Overview
Background
I obtained my BSc.(Hons) from the University of New South Wales in Australia, then went on to pursue a PhD at the Australian National University’s Research School of Chemistry under the supervision of Professor Anthony Hill. After stints at the University of Oxford and the University of Edinburgh as a research fellow in groups of Andrew Weller and Polly Arnold respectively, I began my independent career at the National University of Singapore in 2014. Since then I have focused on methodology development using pincer complexes and frustrated Lewis pairs to address challenges in small molecule activation, in particular the selective activation of carbon-halide and carbon-chalcogen bonds. My achievements have been recognized with research awards including Asian Chemistry Prizes from Japan and China (2018) and the Thieme Chemistry Journal Award in 2019. In 2022 I was awarded an ARC Future Fellowship, which I assumed at the University of Queensland in mid-2023. The theme of the research for this fellowship is the recycling and repurposing of fluorocarbons through selective activation using organometallic techniques.
Availability
- Dr Rowan Young is:
- Available for supervision
Fields of research
Research interests
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Frustrated Lewis Pairs
Activation chemistry based on the interaction of bulky Lewis acid and bases
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Transition Metal Pincer Chemistry
Chemistry concerning synthesis, reactivity and catalysis of PC(carbene)P pincer complexes that feature central alkylidene donors.
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Carbon-Fluorine Bond Activation and Functionalisation
The development of new methods to functionalise fluorocarbons, including the selective activation of fluorine-carbon bonds in poly fluorocarbons.
Research impacts
My research focuses on methodology development utilising base metals and frustrated Lewis pairs. I have developed unique ways to selectively activate carbon-fluorine bonds in polyfluorocarbon compounds. My group continues to explore this field allowing direct access to a wide array of second generation fluorinated molecules. We also develop new frustrated Lewis pair systems based on utilising first row transition metal that allow enhanced activation of and catalysis with otherwise inert compounds. Our last avenue of research is in the field of pincer ligand transition metals. We have developed new methods to synthesize alkylidene centred pincer ligands, and we are exploring how these can be exploited in bond activation and catalysis.
Works
Search Professor Rowan Young’s works on UQ eSpace
2024
Journal Article
Evidence for a kinetic FLP reaction pathway in the activation of benzyl chlorides by alkali metal-phosphine pairs
Csókás, Dániel, Coles, Max, Toh, Zhi Hao and Young, Rowan Drury (2024). Evidence for a kinetic FLP reaction pathway in the activation of benzyl chlorides by alkali metal-phosphine pairs. Dalton Transactions, 53 (35), 14582-14586. doi: 10.1039/d4dt02028f
2024
Journal Article
Alternative Si–F Elimination and Fluoride Abstraction Pathways in Selective Monodefluorination of Me<sub>3</sub>SiCF<sub>3</sub> and Me<sub>3</sub>SiCF<sub>2</sub>H
Lye, Kenneth, Mandal, Dipendu and Young, Rowan D. (2024). Alternative Si–F Elimination and Fluoride Abstraction Pathways in Selective Monodefluorination of Me3SiCF3 and Me3SiCF2H. Organometallics, 43 (17), 1922-1928. doi: 10.1021/acs.organomet.4c00279
2024
Journal Article
A review of frustrated Lewis pair enabled monoselective C-F bond activation
