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Emeritus Professor Curt Wentrup
Emeritus Professor

Curt Wentrup

Email: 
Phone: 
+61 7 336 53817

Overview

Background

Educated at the University of Copenhagen, Denmark, and the Australian National University, Canberra. Career at the Université de Lausanne, Switzerland, and the Universität Marburg, Germany. Professor and Chair of Organic Chemistry and Head of the Organic Chemistry Section, The University of Queensland from 1985. Emeritus professor from 2008. Chair of the National Committee for Chemistry of the Australian Academy of Science 2009-2014. Editor-in-Chief, Australian Journal of Chemistry 2008-15. Editor, Journal of Analytical and Applied Pyrolysis (Elsevier, IF 3.65) 2016-. Visiting Professor Université de Pau, France, 2011-19; Visiting Professor University of Kuwait 2014-18; Visiting Professor / Special Appointed Professor Hiroshima University 2014-18. Fellow of the Australian Academy of Science. Centenary Medal of the Australian Commonwealth 2003 for research in organic and physical chemistry. David Craig Medal of the Academy of Science 2014 for research in chemistry. JSPS Fellowship (Japan) 2014. Honorary doctorate, University of Pau, France, 2014. A.J. Birch Medal of the Royal Australian Chemical Institute (RACI) for ecellence in research in organic chemistry, 2014. Leighton Medal of the RACI 2018.

Research on Unusual Molecules and Reactive Intermediates: Synthesis and Reaction Mechanism. Heterocyclic chemistry. Pyrolysis reactions. Photochemistry

Research in the Wentrup group is concerned with the discovery of novel types of molecules with new and unusual bonding patterns. Such molecules are mostly highly reactive, and special methods are required both for their generation and for their detection. The group has developed these methods over many years and acquired world-class equipment for these purposes, including flash vacuum thermolysis apparatus, cryostats for matrix isolation of reaction products at cryogenic temperatures (down to 7 K), matrix and solution photochemistry equipment, infrared, UV and mass spectrometers, as well as modern computational facilities.

This research has resulted in the synthesis and characterization of many novel compounds, including extended cumulenes of the types RN=C=C=C=X, which themselves are used in the synthesis of many novel types of molecules, some of them of potential pharmaceutical interest (quinolone antibiotics; diazepines).

The research group has a world reputation in the field of carbene and nitrene chemistry, involving reactive intermediates with sextet carbon or nitrogen. These species are also very useful in synthesis, for example in the preparation of diazepines and diazepinones, a family of pharmaceutically interesting compounds. Numerous mechanistic studies and synthetic applications of ketenes have been carried out in our group.

Active collaborations are ongoing with scientists in Australia (UQ and CSIRO), China (Suzhou), France (Pau), Germany (Oldenburg), Japan (Hiroshima), Spain (Donostia - San Sebastian), and Portugal (Coimbra).

Availability

Emeritus Professor Curt Wentrup is:
Not available for supervision
Media expert

Qualifications

  • Doctor of Philosophy, Australian National University
  • Doctor of Philosophy of Science (Advanced), University of Copenhagen
  • Doctoral Diploma, unknown
  • Australian Academy of Science, Australian Academy of Science
  • Royal Australian Chemical Institute, Royal Australian Chemical Institute

Research interests

  • Organic, physical, and historical chemistry

    Reactive intermediates, pyrolysis, photochemistry, reaction mechanism. History of science.

Research impacts

This research leads to the development of new pharmaceuticals, e.g. new antibiotics (quinolones and naphthyridones) and new leads towards a treatment for scizophrenia (diazepine molecules).

Chemical industry has used our pyrolysis techniques in specialized manufacturing processes.

Our analytical/spectroscopic work has led to cooperation with chemical and energy firms and agencies involved in forensic science, and our research has generated collaborations with many scientists at universities in Australia, Austria, Belgium, China, Denmark, France, Germany, Hungary, Japan, Portugal, Singapore, Switzerland, and USA.

