Overview
Background
I obtained my BSc.(Hons) from the University of New South Wales in Australia, then went on to pursue a PhD at the Australian National University’s Research School of Chemistry under the supervision of Professor Anthony Hill. After stints at the University of Oxford and the University of Edinburgh as a research fellow in groups of Andrew Weller and Polly Arnold respectively, I began my independent career at the National University of Singapore in 2014. Since then I have focused on methodology development using pincer complexes and frustrated Lewis pairs to address challenges in small molecule activation, in particular the selective activation of carbon-halide and carbon-chalcogen bonds. My achievements have been recognized with research awards including Asian Chemistry Prizes from Japan and China (2018) and the Thieme Chemistry Journal Award in 2019. In 2022 I was awarded an ARC Future Fellowship, which I assumed at the University of Queensland in mid-2023. The theme of the research for this fellowship is the recycling and repurposing of fluorocarbons through selective activation using organometallic techniques.
Availability
- Dr Rowan Young is:
- Available for supervision
Fields of research
Research interests
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Frustrated Lewis Pairs
Activation chemistry based on the interaction of bulky Lewis acid and bases
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Transition Metal Pincer Chemistry
Chemistry concerning synthesis, reactivity and catalysis of PC(carbene)P pincer complexes that feature central alkylidene donors.
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Carbon-Fluorine Bond Activation and Functionalisation
The development of new methods to functionalise fluorocarbons, including the selective activation of fluorine-carbon bonds in poly fluorocarbons.
Research impacts
My research focuses on methodology development utilising base metals and frustrated Lewis pairs. I have developed unique ways to selectively activate carbon-fluorine bonds in polyfluorocarbon compounds. My group continues to explore this field allowing direct access to a wide array of second generation fluorinated molecules. We also develop new frustrated Lewis pair systems based on utilising first row transition metal that allow enhanced activation of and catalysis with otherwise inert compounds. Our last avenue of research is in the field of pincer ligand transition metals. We have developed new methods to synthesize alkylidene centred pincer ligands, and we are exploring how these can be exploited in bond activation and catalysis.
Works
Search Professor Rowan Young’s works on UQ eSpace
2013
Journal Article
Bis(phosphine)boronium salts. Synthesis, structures and coordination chemistry
Shuttleworth, Timothy A., Huertos, Miguel A., Pernik, Indrek, Young, Rowan D. and Weller, Andrew S. (2013). Bis(phosphine)boronium salts. Synthesis, structures and coordination chemistry. Dalton Transactions, 42 (36), 12917-12925. doi: 10.1039/c3dt50817j
2013
Journal Article
[(μ-C){Re(CO)2(η-C5H5)} 2]: A surprisingly simple bimetallic carbido complex
Young, Rowan D., Hill, Anthony F., Cavigliasso, Germán E. and Stranger, Robert (2013). [(μ-C){Re(CO)2(η-C5H5)} 2]: A surprisingly simple bimetallic carbido complex. Angewandte Chemie - International Edition, 52 (13), 3699-3702. doi: 10.1002/anie.201207731
2013
Journal Article
Carbon–carbon bond construction using boronic acids and aryl methyl sulfides: Orthogonal reactivity in Suzuki-type couplings
Hooper, Joel F., Young, Rowan D., Pernik, Indrek, Weller, Andrew S. and Willis, Michael C. (2013). Carbon–carbon bond construction using boronic acids and aryl methyl sulfides: Orthogonal reactivity in Suzuki-type couplings. Chemical Science, 4 (4), 1568-1572. doi: 10.1039/c3sc00052d
2013
Journal Article
Traceless chelation-controlled rhodium-catalyzed intermolecular alkene and alkyne hydroacylation
Hooper, Joel F., Young, Rowan D., Weller, Andrew S. and Willis, Michael C. (2013). Traceless chelation-controlled rhodium-catalyzed intermolecular alkene and alkyne hydroacylation. Chemistry - A European Journal, 19 (9), 3125-3130. doi: 10.1002/chem.201204056
2012
Journal Article
Observation of a tungsten alkane σ-complex showing selective binding of methyl groups using FTIR and NMR spectroscopies
Young, Rowan D., Lawes, Douglas J., Hill, Anthony F. and Ball, Graham E. (2012). Observation of a tungsten alkane σ-complex showing selective binding of methyl groups using FTIR and NMR spectroscopies. Journal of the American Chemical Society, 134 (20), 8294-8297. doi: 10.1021/ja300281s
2011
Journal Article
Transition metal-alkane θ-complexes with oxygen donor Co-ligands
Young, Rowan D., Hill, Anthony F., Hillier, Warwick and Ball, Graham E. (2011). Transition metal-alkane θ-complexes with oxygen donor Co-ligands. Journal of the American Chemical Society, 133 (35), 13806-13809. doi: 10.1021/ja203470y
2009
Journal Article
On the nature of "RuCl(dmso)2{HB(mt)3}" (mt = methimazolyl)
Abernethy, Robyn J., Hill, Anthony F., Tshabang, Never, Willis, Anthony C. and Young, Rowan D. (2009). On the nature of "RuCl(dmso)2{HB(mt)3}" (mt = methimazolyl). Organometallics, 28 (2), 488-492. doi: 10.1021/om8007426
2008
Journal Article
Poly(methimazolyl)borato nitrosyl complexes of molybdenum and tungsten
Abernethy, Robyn J., Foreman, Mark R. St. -J., Hill, Anthony F., Tshabang, Never, Willis, Anthony C. and Young, Rowan D. (2008). Poly(methimazolyl)borato nitrosyl complexes of molybdenum and tungsten. Organometallics, 27 (17), 4455-4463. doi: 10.1021/om800416j
2006
Journal Article
Covalently linked ferrocenyl quinones: Proton-dependent redox behavior and charge redistribution
Colbran, Stephen B., Lee, Sang Tae, Lonnon, David G., Maharaj, Felicia J. D., McDonagh, Andrew M., Walker, Katherine A. and Young, Rowan D. (2006). Covalently linked ferrocenyl quinones: Proton-dependent redox behavior and charge redistribution. Organometallics, 25 (9), 2216-2224. doi: 10.1021/om060040x
Funding
Current funding
Supervision
Availability
- Dr Rowan Young is:
- Available for supervision
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Available projects
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Fluorocarbon activation using organometallic chemistry
Fundamental challenges in transforming synthetic and energy-based materials are increasingly being met using inorganic chemical solutions.
This project focuses on C-F bond activation and functionalization using main group organometallic catalysts. The project will involve advanced organometallic syntheses as well as organic synthesis to demonstrate catalyst competency.
The successful candidate will also gain a thorough knowledge of fluorocarbon chemistry. Training will be extensive and cover inorganic, organometallic and organic synthetic techniques in synthesis and analytical characterisation.
Media
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