Lye, Kenneth and Young, Rowan D. (2024). A review of frustrated Lewis pair enabled monoselective C-F bond activation. Chemical Science, 15 (8), 2712-2724. doi: 10.1039/d3sc06485a
2023
Journal Article
Stereoselective synthesis of fluoroalkanes via FLP mediated monoselective C─F activation of geminal difluoroalkanes
Csókás, Dániel, Mondal, Bivas, Đokić, Miloš, Gupta, Richa, Lee, Beatrice J. Y. and Young, Rowan D. (2023). Stereoselective synthesis of fluoroalkanes via FLP mediated monoselective C─F activation of geminal difluoroalkanes. Advanced Science, 10 (36) 2305768, 1-5. doi: 10.1002/advs.202305768
2023
Journal Article
Frustrated Lewis pair catalyzed C–F activation of α-trifluoromethylstyrenes
Chan, Chakyu Richard, Mandal, Dipendu and Young, Rowan D. (2023). Frustrated Lewis pair catalyzed C–F activation of α-trifluoromethylstyrenes. Tetrahedron Chem, 8 100050, 1-4. doi: 10.1016/j.tchem.2023.100050
2023
Journal Article
Synthesis of bimetallic rhodium phosphinine complexes with enhanced catalytic activity towards alkyne hydrosilylation
Tan, Clarence, Tinnermann, Hendrik, Wee, Vanessa, Tan, Shaun, Sung, Simon, Wang, Qingyang and Young, Rowan D. (2023). Synthesis of bimetallic rhodium phosphinine complexes with enhanced catalytic activity towards alkyne hydrosilylation. Journal of Organometallic Chemistry, 986 122617. doi: 10.1016/j.jorganchem.2023.122617
2023
Journal Article
Experimental and computational insights into the mechanism of FLP mediated selective C-F bond activation
Gupta, Richa, Csókás, Dániel, Lye, Kenneth and Young, Rowan D. (2023). Experimental and computational insights into the mechanism of FLP mediated selective C-F bond activation. Chemical Science, 14 (5), 1291-1300. doi: 10.1039/d2sc05632a
2022
Journal Article
Gauging the donor strength of iron(0) complexes via their N-heterocyclic carbene gold(i) adducts
Toh, Zhi Hao, Tinnermann, Hendrik, Do, Dinh Cao Huan, Huynh, Han Vinh, Krämer, Tobias and Young, Rowan D. (2022). Gauging the donor strength of iron(0) complexes via their N-heterocyclic carbene gold(i) adducts. Chemical Communications, 58 (93), 12947-12950. doi: 10.1039/d2cc05041b
2022
Journal Article
Fluorine‐18 labeling of difluoromethyl and trifluoromethyl groups via monoselective C−F bond activation
Khanapur, Shivashankar, Lye, Kenneth, Mandal, Dipendu, Jie Wee, Xin, Robins, Edward G. and Young, Rowan D. (2022). Fluorine‐18 labeling of difluoromethyl and trifluoromethyl groups via monoselective C−F bond activation. Angewandte Chemie International Edition, 61 (49) e202210917, 1-5. doi: 10.1002/anie.202210917
2022
Journal Article
Fluorine‐18 Labeling of Difluoromethyl and Trifluoromethyl Groups via Monoselective C−F Bond Activation
Khanapur, Shivashankar, Lye, Kenneth, Mandal, Dipendu, Jie Wee, Xin, Robins, Edward G. and Young, Rowan D. (2022). Fluorine‐18 Labeling of Difluoromethyl and Trifluoromethyl Groups via Monoselective C−F Bond Activation. Angewandte Chemie, 134 (49). doi: 10.1002/ange.202210917
2022
Journal Article
Insights into the mechanism of aluminum-catalyzed halodefluorination
Csókás, Dániel, Gupta, Richa, Prasad, Pragati K., Goh, Kelvin K. K. and Young, Rowan D. (2022). Insights into the mechanism of aluminum-catalyzed halodefluorination. Journal of Organic Chemistry, 88 (7), 4397-4404. doi: 10.1021/acs.joc.2c03005
2022
Book Chapter
Alkane σ-Complexes
Young, Rowan D. (2022). Alkane σ-Complexes. Comprehensive Organometallic Chemistry IV. (pp. 502-520) edited by Gerard Parkin, Karsten Meyer and Dermot O’hare. Amsterdam, Netherlands: Elsevier. doi: 10.1016/b978-0-12-820206-7.00001-9
2021
Journal Article
Cataloguing a renaissance in late transition metal PCcarbeneP pincer complexes