Works

Search Professor Curt Wentrup’s works on UQ eSpace

432 works between 1966 and 2024

21 - 40 of 432 works

2023

Journal Article

Reactive intermediates and unusual molecules at Heron Island

Wentrup, Curt (2023). Reactive intermediates and unusual molecules at Heron Island. Australian Journal of Chemistry, 76 (1), I-II. doi: 10.1071/CHv76n1_FO

Reactive intermediates and unusual molecules at Heron Island

2022

Journal Article

Azulene–naphthalene, naphthalene–naphthalene, and azulene–azulene rearrangements

Mirzaei, M. Saeed, Taherpour, Avat Arman and Wentrup, Curt (2022). Azulene–naphthalene, naphthalene–naphthalene, and azulene–azulene rearrangements. The Journal of Organic Chemistry, 87 (17), 11503-11518. doi: 10.1021/acs.joc.2c01099

Azulene–naphthalene, naphthalene–naphthalene, and azulene–azulene rearrangements

2022

Journal Article

Thermal rearrangement of azulenes to naphthalenes: a deeper insight into the mechanisms

Mirzaei, M. Saeed, Taherpour, Avat Arman and Wentrup, Curt (2022). Thermal rearrangement of azulenes to naphthalenes: a deeper insight into the mechanisms. The Journal of Organic Chemistry, 87 (5) acs.joc.1c02948, 3296-3310. doi: 10.1021/acs.joc.1c02948

Thermal rearrangement of azulenes to naphthalenes: a deeper insight into the mechanisms

2021

Journal Article

Celebrating RACI and Academy of Science Awards 2020–2021

Wentrup, Curt (2021). Celebrating RACI and Academy of Science Awards 2020–2021. Australian Journal of Chemistry, 74 (11), 747-748. doi: 10.1071/chv74n11_fo

Celebrating RACI and Academy of Science Awards 2020–2021

2021

Journal Article

Benzotriazoles and triazoloquinones: rearrangements to carbazoles, benzazirines, azepinediones, and fulvenimines

Marchais, Jérémy, Bégué, Didier, Dargelos, Alain and Wentrup, Curt (2021). Benzotriazoles and triazoloquinones: rearrangements to carbazoles, benzazirines, azepinediones, and fulvenimines. The Journal of Organic Chemistry, 86 (23) acs.joc.1c02131, 16992-17001. doi: 10.1021/acs.joc.1c02131

Benzotriazoles and triazoloquinones: rearrangements to carbazoles, benzazirines, azepinediones, and fulvenimines

2021

Journal Article

When a “Dimroth Rearrangement” is not a Dimroth rearrangement

Wentrup, Curt, Mirzaei, M. Saeed, Kvaskoff, David and Taherpour, Avat Arman (2021). When a “Dimroth Rearrangement” is not a Dimroth rearrangement. The Journal of Organic Chemistry, 86 (12), 8286-8294. doi: 10.1021/acs.joc.1c00730

When a “Dimroth Rearrangement” is not a Dimroth rearrangement

2020

Journal Article

Bunsen the geochemist: Icelandic volcanism, geyser theory, and gas, rock and mineral analyses

Wentrup, Curt (2020). Bunsen the geochemist: Icelandic volcanism, geyser theory, and gas, rock and mineral analyses. Angewandte Chemie International Edition, 59 (3) anie.202008727, 2-18. doi: 10.1002/anie.202008727

Bunsen the geochemist: Icelandic volcanism, geyser theory, and gas, rock and mineral analyses

2020

Journal Article

Ørsted and Bunsen: voltaic batteries, electric arcs, electromagnetism, and electrolysis

Wentrup, Curt (2020). Ørsted and Bunsen: voltaic batteries, electric arcs, electromagnetism, and electrolysis. Angewandte Chemie International Edition, 59 (43) anie.202006761, 18850-18857. doi: 10.1002/anie.202006761

Ørsted and Bunsen: voltaic batteries, electric arcs, electromagnetism, and electrolysis

2020

Journal Article

Rearrangements of aromatic nitrile oxides and nitrile ylides: potential ring expansion to cycloheptatetraene derivatives mimicking arylcarbenes

Marchais, Jérémy, Bégué, Didier, Dargelos, Alain and Wentrup, Curt (2020). Rearrangements of aromatic nitrile oxides and nitrile ylides: potential ring expansion to cycloheptatetraene derivatives mimicking arylcarbenes. Chemistry: A European Journal, 26 (67) chem.202003782, 15700-15707. doi: 10.1002/chem.202003782

Rearrangements of aromatic nitrile oxides and nitrile ylides: potential ring expansion to cycloheptatetraene derivatives mimicking arylcarbenes

2020

Journal Article

Aryl nitrile imines and diazo compounds. Formation of indazole, pyridine N-imine, and 2-pyridyldiazomethane from tetrazoles

