
Overview
Background
Educated at the University of Copenhagen, Denmark, and the Australian National University, Canberra. Career at the Université de Lausanne, Switzerland, and the Universität Marburg, Germany. Professor and Chair of Organic Chemistry and Head of the Organic Chemistry Section, The University of Queensland from 1985. Emeritus professor from 2008. Chair of the National Committee for Chemistry of the Australian Academy of Science 2009-2014. Editor-in-Chief, Australian Journal of Chemistry 2008-15. Editor, Journal of Analytical and Applied Pyrolysis (Elsevier, IF 3.65) 2016-. Visiting Professor Université de Pau, France, 2011-19; Visiting Professor University of Kuwait 2014-18; Visiting Professor / Special Appointed Professor Hiroshima University 2014-18. Fellow of the Australian Academy of Science. Centenary Medal of the Australian Commonwealth 2003 for research in organic and physical chemistry. David Craig Medal of the Academy of Science 2014 for research in chemistry. JSPS Fellowship (Japan) 2014. Honorary doctorate, University of Pau, France, 2014. A.J. Birch Medal of the Royal Australian Chemical Institute (RACI) for ecellence in research in organic chemistry, 2014. Leighton Medal of the RACI 2018.
Research on Unusual Molecules and Reactive Intermediates: Synthesis and Reaction Mechanism. Heterocyclic chemistry. Pyrolysis reactions. Photochemistry
Research in the Wentrup group is concerned with the discovery of novel types of molecules with new and unusual bonding patterns. Such molecules are mostly highly reactive, and special methods are required both for their generation and for their detection. The group has developed these methods over many years and acquired world-class equipment for these purposes, including flash vacuum thermolysis apparatus, cryostats for matrix isolation of reaction products at cryogenic temperatures (down to 7 K), matrix and solution photochemistry equipment, infrared, UV and mass spectrometers, as well as modern computational facilities.
This research has resulted in the synthesis and characterization of many novel compounds, including extended cumulenes of the types RN=C=C=C=X, which themselves are used in the synthesis of many novel types of molecules, some of them of potential pharmaceutical interest (quinolone antibiotics; diazepines).
The research group has a world reputation in the field of carbene and nitrene chemistry, involving reactive intermediates with sextet carbon or nitrogen. These species are also very useful in synthesis, for example in the preparation of diazepines and diazepinones, a family of pharmaceutically interesting compounds. Numerous mechanistic studies and synthetic applications of ketenes have been carried out in our group.
Active collaborations are ongoing with scientists in Australia (UQ and CSIRO), China (Suzhou), France (Pau), Germany (Oldenburg), Japan (Hiroshima), Spain (Donostia - San Sebastian), and Portugal (Coimbra).
Availability
- Emeritus Professor Curt Wentrup is:
- Not available for supervision
- Media expert
Fields of research
Qualifications
- Doctor of Philosophy, Australian National University
- Doctor of Philosophy of Science (Advanced), University of Copenhagen
- Doctoral Diploma, Institution to be confirmed
- Australian Academy of Science, Australian Academy of Science
- Royal Australian Chemical Institute, Royal Australian Chemical Institute
Research interests
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Organic, physical, and historical chemistry
Reactive intermediates, pyrolysis, photochemistry, reaction mechanism. History of science.
Research impacts
This research leads to the development of new pharmaceuticals, e.g. new antibiotics (quinolones and naphthyridones) and new leads towards a treatment for scizophrenia (diazepine molecules).
Chemical industry has used our pyrolysis techniques in specialized manufacturing processes.
Our analytical/spectroscopic work has led to cooperation with chemical and energy firms and agencies involved in forensic science, and our research has generated collaborations with many scientists at universities in Australia, Austria, Belgium, China, Denmark, France, Germany, Hungary, Japan, Portugal, Singapore, Switzerland, and USA.
