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Dr Rowan Young
Dr

Rowan Young

Email: 
Phone: 
+61 7 334 69901

Overview

Background

I obtained my BSc.(Hons) from the University of New South Wales in Australia, then went on to pursue a PhD at the Australian National University’s Research School of Chemistry under the supervision of Professor Anthony Hill. After stints at the University of Oxford and the University of Edinburgh as a research fellow in groups of Andrew Weller and Polly Arnold respectively, I began my independent career at the National University of Singapore in 2014. Since then I have focused on methodology development using pincer complexes and frustrated Lewis pairs to address challenges in small molecule activation, in particular the selective activation of carbon-halide and carbon-chalcogen bonds. My achievements have been recognized with research awards including Asian Chemistry Prizes from Japan and China (2018) and the Thieme Chemistry Journal Award in 2019. In 2022 I was awarded an ARC Future Fellowship, which I assumed at the University of Queensland in mid-2023. The theme of the research for this fellowship is the recycling and repurposing of fluorocarbons through selective activation using organometallic techniques.

Availability

Dr Rowan Young is:
Available for supervision

Research interests

  • Frustrated Lewis Pairs

    Activation chemistry based on the interaction of bulky Lewis acid and bases

  • Transition Metal Pincer Chemistry

    Chemistry concerning synthesis, reactivity and catalysis of PC(carbene)P pincer complexes that feature central alkylidene donors.

  • Carbon-Fluorine Bond Activation and Functionalisation

    The development of new methods to functionalise fluorocarbons, including the selective activation of fluorine-carbon bonds in poly fluorocarbons.

Research impacts

My research focuses on methodology development utilising base metals and frustrated Lewis pairs. I have developed unique ways to selectively activate carbon-fluorine bonds in polyfluorocarbon compounds. My group continues to explore this field allowing direct access to a wide array of second generation fluorinated molecules. We also develop new frustrated Lewis pair systems based on utilising first row transition metal that allow enhanced activation of and catalysis with otherwise inert compounds. Our last avenue of research is in the field of pincer ligand transition metals. We have developed new methods to synthesize alkylidene centred pincer ligands, and we are exploring how these can be exploited in bond activation and catalysis.

Works

Search Professor Rowan Young’s works on UQ eSpace

49 works between 2006 and 2024

1 - 20 of 49 works

2024

Journal Article

Evidence for a kinetic FLP reaction pathway in the activation of benzyl chlorides by alkali metal-phosphine pairs

Csókás, Dániel, Coles, Max, Toh, Zhi Hao and Young, Rowan Drury (2024). Evidence for a kinetic FLP reaction pathway in the activation of benzyl chlorides by alkali metal-phosphine pairs. Dalton Transactions, 53 (35), 14582-14586. doi: 10.1039/d4dt02028f

Evidence for a kinetic FLP reaction pathway in the activation of benzyl chlorides by alkali metal-phosphine pairs

2024

Journal Article

Alternative Si–F Elimination and Fluoride Abstraction Pathways in Selective Monodefluorination of Me<sub>3</sub>SiCF<sub>3</sub> and Me<sub>3</sub>SiCF<sub>2</sub>H

Lye, Kenneth, Mandal, Dipendu and Young, Rowan D. (2024). Alternative Si–F Elimination and Fluoride Abstraction Pathways in Selective Monodefluorination of Me3SiCF3 and Me3SiCF2H. Organometallics, 43 (17), 1922-1928. doi: 10.1021/acs.organomet.4c00279

Alternative Si–F Elimination and Fluoride Abstraction Pathways in Selective Monodefluorination of Me<sub>3</sub>SiCF<sub>3</sub> and Me<sub>3</sub>SiCF<sub>2</sub>H

2024

Journal Article

A review of frustrated Lewis pair enabled monoselective C-F bond activation

Lye, Kenneth and Young, Rowan D. (2024). A review of frustrated Lewis pair enabled monoselective C-F bond activation. Chemical Science, 15 (8), 2712-2724. doi: 10.1039/d3sc06485a

A review of frustrated Lewis pair enabled monoselective C-F bond activation

2023

Journal Article

Stereoselective synthesis of fluoroalkanes via FLP mediated monoselective C─F activation of geminal difluoroalkanes

Csókás, Dániel, Mondal, Bivas, Đokić, Miloš, Gupta, Richa, Lee, Beatrice J. Y. and Young, Rowan D. (2023). Stereoselective synthesis of fluoroalkanes via FLP mediated monoselective C─F activation of geminal difluoroalkanes. Advanced Science, 10 (36) 2305768, 1-5. doi: 10.1002/advs.202305768

Stereoselective synthesis of fluoroalkanes via FLP mediated monoselective C─F activation of geminal difluoroalkanes

