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Emeritus Professor Curt Wentrup
Emeritus Professor

Curt Wentrup

Email: 
Phone: 
+61 7 336 53817

Overview

Background

Educated at the University of Copenhagen, Denmark, and the Australian National University, Canberra. Career at the Université de Lausanne, Switzerland, and the Universität Marburg, Germany. Professor and Chair of Organic Chemistry and Head of the Organic Chemistry Section, The University of Queensland from 1985. Emeritus professor from 2008. Chair of the National Committee for Chemistry of the Australian Academy of Science 2009-2014. Editor-in-Chief, Australian Journal of Chemistry 2008-15. Editor, Journal of Analytical and Applied Pyrolysis (Elsevier, IF 3.65) 2016-. Visiting Professor Université de Pau, France, 2011-19; Visiting Professor University of Kuwait 2014-18; Visiting Professor / Special Appointed Professor Hiroshima University 2014-18. Fellow of the Australian Academy of Science. Centenary Medal of the Australian Commonwealth 2003 for research in organic and physical chemistry. David Craig Medal of the Academy of Science 2014 for research in chemistry. JSPS Fellowship (Japan) 2014. Honorary doctorate, University of Pau, France, 2014. A.J. Birch Medal of the Royal Australian Chemical Institute (RACI) for ecellence in research in organic chemistry, 2014. Leighton Medal of the RACI 2018.

Research on Unusual Molecules and Reactive Intermediates: Synthesis and Reaction Mechanism. Heterocyclic chemistry. Pyrolysis reactions. Photochemistry

Research in the Wentrup group is concerned with the discovery of novel types of molecules with new and unusual bonding patterns. Such molecules are mostly highly reactive, and special methods are required both for their generation and for their detection. The group has developed these methods over many years and acquired world-class equipment for these purposes, including flash vacuum thermolysis apparatus, cryostats for matrix isolation of reaction products at cryogenic temperatures (down to 7 K), matrix and solution photochemistry equipment, infrared, UV and mass spectrometers, as well as modern computational facilities.

This research has resulted in the synthesis and characterization of many novel compounds, including extended cumulenes of the types RN=C=C=C=X, which themselves are used in the synthesis of many novel types of molecules, some of them of potential pharmaceutical interest (quinolone antibiotics; diazepines).

The research group has a world reputation in the field of carbene and nitrene chemistry, involving reactive intermediates with sextet carbon or nitrogen. These species are also very useful in synthesis, for example in the preparation of diazepines and diazepinones, a family of pharmaceutically interesting compounds. Numerous mechanistic studies and synthetic applications of ketenes have been carried out in our group.

Active collaborations are ongoing with scientists in Australia (UQ and CSIRO), China (Suzhou), France (Pau), Germany (Oldenburg), Japan (Hiroshima), Spain (Donostia - San Sebastian), and Portugal (Coimbra).

Availability

Emeritus Professor Curt Wentrup is:
Not available for supervision
Media expert

Qualifications

  • Doctor of Philosophy, Australian National University
  • Doctor of Philosophy of Science (Advanced), University of Copenhagen
  • Doctoral Diploma, unknown
  • Australian Academy of Science, Australian Academy of Science
  • Royal Australian Chemical Institute, Royal Australian Chemical Institute

Research interests

  • Organic, physical, and historical chemistry

    Reactive intermediates, pyrolysis, photochemistry, reaction mechanism. History of science.

Research impacts

This research leads to the development of new pharmaceuticals, e.g. new antibiotics (quinolones and naphthyridones) and new leads towards a treatment for scizophrenia (diazepine molecules).

Chemical industry has used our pyrolysis techniques in specialized manufacturing processes.

Our analytical/spectroscopic work has led to cooperation with chemical and energy firms and agencies involved in forensic science, and our research has generated collaborations with many scientists at universities in Australia, Austria, Belgium, China, Denmark, France, Germany, Hungary, Japan, Portugal, Singapore, Switzerland, and USA.

Works

Search Professor Curt Wentrup’s works on UQ eSpace

432 works between 1966 and 2024

61 - 80 of 432 works

2016

Journal Article

Azulene–naphthalene-type rearrangements in Benz[a]azulene and Cyclohepta[b]indole

Wentrup, Curt and Becker, Jürgen (2016). Azulene–naphthalene-type rearrangements in Benz[a]azulene and Cyclohepta[b]indole. Chemistry - A European Journal, 22 (39), 13835-13839. doi: 10.1002/chem.201603389

Azulene–naphthalene-type rearrangements in Benz[a]azulene and Cyclohepta[b]indole

2016

Journal Article

Nitrene–nitrene rearrangement under thermal, photochemical, and electron-impact conditions: the 2-azidopyridines/tetrazolo[1,5-a]pyridines