Works
Search Professor Curt Wentrup’s works on UQ eSpace
2023
Journal Article
Kekulé’s Oscillating <i>D</i> <sub> 3 <i>h</i> </sub> Cyclohexatriene Structure of Benzene
Wentrup, Curt (2023). Kekulé’s Oscillating D 3 h Cyclohexatriene Structure of Benzene. European Journal of Organic Chemistry, 26 (10) e202201308. doi: 10.1002/ejoc.202201308
2023
Journal Article
Reactive intermediates and unusual molecules at Heron Island
Wentrup, Curt (2023). Reactive intermediates and unusual molecules at Heron Island. Australian Journal of Chemistry, 76 (1), I-II. doi: 10.1071/CHv76n1_FO
2022
Journal Article
Azulene–naphthalene, naphthalene–naphthalene, and azulene–azulene rearrangements
Mirzaei, M. Saeed, Taherpour, Avat Arman and Wentrup, Curt (2022). Azulene–naphthalene, naphthalene–naphthalene, and azulene–azulene rearrangements. The Journal of Organic Chemistry, 87 (17), 11503-11518. doi: 10.1021/acs.joc.2c01099
2022
Journal Article
Thermal rearrangement of azulenes to naphthalenes: a deeper insight into the mechanisms
Mirzaei, M. Saeed, Taherpour, Avat Arman and Wentrup, Curt (2022). Thermal rearrangement of azulenes to naphthalenes: a deeper insight into the mechanisms. The Journal of Organic Chemistry, 87 (5) acs.joc.1c02948, 3296-3310. doi: 10.1021/acs.joc.1c02948
2021
Journal Article
Celebrating RACI and Academy of Science Awards 2020–2021
Wentrup, Curt (2021). Celebrating RACI and Academy of Science Awards 2020–2021. Australian Journal of Chemistry, 74 (11), 747-748. doi: 10.1071/chv74n11_fo
2021
Journal Article
Benzotriazoles and triazoloquinones: rearrangements to carbazoles, benzazirines, azepinediones, and fulvenimines
Marchais, Jérémy, Bégué, Didier, Dargelos, Alain and Wentrup, Curt (2021). Benzotriazoles and triazoloquinones: rearrangements to carbazoles, benzazirines, azepinediones, and fulvenimines. The Journal of Organic Chemistry, 86 (23) acs.joc.1c02131, 16992-17001. doi: 10.1021/acs.joc.1c02131
2021
Journal Article
When a “Dimroth Rearrangement” is not a Dimroth rearrangement
Wentrup, Curt, Mirzaei, M. Saeed, Kvaskoff, David and Taherpour, Avat Arman (2021). When a “Dimroth Rearrangement” is not a Dimroth rearrangement. The Journal of Organic Chemistry, 86 (12), 8286-8294. doi: 10.1021/acs.joc.1c00730
2020
Journal Article
Bunsen the geochemist: Icelandic volcanism, geyser theory, and gas, rock and mineral analyses
Wentrup, Curt (2020). Bunsen the geochemist: Icelandic volcanism, geyser theory, and gas, rock and mineral analyses. Angewandte Chemie International Edition, 59 (3) anie.202008727, 2-18. doi: 10.1002/anie.202008727
2020
Journal Article
Ørsted and Bunsen: voltaic batteries, electric arcs, electromagnetism, and electrolysis
Wentrup, Curt (2020). Ørsted and Bunsen: voltaic batteries, electric arcs, electromagnetism, and electrolysis. Angewandte Chemie International Edition, 59 (43) anie.202006761, 18850-18857. doi: 10.1002/anie.202006761
2020
Journal Article
Rearrangements of aromatic nitrile oxides and nitrile ylides: potential ring expansion to cycloheptatetraene derivatives mimicking arylcarbenes
Marchais, Jérémy, Bégué, Didier, Dargelos, Alain and Wentrup, Curt (2020). Rearrangements of aromatic nitrile oxides and nitrile ylides: potential ring expansion to cycloheptatetraene derivatives mimicking arylcarbenes. Chemistry: A European Journal, 26 (67) chem.202003782, 15700-15707. doi: 10.1002/chem.202003782
2020
Journal Article
Aryl nitrile imines and diazo compounds. Formation of indazole, pyridine N-imine, and 2-pyridyldiazomethane from tetrazoles
Begue, Didier, Dargelos, Alain and Wentrup, Curt (2020). Aryl nitrile imines and diazo compounds. Formation of indazole, pyridine N-imine, and 2-pyridyldiazomethane from tetrazoles. Journal of Organic Chemistry, 85 (12), 7952-7958. doi: 10.1021/acs.joc.0c00773
2020
Journal Article
Zeise, Liebig, Jensen, Hückel, Dewar und die Olefin‐π‐Komplex‐Bindung
Wentrup, Curt (2020). Zeise, Liebig, Jensen, Hückel, Dewar und die Olefin‐π‐Komplex‐Bindung. Angewandte Chemie, 132 (22), 8408-8419. doi: 10.1002/ange.201913840
