Skip to menu Skip to content Skip to footer
Emeritus Professor Curt Wentrup
Emeritus Professor

Curt Wentrup

Email: 
Phone: 
+61 7 336 53817

Overview

Background

Educated at the University of Copenhagen, Denmark, and the Australian National University, Canberra. Career at the Université de Lausanne, Switzerland, and the Universität Marburg, Germany. Professor and Chair of Organic Chemistry and Head of the Organic Chemistry Section, The University of Queensland from 1985. Emeritus professor from 2008. Chair of the National Committee for Chemistry of the Australian Academy of Science 2009-2014. Editor-in-Chief, Australian Journal of Chemistry 2008-15. Editor, Journal of Analytical and Applied Pyrolysis (Elsevier, IF 3.65) 2016-. Visiting Professor Université de Pau, France, 2011-19; Visiting Professor University of Kuwait 2014-18; Visiting Professor / Special Appointed Professor Hiroshima University 2014-18. Fellow of the Australian Academy of Science. Centenary Medal of the Australian Commonwealth 2003 for research in organic and physical chemistry. David Craig Medal of the Academy of Science 2014 for research in chemistry. JSPS Fellowship (Japan) 2014. Honorary doctorate, University of Pau, France, 2014. A.J. Birch Medal of the Royal Australian Chemical Institute (RACI) for ecellence in research in organic chemistry, 2014. Leighton Medal of the RACI 2018.

Research on Unusual Molecules and Reactive Intermediates: Synthesis and Reaction Mechanism. Heterocyclic chemistry. Pyrolysis reactions. Photochemistry

Research in the Wentrup group is concerned with the discovery of novel types of molecules with new and unusual bonding patterns. Such molecules are mostly highly reactive, and special methods are required both for their generation and for their detection. The group has developed these methods over many years and acquired world-class equipment for these purposes, including flash vacuum thermolysis apparatus, cryostats for matrix isolation of reaction products at cryogenic temperatures (down to 7 K), matrix and solution photochemistry equipment, infrared, UV and mass spectrometers, as well as modern computational facilities.

This research has resulted in the synthesis and characterization of many novel compounds, including extended cumulenes of the types RN=C=C=C=X, which themselves are used in the synthesis of many novel types of molecules, some of them of potential pharmaceutical interest (quinolone antibiotics; diazepines).

The research group has a world reputation in the field of carbene and nitrene chemistry, involving reactive intermediates with sextet carbon or nitrogen. These species are also very useful in synthesis, for example in the preparation of diazepines and diazepinones, a family of pharmaceutically interesting compounds. Numerous mechanistic studies and synthetic applications of ketenes have been carried out in our group.

Active collaborations are ongoing with scientists in Australia (UQ and CSIRO), China (Suzhou), France (Pau), Germany (Oldenburg), Japan (Hiroshima), Spain (Donostia - San Sebastian), and Portugal (Coimbra).

Availability

Emeritus Professor Curt Wentrup is:
Not available for supervision
Media expert

Qualifications

  • Doctor of Philosophy, Australian National University
  • Doctor of Philosophy of Science (Advanced), University of Copenhagen
  • Doctoral Diploma, unknown
  • Australian Academy of Science, Australian Academy of Science
  • Royal Australian Chemical Institute, Royal Australian Chemical Institute

Research interests

  • Organic, physical, and historical chemistry

    Reactive intermediates, pyrolysis, photochemistry, reaction mechanism. History of science.

Research impacts

This research leads to the development of new pharmaceuticals, e.g. new antibiotics (quinolones and naphthyridones) and new leads towards a treatment for scizophrenia (diazepine molecules).

Chemical industry has used our pyrolysis techniques in specialized manufacturing processes.

Our analytical/spectroscopic work has led to cooperation with chemical and energy firms and agencies involved in forensic science, and our research has generated collaborations with many scientists at universities in Australia, Austria, Belgium, China, Denmark, France, Germany, Hungary, Japan, Portugal, Singapore, Switzerland, and USA.