Wentrup, Curt, Braybrook, Carl, Liu, Shanshan, Tzschucke, C. Christoph, Dargelos, Alain and Bégué, Didier (2016). Nitrene–nitrene rearrangement under thermal, photochemical, and electron-impact conditions: the 2-azidopyridines/tetrazolo[1,5-a]pyridines. European Journal of Organic Chemistry, 2016 (24), 4200-4206. doi: 10.1002/ejoc.201600655

Nitrene–nitrene rearrangement under thermal, photochemical, and electron-impact conditions: the 2-azidopyridines/tetrazolo[1,5-a]pyridines

2016

Journal Article

Pyrolysis of Benzotriazoles. Relationships between 1- and 2-Vinylbenzotriazoles, α- and β-Azidostyrenes, N-Phenylketenimine and Indole. Pitfalls in the use of Pyrolysis-Mass Spectrometry in Mechanistic Studies

Wentrup, Curt and Freiermuth, Beat (2016). Pyrolysis of Benzotriazoles. Relationships between 1- and 2-Vinylbenzotriazoles, α- and β-Azidostyrenes, N-Phenylketenimine and Indole. Pitfalls in the use of Pyrolysis-Mass Spectrometry in Mechanistic Studies. Journal of Analytical and Applied Pyrolysis, 121, 67-74. doi: 10.1016/j.jaap.2016.07.003

Pyrolysis of Benzotriazoles. Relationships between 1- and 2-Vinylbenzotriazoles, α- and β-Azidostyrenes, N-Phenylketenimine and Indole. Pitfalls in the use of Pyrolysis-Mass Spectrometry in Mechanistic Studies

2016

Journal Article

Triazoloazine-diazomethylazine valence isomerization. [1,2,3]triazolo[1,5-a]pyridines and 2-diazomethylpyridines

Aylward, Nigel, Winter, Hans-Wilhelm, Eckhardt, Ulrich and Wentrup, Curt (2016). Triazoloazine-diazomethylazine valence isomerization. [1,2,3]triazolo[1,5-a]pyridines and 2-diazomethylpyridines. Journal of Organic Chemistry, 81 (2), 667-672. doi: 10.1021/acs.joc.5b02639

Triazoloazine-diazomethylazine valence isomerization. [1,2,3]triazolo[1,5-a]pyridines and 2-diazomethylpyridines

2016

Journal Article

Celebrating RACI and Academy of Science Awards

Wentrup, Curt (2016). Celebrating RACI and Academy of Science Awards. Australian Journal of Chemistry, 69 (12), 1321-1322. doi: 10.1071/CHv69n12_FO

Celebrating RACI and Academy of Science Awards

2015

Journal Article

RACI Research Awards 2014

Wentrup, Curt (2015). RACI Research Awards 2014. Australian Journal of Chemistry, 68 (8), 1173-1173. doi: 10.1071/CH15416

RACI Research Awards 2014

2015

Journal Article

α-Oxo-Iminoxyls of Isoxazolones, Pyrazol­ones and 1,2,3-Triazolone

Koch, Rainer, Wollweber, Hans-Joachim, Muller-Starke, Hans and Wentrup, Curt (2015). α-Oxo-Iminoxyls of Isoxazolones, Pyrazol­ones and 1,2,3-Triazolone. European Journal of Organic Chemistry, 2015 (23), 5143-5149. doi: 10.1002/ejoc.201500728

α-Oxo-Iminoxyls of Isoxazolones, Pyrazol­ones and 1,2,3-Triazolone

2015

Journal Article

Comment on "The Mechanism of Pyrolysis of Benzyl Azide: Spectroscopic Evidence for Benzenemethanimine Formation"

Wentrup, Curt (2015). Comment on "The Mechanism of Pyrolysis of Benzyl Azide: Spectroscopic Evidence for Benzenemethanimine Formation". Journal of Physical Chemistry A, 119 (29), 8256-8257. doi: 10.1021/acs.jpca.5b04198

Comment on "The Mechanism of Pyrolysis of Benzyl Azide: Spectroscopic Evidence for Benzenemethanimine Formation"

2015

Journal Article

C15H10 and C15H12 Thermal Chemistry: Phenanthrylcarbene Isomers and Phenylindenes by Falling Solid Flash Vacuum Pyrolysis of Tetrazoles

Wentrup, Curt, Becker, Jurgen and Diehl, Manfred (2015). C15H10 and C15H12 Thermal Chemistry: Phenanthrylcarbene Isomers and Phenylindenes by Falling Solid Flash Vacuum Pyrolysis of Tetrazoles. Journal of Organic Chemistry, 80 (14), 7144-7149. doi: 10.1021/acs.joc.5b01007