2019
Journal Article
Photolysis and pyrolysis of phenyltetrazoles: Formation of phenylcarbodiimide,N-phenylnitrile imine, phenylnitrene, indazole, and fulvenallene
Zhao, Xiaofang, Liu, Qian, Feng, Ruijuan, Zeng, Xiaoqing and Wentrup, Curt (2019). Photolysis and pyrolysis of phenyltetrazoles: Formation of phenylcarbodiimide,N-phenylnitrile imine, phenylnitrene, indazole, and fulvenallene. European Journal of Organic Chemistry, 2019 (41), 6945-6950. doi: 10.1002/ejoc.201901271
2019
Journal Article
Knallgold und Knallsilber
Wentrup, Curt (2019). Knallgold und Knallsilber. Angewandte Chemie, 131 (42) ange.201906356, 14942-14951. doi: 10.1002/ange.201906356
2019
Journal Article
Transforming triplet vinylnitrene into triplet alkylnitrene at cryogenic temperatures
Shields, Dylan J., Sarkar, Sujan K., Sriyarathne, H. Dushanee M., Brown, Jocelyn R., Wentrup, Curt, Abe, Manabu and Gudmundsdottir, Anna D. (2019). Transforming triplet vinylnitrene into triplet alkylnitrene at cryogenic temperatures. Organic Letters, 21 (18) acs.orglett.9b01950, 7194-7198. doi: 10.1021/acs.orglett.9b01950
2019
Journal Article
Rearrangements of nitrile imines: ring expansion of benzonitrile imines to cycloheptatetraenes and ring closure to 3-phenyl-3H-diazirines
Bégué, Didier, Dargelos, Alain and Wentrup, Curt (2019). Rearrangements of nitrile imines: ring expansion of benzonitrile imines to cycloheptatetraenes and ring closure to 3-phenyl-3H-diazirines. The Journal of Organic Chemistry, 84 (13) acs.joc.9b01183, 8668-8673. doi: 10.1021/acs.joc.9b01183
2019
Journal Article
Spectroscopic characterization of nicotinoyl and isonicotinoyl nitrenes and the photointerconversion of 4-pyridylnitrene with diazacycloheptatetraene
Liu, Qian, Qin, Yuanyuan, Lu, Yan, Wentrup, Curt and Zeng, Xiaoqing (2019). Spectroscopic characterization of nicotinoyl and isonicotinoyl nitrenes and the photointerconversion of 4-pyridylnitrene with diazacycloheptatetraene. The Journal of Physical Chemistry A, 123 (17) acs.jpca.9b01680, 3793-3801. doi: 10.1021/acs.jpca.9b01680
2019
Journal Article
Heteroarylcarbene–arylnitrene radical cation isomerizations
Bégué, Didier, Dargelos, Alain, Braybrook, Carl and Wentrup, Curt (2019). Heteroarylcarbene–arylnitrene radical cation isomerizations. The Journal of Physical Chemistry A, 123 (10) acs.jpca.9b00309, 2073-2079. doi: 10.1021/acs.jpca.9b00309
2019
Journal Article
Phenylnitrene radical cation and its isomers from tetrazoles, nitrile imines, indazole, and benzimidazole
Bégué, Didier, Dargelos, Alain, Braybrook, Carl and Wentrup, Curt (2019). Phenylnitrene radical cation and its isomers from tetrazoles, nitrile imines, indazole, and benzimidazole. The Journal of Physical Chemistry A, 123 (7) acs.jpca.8b11858, 1410-1422. doi: 10.1021/acs.jpca.8b11858
2019
Journal Article
Nitrogen-and Sulfur-Containing Energetic Compounds. 64 Years of Fascinating Chemistry
Wentrup, Curt (2019). Nitrogen-and Sulfur-Containing Energetic Compounds. 64 Years of Fascinating Chemistry. Australian Journal of Chemistry, 72 (8), 585-594. doi: 10.1071/CH19263
Funding
Supervision
Availability
- Emeritus Professor Curt Wentrup is:
- Not available for supervision
Supervision history
Completed supervision
-
2006
Doctor Philosophy
SYNTHESES AND REACTIONS OF IMINOPROPADIENONES, SYDNONES AND OXAZINONES
Principal Advisor
Other advisors: Professor Craig Williams
-
2002
Doctor Philosophy
HETEROCYCLIC SYNTHESIS BASED ON IMINOPROPADIENONES
Principal Advisor
-
2002
Doctor Philosophy
SYNTHESIS AND CHARACTERISATION OF 1,3- and 1,4- DIAZEPINES AND DERIVATIVES
Principal Advisor
-
Doctor Philosophy
NITRENES REARRANGEMENTS: FORMATION OF REACTIVE INTERMEDIATES AND UNUSUAL MOLECULES
Principal Advisor
Other advisors: Professor Craig Williams
Media
Enquiries
Contact Emeritus Professor Curt Wentrup directly for media enquiries about:
- Organic reaction mechanisms
- Photochemistry
- Pyrolysis
- Reactive intermediates
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