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2024 Journal Article Evidence for a kinetic FLP reaction pathway in the activation of benzyl chlorides by alkali metal-phosphine pairsCsókás, Dániel, Coles, Max, Toh, Zhi Hao and Young, Rowan Drury (2024). Evidence for a kinetic FLP reaction pathway in the activation of benzyl chlorides by alkali metal-phosphine pairs. Dalton Transactions, 53 (35), 14582-14586. doi: 10.1039/d4dt02028f |
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2024 Journal Article Alternative Si–F Elimination and Fluoride Abstraction Pathways in Selective Monodefluorination of Me<sub>3</sub>SiCF<sub>3</sub> and Me<sub>3</sub>SiCF<sub>2</sub>HLye, Kenneth, Mandal, Dipendu and Young, Rowan D. (2024). Alternative Si–F Elimination and Fluoride Abstraction Pathways in Selective Monodefluorination of Me3SiCF3 and Me3SiCF2H. Organometallics, 43 (17), 1922-1928. doi: 10.1021/acs.organomet.4c00279 |
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2024 Journal Article A review of frustrated Lewis pair enabled monoselective C-F bond activationLye, Kenneth and Young, Rowan D. (2024). A review of frustrated Lewis pair enabled monoselective C-F bond activation. Chemical Science, 15 (8), 2712-2724. doi: 10.1039/d3sc06485a |
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2023 Journal Article Stereoselective synthesis of fluoroalkanes via FLP mediated monoselective C─F activation of geminal difluoroalkanesCsókás, Dániel, Mondal, Bivas, Đokić, Miloš, Gupta, Richa, Lee, Beatrice J. Y. and Young, Rowan D. (2023). Stereoselective synthesis of fluoroalkanes via FLP mediated monoselective C─F activation of geminal difluoroalkanes. Advanced Science, 10 (36) 2305768, 1-5. doi: 10.1002/advs.202305768 |
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2023 Journal Article Frustrated Lewis pair catalyzed C–F activation of α-trifluoromethylstyrenesChan, Chakyu Richard, Mandal, Dipendu and Young, Rowan D. (2023). Frustrated Lewis pair catalyzed C–F activation of α-trifluoromethylstyrenes. Tetrahedron Chem, 8 100050, 1-4. doi: 10.1016/j.tchem.2023.100050 |
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2023 Journal Article Synthesis of bimetallic rhodium phosphinine complexes with enhanced catalytic activity towards alkyne hydrosilylationTan, Clarence, Tinnermann, Hendrik, Wee, Vanessa, Tan, Shaun, Sung, Simon, Wang, Qingyang and Young, Rowan D. (2023). Synthesis of bimetallic rhodium phosphinine complexes with enhanced catalytic activity towards alkyne hydrosilylation. Journal of Organometallic Chemistry, 986 122617. doi: 10.1016/j.jorganchem.2023.122617 |
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2023 Journal Article Experimental and computational insights into the mechanism of FLP mediated selective C-F bond activationGupta, Richa, Csókás, Dániel, Lye, Kenneth and Young, Rowan D. (2023). Experimental and computational insights into the mechanism of FLP mediated selective C-F bond activation. Chemical Science, 14 (5), 1291-1300. doi: 10.1039/d2sc05632a |
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2022 Journal Article Gauging the donor strength of iron(0) complexes via their N-heterocyclic carbene gold(i) adductsToh, Zhi Hao, Tinnermann, Hendrik, Do, Dinh Cao Huan, Huynh, Han Vinh, Krämer, Tobias and Young, Rowan D. (2022). Gauging the donor strength of iron(0) complexes via their N-heterocyclic carbene gold(i) adducts. Chemical Communications, 58 (93), 12947-12950. doi: 10.1039/d2cc05041b |
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2022 Journal Article Fluorine‐18 Labeling of Difluoromethyl and Trifluoromethyl Groups via Monoselective C−F Bond ActivationKhanapur, Shivashankar, Lye, Kenneth, Mandal, Dipendu, Jie Wee, Xin, Robins, Edward G. and Young, Rowan D. (2022). Fluorine‐18 Labeling of Difluoromethyl and Trifluoromethyl Groups via Monoselective C−F Bond Activation. Angewandte Chemie, 134 (49). doi: 10.1002/ange.202210917 |
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2022 Journal Article Fluorine‐18 labeling of difluoromethyl and trifluoromethyl groups via monoselective C−F bond activationKhanapur, Shivashankar, Lye, Kenneth, Mandal, Dipendu, Jie Wee, Xin, Robins, Edward G. and Young, Rowan D. (2022). Fluorine‐18 labeling of difluoromethyl and trifluoromethyl groups via monoselective C−F bond activation. Angewandte Chemie International Edition, 61 (49) e202210917, 1-5. doi: 10.1002/anie.202210917 |