C15H10 and C15H12 Thermal Chemistry: Phenanthrylcarbene Isomers and Phenylindenes by Falling Solid Flash Vacuum Pyrolysis of Tetrazoles

2015

Journal Article

Pyrolysis of annelated hexa- and heptamethylene-tetrazoles: Formation of 9- and 10-membered cyclic carbodiimides

Wentrup, Curt and Vosswinkel, Micheal (2015). Pyrolysis of annelated hexa- and heptamethylene-tetrazoles: Formation of 9- and 10-membered cyclic carbodiimides. Journal of Analytical and Applied Pyrolysis, 117, 214-219. doi: 10.1016/j.jaap.2015.11.013

Pyrolysis of annelated hexa- and heptamethylene-tetrazoles: Formation of 9- and 10-membered cyclic carbodiimides

2015

Journal Article

C9H8 pyrolysis. o-tolylacetylene, indene, 1-indenyl, and biindenyls and the mechanism of indene pyrolysis

Wentrup, Curt, Winter, Hans-Wilhelm and Kvaskoff, David (2015). C9H8 pyrolysis. o-tolylacetylene, indene, 1-indenyl, and biindenyls and the mechanism of indene pyrolysis. Journal of Physical Chemistry A, 119 (24), 6370-6376. doi: 10.1021/acs.jpca.5b03453

C9H8 pyrolysis. o-tolylacetylene, indene, 1-indenyl, and biindenyls and the mechanism of indene pyrolysis

2015

Journal Article

Acetylenes from aldehydes. preparation of ethynylphenols and phenylacetylenes by flash vacuum pyrolysis of isoxazolones

Wentrup, Curt, Wiedenstritt, Maria and Winter, Hans-Wilhelm (2015). Acetylenes from aldehydes. preparation of ethynylphenols and phenylacetylenes by flash vacuum pyrolysis of isoxazolones. Australian Journal of Chemistry, 68 (8), 1233-1236. doi: 10.1071/CH15234

Acetylenes from aldehydes. preparation of ethynylphenols and phenylacetylenes by flash vacuum pyrolysis of isoxazolones

2015

Journal Article

Azulenylcarbene and naphthylcarbene isomerizations. falling solid flash vacuum pyrolysis

Kvaskoff, David, Becker, Jurgen and Wentrup, Curt (2015). Azulenylcarbene and naphthylcarbene isomerizations. falling solid flash vacuum pyrolysis. Journal of Organic Chemistry, 80 (10), 5030-5034. doi: 10.1021/acs.joc.5b00412

Azulenylcarbene and naphthylcarbene isomerizations. falling solid flash vacuum pyrolysis

2015

Journal Article

Oximes in the isoxazolone, pyrazolone, and 1,2,3-triazolone series: experimental and computational investigation of energies and structures of e/z isomers of α-oxo-oximes in the gas phase and in solution

Koch, Rainer, Wollweber, Hans-Joachim and Wentrup, Curt (2015). Oximes in the isoxazolone, pyrazolone, and 1,2,3-triazolone series: experimental and computational investigation of energies and structures of e/z isomers of α-oxo-oximes in the gas phase and in solution. Australian Journal of Chemistry, 68 (9), 1329-1335. doi: 10.1071/CH15095

Oximes in the isoxazolone, pyrazolone, and 1,2,3-triazolone series: experimental and computational investigation of energies and structures of e/z isomers of α-oxo-oximes in the gas phase and in solution

2015

Journal Article

Direct detection of a triplet vinylnitrene, 1,4-naphthoquinone-2-ylnitrene, in solution and cryogenic matrices

Sarkar, Sujan K, Sawai, Asako, Kanahara, Kousei, Wentrup, Curt, Abe, Manabu and Gudmundsdottir, Anna D (2015). Direct detection of a triplet vinylnitrene, 1,4-naphthoquinone-2-ylnitrene, in solution and cryogenic matrices. Journal of the American Chemical Society, 137 (12), 4207-4214. doi: 10.1021/jacs.5b00998

Direct detection of a triplet vinylnitrene, 1,4-naphthoquinone-2-ylnitrene, in solution and cryogenic matrices

2015

Journal Article

Comments on photochromism of 3-(3-pyridyl)sydnone and 4-alkenylsydnones

Wentrup, Curt, Kvaskoff, David and Veedu, Rakesh N (2015). Comments on photochromism of 3-(3-pyridyl)sydnone and 4-alkenylsydnones. Journal of Photochemistry and Photobiology A: Chemistry, 298, 62-63. doi: 10.1016/j.jphotochem.2014.10.010