Works

Search Professor Curt Wentrup’s works on UQ eSpace

432 works between 1966 and 2024

81 - 100 of 432 works

2015

Journal Article

Trifluoromethylphenylcarbenes. Carbene-Carbene Interconversion on the Singlet Energy Surface and Rearrangement to Trifluorobenzocyclobutene, Trifluorostyrene, and Trifluoromethylfulvenallenes

Blanch, Rodney J. and Wentrup, Curt (2015). Trifluoromethylphenylcarbenes. Carbene-Carbene Interconversion on the Singlet Energy Surface and Rearrangement to Trifluorobenzocyclobutene, Trifluorostyrene, and Trifluoromethylfulvenallenes. Australian Journal of Chemistry, 68 (1), 36-43. doi: 10.1071/CH14097

Trifluoromethylphenylcarbenes. Carbene-Carbene Interconversion on the Singlet Energy Surface and Rearrangement to Trifluorobenzocyclobutene, Trifluorostyrene, and Trifluoromethylfulvenallenes

2015

Journal Article

Sir John Cornforth Memorial Issue

Wentrup, Curt (2015). Sir John Cornforth Memorial Issue. Australian Journal of Chemistry, 68 (4), 519-520. doi: 10.1071/CH15100

Sir John Cornforth Memorial Issue

2014

Journal Article

Phenylnitrene, phenylcarbene, and pyridylcarbenes. Rearrangements to cyanocyclopentadiene and fulvenallene.

Kvaskoff, David, Lüerssen, Holger, Bednarek, Pawel and Wentrup, Curt (2014). Phenylnitrene, phenylcarbene, and pyridylcarbenes. Rearrangements to cyanocyclopentadiene and fulvenallene.. Journal of the American Chemical Society, 136 (43), 15203-15214. doi: 10.1021/ja506151p

Phenylnitrene, phenylcarbene, and pyridylcarbenes. Rearrangements to cyanocyclopentadiene and fulvenallene.

2014

Journal Article

Flash (vacuum) pyrolysis apparatus and methods

Wentrup, Curt (2014). Flash (vacuum) pyrolysis apparatus and methods. Australian Journal of Chemistry, 67 (9), 1150-1165. doi: 10.1071/CH14096

Flash (vacuum) pyrolysis apparatus and methods

2014

Journal Article

Ketene-Ketene interconversion. 6-Carbonylcyclohexa-2,4-dienone-hepta-1,2,4, 6-tetraene-1,7-dione-6-oxocyclohexa-2,4-dienylidene and wolff rearrangement to fulven-6-one

Koch, Rainer, Blanch, Rodney J. and Wentrup, Curt (2014). Ketene-Ketene interconversion. 6-Carbonylcyclohexa-2,4-dienone-hepta-1,2,4, 6-tetraene-1,7-dione-6-oxocyclohexa-2,4-dienylidene and wolff rearrangement to fulven-6-one. Journal of Organic Chemistry, 79 (15), 6978-6986. doi: 10.1021/jo5011087

Ketene-Ketene interconversion. 6-Carbonylcyclohexa-2,4-dienone-hepta-1,2,4, 6-tetraene-1,7-dione-6-oxocyclohexa-2,4-dienylidene and wolff rearrangement to fulven-6-one

2014

Journal Article

Comment on "Computational Study on the Vinyl Azide Decomposition"

Wentrup, Curt, Nunes, Claudio M and Reva, Igor (2014). Comment on "Computational Study on the Vinyl Azide Decomposition". Journal of Physical Chemistry A, 118 (27), 5122-5123. doi: 10.1021/jp503958z

Comment on "Computational Study on the Vinyl Azide Decomposition"

2014

Journal Article

Flash vacuum thermolysis of N-(3- and 4-pyridylmethylidene)-tert-butylamines: mechanisms of formation of pyrrolopyridines and naphthyridines

