bromophenyl 4-bromobenzoate. Elastic, brittle, plastic” by S. Saha and G. R. Desiraju, Chem. Commun., 2018, 54, 6348. Chemical Communications, 57 (40), 4974-4975. doi: 10.1039/d0cc07668f
2021
Journal Article
The kinetics and mechanism of interconversion within a system of [Fe2L3]4+ helicates and [Fe4L6]8+ cages
Siddique, Rashid G., Arachchige, Kasun S. A., AL-Fayaad, Hydar A., Brock, Aidan J., Micallef, Aaron S., Luis, Ena T., Thoburn, John D., McMurtrie, John C. and Clegg, Jack K. (2021). The kinetics and mechanism of interconversion within a system of [Fe2L3]4+ helicates and [Fe4L6]8+ cages. Chemical Communications, 57 (40), 4918-4921. doi: 10.1039/d1cc01583d
Funding
Current funding
Past funding
Supervision
Availability
- Professor Jack Clegg is:
- Available for supervision
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Supervision history
Current supervision
-
Doctor Philosophy
New switchable metallo-supramolecular materials for separation and storage
Principal Advisor
Other advisors: Associate Professor Evan Moore
-
Doctor Philosophy
New Metallo-supramolecular Architectures
Principal Advisor
Other advisors: Associate Professor Evan Moore
-
Doctor Philosophy
Flexible Molecular Crystals: Single Crystals that Bend, Stretch and Twist
Principal Advisor
-
Doctor Philosophy
Flexible Molecular Crystals: Single Crystals that Bend, Stretch and Twist
Principal Advisor
-
Doctor Philosophy
Tuning the flexibility of crystals through intermolecular interactions
Principal Advisor
-
Doctor Philosophy
New Metallo-supramolecular Architectures
Principal Advisor
Other advisors: Associate Professor Evan Moore
-
Doctor Philosophy
Tuning the flexibility of crystals through intermolecular interactions
Principal Advisor
-
Doctor Philosophy
Rational Design of Carboxylate Supramolecular Complexes for Pyrolysis Bio-oil Valorization
Principal Advisor
-
Doctor Philosophy
Anion-induced transformations in metallosupramolecular cages incorporating 3,3 ' -bipyridine-cored ligands
Principal Advisor
Other advisors: Associate Professor Evan Moore
-
Doctor Philosophy
New flexible piezoelectric crystals
Principal Advisor
-
Doctor Philosophy
Understanding the photoexcited states within molecular crystals
Principal Advisor
Other advisors: Associate Professor Evan Moore
-
Doctor Philosophy
Rational Design of Carboxylate Supramolecular Complexes for Pyrolysis Bio-oil Valorization
Principal Advisor
-
Doctor Philosophy
Tuning the flexibility of crystals through intermolecular interactions
Principal Advisor
-
Doctor Philosophy
Investigation into pore functionalisation of metal organic frameworks
Principal Advisor
-
Doctor Philosophy
The role of spin-orbit coupling in spin crossover materials
Associate Advisor
Other advisors: Professor Ben Powell
Completed supervision
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2023
Doctor Philosophy
1,001 Crystal Structures: Understanding the Mechanisms of Deformation in Elastically Flexible Crystals Using Automated Analysis
Principal Advisor
-
2023
Doctor Philosophy
Stimuli-responsive behaviour in metallo-supramolecular materials
Principal Advisor
Other advisors: Associate Professor Evan Moore
-
2020
Doctor Philosophy
The Design and Self-assembly of Allosterically Regulated Metal-organic Cages
Principal Advisor
Other advisors: Associate Professor Evan Moore
-
2020
Doctor Philosophy
Design and Synthesis of acetylene-tagged and "clicked" chiral discrete and polymeric metallosupramolecular architectures
Principal Advisor
-
2019
Doctor Philosophy
Metallo-Supramolecular Materials for Chiral Discrimination and Enantiomeric Separation
Principal Advisor
Other advisors: Associate Professor Evan Moore
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2017
Doctor Philosophy
Synthesis of new metal-organic frameworks via a hierarchical self-assembly approach
Principal Advisor
Other advisors: Professor Lisbeth Grondahl
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2023
Doctor Philosophy
Earth Abundant Photocatalysis and Supramolecular Assemblies
Associate Advisor
Other advisors: Associate Professor Evan Moore
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2023
Doctor Philosophy
Investigating Energy Transfer in Homo- and Heterometallic Lanthanide Helicates
Associate Advisor
Other advisors: Associate Professor Evan Moore
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2022
Doctor Philosophy
Incorporation of Ir(III) cyclometalated motifs into heterometallic supramolecular assemblies
Associate Advisor
Other advisors: Associate Professor Evan Moore
-
2022
Doctor Philosophy
Re-examining catalytic chain transfer for the synthesis of specialty polymers
Associate Advisor
Other advisors: Professor Kristofer Thurecht, Associate Professor Idriss Blakey, Professor Andrew Whittaker
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2021
Doctor Philosophy
Sensitised Luminescence of Heterometallic d-f Lanthanide Complexes
Associate Advisor
Other advisors: Associate Professor Evan Moore
-
2021
Doctor Philosophy
Exploring the LnIII-to-LnIII Energy Transfer Properties of Lanthanoid Dimer Complexes
Associate Advisor
Other advisors: Associate Professor Evan Moore
Media
Enquiries
Contact Professor Jack Clegg directly for media enquiries about:
- Chemistry
- Crystals
- Physical Sciences
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