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2022 Journal Article Insights into the mechanism of aluminum-catalyzed halodefluorinationCsókás, Dániel, Gupta, Richa, Prasad, Pragati K., Goh, Kelvin K. K. and Young, Rowan D. (2022). Insights into the mechanism of aluminum-catalyzed halodefluorination. Journal of Organic Chemistry, 88 (7), 4397-4404. doi: 10.1021/acs.joc.2c03005 |
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2022 Book Chapter Alkane σ-ComplexesYoung, Rowan D. (2022). Alkane σ-Complexes. Comprehensive Organometallic Chemistry IV. (pp. 502-520) edited by Gerard Parkin, Karsten Meyer and Dermot O’hare. Amsterdam, Netherlands: Elsevier. doi: 10.1016/b978-0-12-820206-7.00001-9 |
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2021 Journal Article Cataloguing a renaissance in late transition metal PCcarbeneP pincer complexesManzano, Richard A. and Young, Rowan D. (2021). Cataloguing a renaissance in late transition metal PCcarbeneP pincer complexes. Coordination Chemistry Reviews, 449 214215, 1-19. doi: 10.1016/j.ccr.2021.214215 |
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2021 Journal Article Nonpalindromic rhodium PCcarbeneP pincer complexes featuring electron-deficient phosphino substituentsTan, Clarence, Tinnermann, Hendrik, Sung, Simon, Kat, Li Heng and Young, Rowan D. (2021). Nonpalindromic rhodium PCcarbeneP pincer complexes featuring electron-deficient phosphino substituents. Organometallics, 40 (24), 4098-4103. doi: 10.1021/acs.organomet.1c00538 |
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2021 Journal Article A review on the halodefluorination of aliphatic fluoridesGupta, Richa and Young, Rowan D. (2021). A review on the halodefluorination of aliphatic fluorides. Synthesis, 54 (07) ss-2021-r0598-r, 1671-1683. doi: 10.1055/a-1684-0121 |
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2021 Journal Article Access to and reactivity of Fe0, Fe−I, FeI, and FeII PCcarbeneP pincer complexesWang, Qingyang, Manzano, Richard A., Tinnermann, Hendrik, Sung, Simon, Leforestier, Baptiste, Krämer, Tobias and Young, Rowan D. (2021). Access to and reactivity of Fe0, Fe−I, FeI, and FeII PCcarbeneP pincer complexes. Angewandte Chemie - International Edition, 60 (33), 18168-18177. doi: 10.1002/anie.202104130 |
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2021 Journal Article Alkali metal adducts of an iron(0) complex and their synergistic FLP-type activation of aliphatic C-X bondsTinnermann, Hendrik, Sung, Simon, Csókás, Dániel, Toh, Zhi Hao, Fraser, Craig and Young, Rowan D. (2021). Alkali metal adducts of an iron(0) complex and their synergistic FLP-type activation of aliphatic C-X bonds. Journal of the American Chemical Society, 143 (28), 10700-10708. doi: 10.1021/jacs.1c04815 |
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2021 Journal Article Access to and Reactivity of Fe<sup>0</sup>, Fe<sup>−I</sup>, Fe<sup>I</sup>, and Fe<sup>II</sup> PC<sub>carbene</sub>P Pincer ComplexesWang, Qingyang, Manzano, Richard A., Tinnermann, Hendrik, Sung, Simon, Leforestier, Baptiste, Krämer, Tobias and Young, Rowan D. (2021). Access to and Reactivity of Fe0, Fe−I, FeI, and FeII PCcarbeneP Pincer Complexes. Angewandte Chemie, 133 (33), 18316-18325. doi: 10.1002/ange.202104130 |
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2021 Journal Article FLP-catalyzed monoselective C-F functionalization in polyfluorocarbons at geminal or distal sitesGupta, Richa, Mandal, Dipendu, Jaiswal, Amit K. and Young, Rowan D. (2021). FLP-catalyzed monoselective C-F functionalization in polyfluorocarbons at geminal or distal sites. Organic Letters, 23 (5), 1915-1920. doi: 10.1021/acs.orglett.1c00346 |
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2020 Journal Article Zero valent iron complexes as base partners in frustrated Lewis pair chemistryTinnermann, Hendrik, Fraser, Craig and Young, Rowan D. (2020). Zero valent iron complexes as base partners in frustrated Lewis pair chemistry. Dalton Transactions, 49 (43), 15184-15189. doi: 10.1039/d0dt03551c |