2023

Journal Article

Frustrated Lewis pair catalyzed C–F activation of α-trifluoromethylstyrenes

Chan, Chakyu Richard, Mandal, Dipendu and Young, Rowan D. (2023). Frustrated Lewis pair catalyzed C–F activation of α-trifluoromethylstyrenes. Tetrahedron Chem, 8 100050, 1-4. doi: 10.1016/j.tchem.2023.100050

Frustrated Lewis pair catalyzed C–F activation of α-trifluoromethylstyrenes

2023

Journal Article

Synthesis of bimetallic rhodium phosphinine complexes with enhanced catalytic activity towards alkyne hydrosilylation

Tan, Clarence, Tinnermann, Hendrik, Wee, Vanessa, Tan, Shaun, Sung, Simon, Wang, Qingyang and Young, Rowan D. (2023). Synthesis of bimetallic rhodium phosphinine complexes with enhanced catalytic activity towards alkyne hydrosilylation. Journal of Organometallic Chemistry, 986 122617. doi: 10.1016/j.jorganchem.2023.122617

Synthesis of bimetallic rhodium phosphinine complexes with enhanced catalytic activity towards alkyne hydrosilylation

2023

Journal Article

Experimental and computational insights into the mechanism of FLP mediated selective C-F bond activation

Gupta, Richa, Csókás, Dániel, Lye, Kenneth and Young, Rowan D. (2023). Experimental and computational insights into the mechanism of FLP mediated selective C-F bond activation. Chemical Science, 14 (5), 1291-1300. doi: 10.1039/d2sc05632a

Experimental and computational insights into the mechanism of FLP mediated selective C-F bond activation

2022

Journal Article

Gauging the donor strength of iron(0) complexes via their N-heterocyclic carbene gold(i) adducts

Toh, Zhi Hao, Tinnermann, Hendrik, Do, Dinh Cao Huan, Huynh, Han Vinh, Krämer, Tobias and Young, Rowan D. (2022). Gauging the donor strength of iron(0) complexes via their N-heterocyclic carbene gold(i) adducts. Chemical Communications, 58 (93), 12947-12950. doi: 10.1039/d2cc05041b

Gauging the donor strength of iron(0) complexes via their N-heterocyclic carbene gold(i) adducts

2022

Journal Article

Fluorine‐18 labeling of difluoromethyl and trifluoromethyl groups via monoselective C−F bond activation

Khanapur, Shivashankar, Lye, Kenneth, Mandal, Dipendu, Jie Wee, Xin, Robins, Edward G. and Young, Rowan D. (2022). Fluorine‐18 labeling of difluoromethyl and trifluoromethyl groups via monoselective C−F bond activation. Angewandte Chemie International Edition, 61 (49) e202210917, 1-5. doi: 10.1002/anie.202210917

Fluorine‐18 labeling of difluoromethyl and trifluoromethyl groups via monoselective C−F bond activation

2022

Journal Article

Fluorine‐18 Labeling of Difluoromethyl and Trifluoromethyl Groups via Monoselective C−F Bond Activation

Khanapur, Shivashankar, Lye, Kenneth, Mandal, Dipendu, Jie Wee, Xin, Robins, Edward G. and Young, Rowan D. (2022). Fluorine‐18 Labeling of Difluoromethyl and Trifluoromethyl Groups via Monoselective C−F Bond Activation. Angewandte Chemie, 134 (49). doi: 10.1002/ange.202210917

Fluorine‐18 Labeling of Difluoromethyl and Trifluoromethyl Groups via Monoselective C−F Bond Activation

2022

Journal Article

Insights into the mechanism of aluminum-catalyzed halodefluorination

Csókás, Dániel, Gupta, Richa, Prasad, Pragati K., Goh, Kelvin K. K. and Young, Rowan D. (2022). Insights into the mechanism of aluminum-catalyzed halodefluorination. Journal of Organic Chemistry, 88 (7), 4397-4404. doi: 10.1021/acs.joc.2c03005

Insights into the mechanism of aluminum-catalyzed halodefluorination

2022

Book Chapter

Alkane σ-Complexes

Young, Rowan D. (2022). Alkane σ-Complexes. Comprehensive Organometallic Chemistry IV. (pp. 502-520) edited by Gerard Parkin, Karsten Meyer and Dermot O’hare. Amsterdam, Netherlands: Elsevier. doi: 10.1016/b978-0-12-820206-7.00001-9

Alkane σ-Complexes

2021

Journal Article

Cataloguing a renaissance in late transition metal PCcarbeneP pincer complexes

Manzano, Richard A. and Young, Rowan D. (2021). Cataloguing a renaissance in late transition metal PCcarbeneP pincer complexes. Coordination Chemistry Reviews, 449 214215, 1-19. doi: 10.1016/j.ccr.2021.214215

Cataloguing a renaissance in late transition metal PCcarbeneP pincer complexes

2021

Journal Article

Nonpalindromic rhodium PCcarbeneP pincer complexes featuring electron-deficient phosphino substituents