Justyna, Katarzyna, Leśniak, Stanisław, Nazarski, Ryszard B., Rachwalski, Michał, Vu, Thien Y., Huynh, Thi Kieu Xuan, Khayar, Saïd, Dargelos, Alain, Chrostowska, Anna and Wentrup, Curt (2014). Flash vacuum thermolysis of N-(3- and 4-pyridylmethylidene)-tert-butylamines: mechanisms of formation of pyrrolopyridines and naphthyridines. European Journal of Organic Chemistry, 2014 (14), 3020-3027. doi: 10.1002/ejoc.201400112

Flash vacuum thermolysis of N-(3- and 4-pyridylmethylidene)-tert-butylamines: mechanisms of formation of pyrrolopyridines and naphthyridines

2014

Journal Article

6th Heron Island conference on reactive intermediates and unusual molecules

Wentrup, Curt and Williams, Craig (2014). 6th Heron Island conference on reactive intermediates and unusual molecules. Australian Journal of Chemistry, 67 (3), 317-319. doi: 10.1071/CH14041

6th Heron Island conference on reactive intermediates and unusual molecules

2014

Journal Article

Nitrile ylides: allenic and propargylic structures from pyrazinylnitrenes. Experimental and theoretical characterization

Begue, Didier, Addicott, Chris, Burgard, Riko, Bednarek, Pawel, Guille, Emilie, Baraille, Isabelle and Wentrup, Curt (2014). Nitrile ylides: allenic and propargylic structures from pyrazinylnitrenes. Experimental and theoretical characterization. Journal of Organic Chemistry, 79 (5), 2148-2155. doi: 10.1021/jo500002r

Nitrile ylides: allenic and propargylic structures from pyrazinylnitrenes. Experimental and theoretical characterization

2014

Journal Article

3-pyridazinylnitrenes and 2-pyrimidinylnitrenes

Torker, Sebastian, Kvaskoff, David and Wentrup, Curt (2014). 3-pyridazinylnitrenes and 2-pyrimidinylnitrenes. Journal of Organic Chemistry, 79 (4), 1758-1770. doi: 10.1021/jo4027897

3-pyridazinylnitrenes and 2-pyrimidinylnitrenes

2014

Journal Article

Carbenic nitrile imines: Properties and reactivity

Begue, Didier and Wentrup, Curt (2014). Carbenic nitrile imines: Properties and reactivity. Journal of Organic Chemistry, 79 (3), 1418-1426. doi: 10.1021/jo402875c

Carbenic nitrile imines: Properties and reactivity

2014

Journal Article

Nitrile imines and nitrile ylides: Rearrangements of benzonitrile N-methylimine and benzonitrile dimethylmethylide to azabutadienes, carbodiimides, and ketenimines. chemical activation in thermolysis of azirenes, tetrazoles, oxazolones, isoxazolones, and

Begue, Didier, Dargelos, Alain, Berstermann, Hans M., Netsch, Klaus P., Bednarek, Pawel and Wentrup, Curt (2014). Nitrile imines and nitrile ylides: Rearrangements of benzonitrile N-methylimine and benzonitrile dimethylmethylide to azabutadienes, carbodiimides, and ketenimines. chemical activation in thermolysis of azirenes, tetrazoles, oxazolones, isoxazolones, and. Journal of Organic Chemistry, 79 (3), 1247-1253. doi: 10.1021/jo402667y

Nitrile imines and nitrile ylides: Rearrangements of benzonitrile N-methylimine and benzonitrile dimethylmethylide to azabutadienes, carbodiimides, and ketenimines. chemical activation in thermolysis of azirenes, tetrazoles, oxazolones, isoxazolones, and

2014

Journal Article

New year editorial 2014

Wentrup, Curt (2014). New year editorial 2014. Australian Journal of Chemistry, 67 (1), 1-2. doi: 10.1071/CH13677

New year editorial 2014

2014

Journal Article

Formation of allenyl ketones, 3-ethynylcoumarins, and arylfurans, furylfurans, and furylthiophenes by flash vacuum thermolysis of 3-methylidenefuran-2(3 H)-ones