Manzano, Richard A. and Young, Rowan D. (2021). Cataloguing a renaissance in late transition metal PCcarbeneP pincer complexes. Coordination Chemistry Reviews, 449 214215, 1-19. doi: 10.1016/j.ccr.2021.214215
2021
Journal Article
Nonpalindromic rhodium PCcarbeneP pincer complexes featuring electron-deficient phosphino substituents
Tan, Clarence, Tinnermann, Hendrik, Sung, Simon, Kat, Li Heng and Young, Rowan D. (2021). Nonpalindromic rhodium PCcarbeneP pincer complexes featuring electron-deficient phosphino substituents. Organometallics, 40 (24), 4098-4103. doi: 10.1021/acs.organomet.1c00538
2021
Journal Article
A review on the halodefluorination of aliphatic fluorides
Gupta, Richa and Young, Rowan D. (2021). A review on the halodefluorination of aliphatic fluorides. Synthesis, 54 (07) ss-2021-r0598-r, 1671-1683. doi: 10.1055/a-1684-0121
2021
Journal Article
Access to and reactivity of Fe0, Fe−I, FeI, and FeII PCcarbeneP pincer complexes
Wang, Qingyang, Manzano, Richard A., Tinnermann, Hendrik, Sung, Simon, Leforestier, Baptiste, Krämer, Tobias and Young, Rowan D. (2021). Access to and reactivity of Fe0, Fe−I, FeI, and FeII PCcarbeneP pincer complexes. Angewandte Chemie - International Edition, 60 (33), 18168-18177. doi: 10.1002/anie.202104130
2021
Journal Article
Alkali metal adducts of an iron(0) complex and their synergistic FLP-type activation of aliphatic C-X bonds
Tinnermann, Hendrik, Sung, Simon, Csókás, Dániel, Toh, Zhi Hao, Fraser, Craig and Young, Rowan D. (2021). Alkali metal adducts of an iron(0) complex and their synergistic FLP-type activation of aliphatic C-X bonds. Journal of the American Chemical Society, 143 (28), 10700-10708. doi: 10.1021/jacs.1c04815
2021
Journal Article
Access to and Reactivity of Fe<sup>0</sup>, Fe<sup>−I</sup>, Fe<sup>I</sup>, and Fe<sup>II</sup> PC<sub>carbene</sub>P Pincer Complexes
Wang, Qingyang, Manzano, Richard A., Tinnermann, Hendrik, Sung, Simon, Leforestier, Baptiste, Krämer, Tobias and Young, Rowan D. (2021). Access to and Reactivity of Fe0, Fe−I, FeI, and FeII PCcarbeneP Pincer Complexes. Angewandte Chemie, 133 (33), 18316-18325. doi: 10.1002/ange.202104130
2021
Journal Article
FLP-catalyzed monoselective C-F functionalization in polyfluorocarbons at geminal or distal sites
Gupta, Richa, Mandal, Dipendu, Jaiswal, Amit K. and Young, Rowan D. (2021). FLP-catalyzed monoselective C-F functionalization in polyfluorocarbons at geminal or distal sites. Organic Letters, 23 (5), 1915-1920. doi: 10.1021/acs.orglett.1c00346
2020
Journal Article
Zero valent iron complexes as base partners in frustrated Lewis pair chemistry
Tinnermann, Hendrik, Fraser, Craig and Young, Rowan D. (2020). Zero valent iron complexes as base partners in frustrated Lewis pair chemistry. Dalton Transactions, 49 (43), 15184-15189. doi: 10.1039/d0dt03551c
Funding
Current funding
Supervision
Availability
- Dr Rowan Young is:
- Available for supervision
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Available projects
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Fluorocarbon activation using organometallic chemistry
Fundamental challenges in transforming synthetic and energy-based materials are increasingly being met using inorganic chemical solutions.
This project focuses on C-F bond activation and functionalization using main group organometallic catalysts. The project will involve advanced organometallic syntheses as well as organic synthesis to demonstrate catalyst competency.
The successful candidate will also gain a thorough knowledge of fluorocarbon chemistry. Training will be extensive and cover inorganic, organometallic and organic synthetic techniques in synthesis and analytical characterisation.
Media
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