Tan, Clarence, Tinnermann, Hendrik, Sung, Simon, Kat, Li Heng and Young, Rowan D. (2021). Nonpalindromic rhodium PCcarbeneP pincer complexes featuring electron-deficient phosphino substituents. Organometallics, 40 (24), 4098-4103. doi: 10.1021/acs.organomet.1c00538

Nonpalindromic rhodium PCcarbeneP pincer complexes featuring electron-deficient phosphino substituents

2021

Journal Article

A review on the halodefluorination of aliphatic fluorides

Gupta, Richa and Young, Rowan D. (2021). A review on the halodefluorination of aliphatic fluorides. Synthesis, 54 (07) ss-2021-r0598-r, 1671-1683. doi: 10.1055/a-1684-0121

A review on the halodefluorination of aliphatic fluorides

2021

Journal Article

Access to and reactivity of Fe0, Fe−I, FeI, and FeII PCcarbeneP pincer complexes

Wang, Qingyang, Manzano, Richard A., Tinnermann, Hendrik, Sung, Simon, Leforestier, Baptiste, Krämer, Tobias and Young, Rowan D. (2021). Access to and reactivity of Fe0, Fe−I, FeI, and FeII PCcarbeneP pincer complexes. Angewandte Chemie - International Edition, 60 (33), 18168-18177. doi: 10.1002/anie.202104130

Access to and reactivity of Fe0, Fe−I, FeI, and FeII PCcarbeneP pincer complexes

2021

Journal Article

Alkali metal adducts of an iron(0) complex and their synergistic FLP-type activation of aliphatic C-X bonds

Tinnermann, Hendrik, Sung, Simon, Csókás, Dániel, Toh, Zhi Hao, Fraser, Craig and Young, Rowan D. (2021). Alkali metal adducts of an iron(0) complex and their synergistic FLP-type activation of aliphatic C-X bonds. Journal of the American Chemical Society, 143 (28), 10700-10708. doi: 10.1021/jacs.1c04815

Alkali metal adducts of an iron(0) complex and their synergistic FLP-type activation of aliphatic C-X bonds

2021

Journal Article

Access to and Reactivity of Fe<sup>0</sup>, Fe<sup>−I</sup>, Fe<sup>I</sup>, and Fe<sup>II</sup> PC<sub>carbene</sub>P Pincer Complexes

Wang, Qingyang, Manzano, Richard A., Tinnermann, Hendrik, Sung, Simon, Leforestier, Baptiste, Krämer, Tobias and Young, Rowan D. (2021). Access to and Reactivity of Fe0, Fe−I, FeI, and FeII PCcarbeneP Pincer Complexes. Angewandte Chemie, 133 (33), 18316-18325. doi: 10.1002/ange.202104130

Access to and Reactivity of Fe<sup>0</sup>, Fe<sup>−I</sup>, Fe<sup>I</sup>, and Fe<sup>II</sup> PC<sub>carbene</sub>P Pincer Complexes

2021

Journal Article

FLP-catalyzed monoselective C-F functionalization in polyfluorocarbons at geminal or distal sites

Gupta, Richa, Mandal, Dipendu, Jaiswal, Amit K. and Young, Rowan D. (2021). FLP-catalyzed monoselective C-F functionalization in polyfluorocarbons at geminal or distal sites. Organic Letters, 23 (5), 1915-1920. doi: 10.1021/acs.orglett.1c00346

FLP-catalyzed monoselective C-F functionalization in polyfluorocarbons at geminal or distal sites

2020

Journal Article

Zero valent iron complexes as base partners in frustrated Lewis pair chemistry

Tinnermann, Hendrik, Fraser, Craig and Young, Rowan D. (2020). Zero valent iron complexes as base partners in frustrated Lewis pair chemistry. Dalton Transactions, 49 (43), 15184-15189. doi: 10.1039/d0dt03551c

Zero valent iron complexes as base partners in frustrated Lewis pair chemistry

Funding

Current funding

  • 2023 - 2027
    A top-down approach to synthesising high-value fluorocarbons
    ARC Future Fellowships
    Open grant

Supervision

Availability

Dr Rowan Young is:
Available for supervision

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Available projects

  • Fluorocarbon activation using organometallic chemistry

    Fundamental challenges in transforming synthetic and energy-based materials are increasingly being met using inorganic chemical solutions.

    This project focuses on C-F bond activation and functionalization using main group organometallic catalysts. The project will involve advanced organometallic syntheses as well as organic synthesis to demonstrate catalyst competency.

    The successful candidate will also gain a thorough knowledge of fluorocarbon chemistry. Training will be extensive and cover inorganic, organometallic and organic synthetic techniques in synthesis and analytical characterisation.

Media

Enquiries

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