Koch, Rainer, Berstermann, Hans Michael and Wentrup, Curt (2014). Formation of allenyl ketones, 3-ethynylcoumarins, and arylfurans, furylfurans, and furylthiophenes by flash vacuum thermolysis of 3-methylidenefuran-2(3 H)-ones. Journal of Organic Chemistry, 79 (1), 65-71. doi: 10.1021/jo402139a

Formation of allenyl ketones, 3-ethynylcoumarins, and arylfurans, furylfurans, and furylthiophenes by flash vacuum thermolysis of 3-methylidenefuran-2(3 H)-ones

2014

Journal Article

Nitrene-carbene-carbene rearrangement. photolysis and thermolysis of tetrazolo[5,1- a ]phthalazine with formation of 1-phthalazinylnitrene, o-cyanophenylcarbene, and phenylcyanocarbene

Hoj, Martin, Kvaskoff, David and Wentrup, Curt (2014). Nitrene-carbene-carbene rearrangement. photolysis and thermolysis of tetrazolo[5,1- a ]phthalazine with formation of 1-phthalazinylnitrene, o-cyanophenylcarbene, and phenylcyanocarbene. Journal of Organic Chemistry, 79 (1), 307-313. doi: 10.1021/jo402448u

Nitrene-carbene-carbene rearrangement. photolysis and thermolysis of tetrazolo[5,1- a ]phthalazine with formation of 1-phthalazinylnitrene, o-cyanophenylcarbene, and phenylcyanocarbene

2014

Conference Publication

Reactions of adamantanethione with ketenes: Formation of a 1,3,5-dioxathiane

Drinnan, Nicholas and Wentrup, Curt (2014). Reactions of adamantanethione with ketenes: Formation of a 1,3,5-dioxathiane. 6th Heron Island Conference on Reactive Intermediates and Unusual Molecules, Heron Island, QLD, Australia, 7-13 July 2013. Collingwood, VIC Australia: CSIRO. doi: 10.1071/CH13449

Reactions of adamantanethione with ketenes: Formation of a 1,3,5-dioxathiane

2014

Journal Article

Roger F. C. Brown Memorial Issue

Wentrup, Curt (2014). Roger F. C. Brown Memorial Issue. Australian Journal of Chemistry, 67 (8-9), 1139-1141. doi: 10.1071/CH14419

Roger F. C. Brown Memorial Issue

2014

Conference Publication

Sydnone photochemistry: Direct observation of earl's bicyclic lactone valence isomers (oxadiazabicyclo[2.1.0] pentanones), formation of carbodiimides, reaction mechanism, and photochromism

Veedu, Rakesh N., Kvaskoff, David and Wentrup, Curt (2014). Sydnone photochemistry: Direct observation of earl's bicyclic lactone valence isomers (oxadiazabicyclo[2.1.0] pentanones), formation of carbodiimides, reaction mechanism, and photochromism. 6th Heron Island Conference on Reactive Intermediates and Unusual Molecules, Heron Island, Qld, Australia, 7 - 13 July 2013. Collingwood, VIC Australia: CSIRO. doi: 10.1071/CH13536

Sydnone photochemistry: Direct observation of earl's bicyclic lactone valence isomers (oxadiazabicyclo[2.1.0] pentanones), formation of carbodiimides, reaction mechanism, and photochromism

2014

Journal Article

C8H6 thermal chemistry. 7-Methylenecyclohepta-1,3,5- dienyne (heptafulvyne) by flash vacuum thermolysis]matrix isolation. Chemical activation in the rearrangements of phenylenedicarbenes and of benzocyclobutadiene to phenylacetylene

Kuhn, Arvid, Miura, Daisuke, Tomioka, Hideo and Wentrup, Curt (2014). C8H6 thermal chemistry. 7-Methylenecyclohepta-1,3,5- dienyne (heptafulvyne) by flash vacuum thermolysis]matrix isolation. Chemical activation in the rearrangements of phenylenedicarbenes and of benzocyclobutadiene to phenylacetylene. Australian Journal of Chemistry, 67 (8-9), 1174-1179. doi: 10.1071/CH13670