Begue, Didier, Dargelos, Alain and Wentrup, Curt (2020). Aryl nitrile imines and diazo compounds. Formation of indazole, pyridine N-imine, and 2-pyridyldiazomethane from tetrazoles. Journal of Organic Chemistry, 85 (12), 7952-7958. doi: 10.1021/acs.joc.0c00773

Aryl nitrile imines and diazo compounds. Formation of indazole, pyridine N-imine, and 2-pyridyldiazomethane from tetrazoles

2020

Journal Article

Zeise, Liebig, Jensen, Hückel, Dewar und die Olefin‐π‐Komplex‐Bindung

Wentrup, Curt (2020). Zeise, Liebig, Jensen, Hückel, Dewar und die Olefin‐π‐Komplex‐Bindung. Angewandte Chemie, 132 (22), 8408-8419. doi: 10.1002/ange.201913840

Zeise, Liebig, Jensen, Hückel, Dewar und die Olefin‐π‐Komplex‐Bindung

2019

Journal Article

Photolysis and pyrolysis of phenyltetrazoles: Formation of phenylcarbodiimide,N-phenylnitrile imine, phenylnitrene, indazole, and fulvenallene

Zhao, Xiaofang, Liu, Qian, Feng, Ruijuan, Zeng, Xiaoqing and Wentrup, Curt (2019). Photolysis and pyrolysis of phenyltetrazoles: Formation of phenylcarbodiimide,N-phenylnitrile imine, phenylnitrene, indazole, and fulvenallene. European Journal of Organic Chemistry, 2019 (41), 6945-6950. doi: 10.1002/ejoc.201901271

Photolysis and pyrolysis of phenyltetrazoles: Formation of phenylcarbodiimide,N-phenylnitrile imine, phenylnitrene, indazole, and fulvenallene

2019

Journal Article

Knallgold und Knallsilber

Wentrup, Curt (2019). Knallgold und Knallsilber. Angewandte Chemie, 131 (42) ange.201906356, 14942-14951. doi: 10.1002/ange.201906356

Knallgold und Knallsilber

2019

Journal Article

Transforming triplet vinylnitrene into triplet alkylnitrene at cryogenic temperatures

Shields, Dylan J., Sarkar, Sujan K., Sriyarathne, H. Dushanee M., Brown, Jocelyn R., Wentrup, Curt, Abe, Manabu and Gudmundsdottir, Anna D. (2019). Transforming triplet vinylnitrene into triplet alkylnitrene at cryogenic temperatures. Organic Letters, 21 (18) acs.orglett.9b01950, 7194-7198. doi: 10.1021/acs.orglett.9b01950

Transforming triplet vinylnitrene into triplet alkylnitrene at cryogenic temperatures

2019

Journal Article

Rearrangements of nitrile imines: ring expansion of benzonitrile imines to cycloheptatetraenes and ring closure to 3-phenyl-3H-diazirines

Bégué, Didier, Dargelos, Alain and Wentrup, Curt (2019). Rearrangements of nitrile imines: ring expansion of benzonitrile imines to cycloheptatetraenes and ring closure to 3-phenyl-3H-diazirines. The Journal of Organic Chemistry, 84 (13) acs.joc.9b01183, 8668-8673. doi: 10.1021/acs.joc.9b01183

Rearrangements of nitrile imines: ring expansion of benzonitrile imines to cycloheptatetraenes and ring closure to 3-phenyl-3H-diazirines

2019

Journal Article

Spectroscopic characterization of nicotinoyl and isonicotinoyl nitrenes and the photointerconversion of 4-pyridylnitrene with diazacycloheptatetraene

Liu, Qian, Qin, Yuanyuan, Lu, Yan, Wentrup, Curt and Zeng, Xiaoqing (2019). Spectroscopic characterization of nicotinoyl and isonicotinoyl nitrenes and the photointerconversion of 4-pyridylnitrene with diazacycloheptatetraene. The Journal of Physical Chemistry A, 123 (17) acs.jpca.9b01680, 3793-3801. doi: 10.1021/acs.jpca.9b01680

Spectroscopic characterization of nicotinoyl and isonicotinoyl nitrenes and the photointerconversion of 4-pyridylnitrene with diazacycloheptatetraene

2019

Journal Article

Heteroarylcarbene–arylnitrene radical cation isomerizations

Bégué, Didier, Dargelos, Alain, Braybrook, Carl and Wentrup, Curt (2019). Heteroarylcarbene–arylnitrene radical cation isomerizations. The Journal of Physical Chemistry A, 123 (10) acs.jpca.9b00309, 2073-2079. doi: 10.1021/acs.jpca.9b00309