Comments on photochromism of 3-(3-pyridyl)sydnone and 4-alkenylsydnones

2015

Journal Article

Molecular cleft or tweezer compounds derived from trioxabicyclo[3.3.1]nonadiene diisocyanate and diacid dichloride

Kollenz, Gert, Smounig, Ralf, Belaj, Ferdinand, Kvaskoff, David and Wentrup, Curt (2015). Molecular cleft or tweezer compounds derived from trioxabicyclo[3.3.1]nonadiene diisocyanate and diacid dichloride. Beilstein Journal of Organic Chemistry, 11 (1), 1-8. doi: 10.3762/bjoc.11.1

Molecular cleft or tweezer compounds derived from trioxabicyclo[3.3.1]nonadiene diisocyanate and diacid dichloride

2015

Journal Article

RACI Congress Adelaide

Wentrup, Curt (2015). RACI Congress Adelaide. Australian Journal of Chemistry, 68 (9), 1317-1318. doi: 10.1071/CH15508

RACI Congress Adelaide

2015

Journal Article

New Year Editorial 2015

Wentrup, Curt (2015). New Year Editorial 2015. Australian Journal of Chemistry, 68 (1), 1-2. doi: 10.1071/CH14678

New Year Editorial 2015

2015

Journal Article

Ketenes from N-(2-Pyridyl)amides

Plug, Carsten, Kanaani, Hussein and Wentrup, Curt (2015). Ketenes from N-(2-Pyridyl)amides. Australian Journal of Chemistry, 68 (4), 687-692. doi: 10.1071/CH14714

Ketenes from N-(2-Pyridyl)amides

Funding

Past funding

  • 2012 - 2013
    Heron Island Conference on reactive intermediate and unusual molecules
    Ian Potter Foundation
    Open grant
  • 2010
    UQ Travel Awards Category 1, Fabian Borget
    UQ Travel Grants Scheme
    Open grant
  • 2007 - 2009
    Reactive intermediates and microwave-assisted organic reactions
    ARC Discovery Projects
    Open grant
  • 2007
    Research in pre-biotic chemistry
    UQ Travel Grants Scheme
    Open grant
  • 2004
    Research conference grant for Prof Josef Michl, University of Colorado, Boulder, to attend Heron Island Conference on reactive intermediates and unusual molecules, 17-23 July 2004
    Potter Foundation
    Open grant
  • 2004 - 2006
    New mechanisms and methods in carbene and nitrene chemistry
    ARC Discovery Projects
    Open grant
  • 2003 - 2005
    Bimolecular chemistry at very low temperature
    ARC Linkage International
    Open grant
  • 2002
    To expand work on cryogenic matrix isolation research.
    UQ Travel Grants Scheme
    Open grant
  • 2001 - 2003
    Chemistry of Iminopropadienones and Related Compounds.
    ARC Australian Research Council (Large grants)
    Open grant
  • 2000
    Novel approaches to heterocyclic synthesis.
    ARC Australian Research Council (Small grants)
    Open grant
  • 1997
    Brisbane Advanced Mass Spectrometry Facility
    Research Infrastructure (Equip & Fac) Program
    Open grant
  • 1997
    Synthesis of 1,3-diazepines
    ARC Australian Research Council (Small grants)
    Open grant
  • 1996 - 1997
    International Network in Advanced Techniques of Applied Molecular Science
    Quality Funds Round 3
    Open grant
  • 1996
    Pulsed pyrolysis
    ARC Australian Research Council (Small grants)
    Open grant

Supervision

Availability

Emeritus Professor Curt Wentrup is:
Not available for supervision

Supervision history

Completed supervision

  • 2006

    Doctor Philosophy

    SYNTHESES AND REACTIONS OF IMINOPROPADIENONES, SYDNONES AND OXAZINONES

    Principal Advisor

    Other advisors: Professor Craig Williams

  • 2002

    Doctor Philosophy

    HETEROCYCLIC SYNTHESIS BASED ON IMINOPROPADIENONES

    Principal Advisor

  • 2002

    Doctor Philosophy

    SYNTHESIS AND CHARACTERISATION OF 1,3- and 1,4- DIAZEPINES AND DERIVATIVES

    Principal Advisor

  • Doctor Philosophy

    NITRENES REARRANGEMENTS: FORMATION OF REACTIVE INTERMEDIATES AND UNUSUAL MOLECULES

    Principal Advisor

    Other advisors: Professor Craig Williams

Media

Enquiries

Contact Emeritus Professor Curt Wentrup directly for media enquiries about:

  • Organic reaction mechanisms
  • Photochemistry
  • Pyrolysis
  • Reactive intermediates

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