C8H6 thermal chemistry. 7-Methylenecyclohepta-1,3,5- dienyne (heptafulvyne) by flash vacuum thermolysis]matrix isolation. Chemical activation in the rearrangements of phenylenedicarbenes and of benzocyclobutadiene to phenylacetylene

2013

Journal Article

Photolysis of dimethylcarbamoyl azide in an argon matrix: Spectroscopic identification of dimethylamino isocyanate and 1,1-dimethyldiazene

Pasinszki, Tibor, Krebsz, Melinda, Tarczay, György and Wentrup, Curt (2013). Photolysis of dimethylcarbamoyl azide in an argon matrix: Spectroscopic identification of dimethylamino isocyanate and 1,1-dimethyldiazene. Journal of Organic Chemistry, 78 (23), 11985-11991. doi: 10.1021/jo402023m

Photolysis of dimethylcarbamoyl azide in an argon matrix: Spectroscopic identification of dimethylamino isocyanate and 1,1-dimethyldiazene

Funding

Past funding

  • 2012 - 2013
    Heron Island Conference on reactive intermediate and unusual molecules
    Ian Potter Foundation
    Open grant
  • 2010
    UQ Travel Awards Category 1, Fabian Borget
    UQ Travel Grants Scheme
    Open grant
  • 2007 - 2009
    Reactive intermediates and microwave-assisted organic reactions
    ARC Discovery Projects
    Open grant
  • 2007
    Research in pre-biotic chemistry
    UQ Travel Grants Scheme
    Open grant
  • 2004
    Research conference grant for Prof Josef Michl, University of Colorado, Boulder, to attend Heron Island Conference on reactive intermediates and unusual molecules, 17-23 July 2004
    Potter Foundation
    Open grant
  • 2004 - 2006
    New mechanisms and methods in carbene and nitrene chemistry
    ARC Discovery Projects
    Open grant
  • 2003 - 2005
    Bimolecular chemistry at very low temperature
    ARC Linkage International
    Open grant
  • 2002
    To expand work on cryogenic matrix isolation research.
    UQ Travel Grants Scheme
    Open grant
  • 2001 - 2003
    Chemistry of Iminopropadienones and Related Compounds.
    ARC Australian Research Council (Large grants)
    Open grant
  • 2000
    Novel approaches to heterocyclic synthesis.
    ARC Australian Research Council (Small grants)
    Open grant
  • 1997
    Brisbane Advanced Mass Spectrometry Facility
    Research Infrastructure (Equip & Fac) Program
    Open grant
  • 1997
    Synthesis of 1,3-diazepines
    ARC Australian Research Council (Small grants)
    Open grant
  • 1996 - 1997
    International Network in Advanced Techniques of Applied Molecular Science
    Quality Funds Round 3
    Open grant
  • 1996
    Pulsed pyrolysis
    ARC Australian Research Council (Small grants)
    Open grant

Supervision

Availability

Emeritus Professor Curt Wentrup is:
Not available for supervision

Supervision history

Completed supervision

  • 2006

    Doctor Philosophy

    SYNTHESES AND REACTIONS OF IMINOPROPADIENONES, SYDNONES AND OXAZINONES

    Principal Advisor

    Other advisors: Professor Craig Williams

  • 2002

    Doctor Philosophy

    HETEROCYCLIC SYNTHESIS BASED ON IMINOPROPADIENONES

    Principal Advisor

  • 2002

    Doctor Philosophy

    SYNTHESIS AND CHARACTERISATION OF 1,3- and 1,4- DIAZEPINES AND DERIVATIVES

    Principal Advisor

  • Doctor Philosophy

    NITRENES REARRANGEMENTS: FORMATION OF REACTIVE INTERMEDIATES AND UNUSUAL MOLECULES

    Principal Advisor

    Other advisors: Professor Craig Williams

Media

Enquiries

Contact Emeritus Professor Curt Wentrup directly for media enquiries about:

  • Organic reaction mechanisms
  • Photochemistry
  • Pyrolysis
  • Reactive intermediates

Need help?

For help with finding experts, story ideas and media enquiries, contact our Media team:

communications@uq.edu.au