Heteroarylcarbene–arylnitrene radical cation isomerizations

2019

Journal Article

Phenylnitrene radical cation and its isomers from tetrazoles, nitrile imines, indazole, and benzimidazole

Bégué, Didier, Dargelos, Alain, Braybrook, Carl and Wentrup, Curt (2019). Phenylnitrene radical cation and its isomers from tetrazoles, nitrile imines, indazole, and benzimidazole. The Journal of Physical Chemistry A, 123 (7) acs.jpca.8b11858, 1410-1422. doi: 10.1021/acs.jpca.8b11858

Phenylnitrene radical cation and its isomers from tetrazoles, nitrile imines, indazole, and benzimidazole

2019

Journal Article

Nitrogen-and Sulfur-Containing Energetic Compounds. 64 Years of Fascinating Chemistry

Wentrup, Curt (2019). Nitrogen-and Sulfur-Containing Energetic Compounds. 64 Years of Fascinating Chemistry. Australian Journal of Chemistry, 72 (8), 585-594. doi: 10.1071/CH19263

Nitrogen-and Sulfur-Containing Energetic Compounds. 64 Years of Fascinating Chemistry

2019

Journal Article

RACI Awards 2017-19

Wentrup, Curt (2019). RACI Awards 2017-19. Australian Journal of Chemistry, 72 (8), 561-562. doi: 10.1071/CHv72n8_FO

RACI Awards 2017-19

Funding

Past funding

  • 2012 - 2013
    Heron Island Conference on reactive intermediate and unusual molecules
    Ian Potter Foundation
    Open grant
  • 2010
    UQ Travel Awards Category 1, Fabian Borget
    UQ Travel Grants Scheme
    Open grant
  • 2007 - 2009
    Reactive intermediates and microwave-assisted organic reactions
    ARC Discovery Projects
    Open grant
  • 2007
    Research in pre-biotic chemistry
    UQ Travel Grants Scheme
    Open grant
  • 2004
    Research conference grant for Prof Josef Michl, University of Colorado, Boulder, to attend Heron Island Conference on reactive intermediates and unusual molecules, 17-23 July 2004
    Potter Foundation
    Open grant
  • 2004 - 2006
    New mechanisms and methods in carbene and nitrene chemistry
    ARC Discovery Projects
    Open grant
  • 2003 - 2005
    Bimolecular chemistry at very low temperature
    ARC Linkage International
    Open grant
  • 2002
    To expand work on cryogenic matrix isolation research.
    UQ Travel Grants Scheme
    Open grant
  • 2001 - 2003
    Chemistry of Iminopropadienones and Related Compounds.
    ARC Australian Research Council (Large grants)
    Open grant
  • 2000
    Novel approaches to heterocyclic synthesis.
    ARC Australian Research Council (Small grants)
    Open grant
  • 1997
    Brisbane Advanced Mass Spectrometry Facility
    Research Infrastructure (Equip & Fac) Program
    Open grant
  • 1997
    Synthesis of 1,3-diazepines
    ARC Australian Research Council (Small grants)
    Open grant
  • 1996 - 1997
    International Network in Advanced Techniques of Applied Molecular Science
    Quality Funds Round 3
    Open grant
  • 1996
    Pulsed pyrolysis
    ARC Australian Research Council (Small grants)
    Open grant

Supervision

Availability

Emeritus Professor Curt Wentrup is:
Not available for supervision

Supervision history

Completed supervision

  • 2006

    Doctor Philosophy

    SYNTHESES AND REACTIONS OF IMINOPROPADIENONES, SYDNONES AND OXAZINONES

    Principal Advisor

    Other advisors: Professor Craig Williams

  • 2002

    Doctor Philosophy

    HETEROCYCLIC SYNTHESIS BASED ON IMINOPROPADIENONES

    Principal Advisor

  • 2002

    Doctor Philosophy

    SYNTHESIS AND CHARACTERISATION OF 1,3- and 1,4- DIAZEPINES AND DERIVATIVES

    Principal Advisor

  • Doctor Philosophy

    NITRENES REARRANGEMENTS: FORMATION OF REACTIVE INTERMEDIATES AND UNUSUAL MOLECULES

    Principal Advisor

    Other advisors: Professor Craig Williams

Media

Enquiries

Contact Emeritus Professor Curt Wentrup directly for media enquiries about:

  • Organic reaction mechanisms
  • Photochemistry
  • Pyrolysis
  • Reactive intermediates

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