
Overview
Background
Educated at the University of Copenhagen, Denmark, and the Australian National University, Canberra. Career at the Université de Lausanne, Switzerland, and the Universität Marburg, Germany. Professor and Chair of Organic Chemistry and Head of the Organic Chemistry Section, The University of Queensland from 1985. Emeritus professor from 2008. Chair of the National Committee for Chemistry of the Australian Academy of Science 2009-2014. Editor-in-Chief, Australian Journal of Chemistry 2008-15. Editor, Journal of Analytical and Applied Pyrolysis (Elsevier, IF 3.65) 2016-. Visiting Professor Université de Pau, France, 2011-19; Visiting Professor University of Kuwait 2014-18; Visiting Professor / Special Appointed Professor Hiroshima University 2014-18. Fellow of the Australian Academy of Science. Centenary Medal of the Australian Commonwealth 2003 for research in organic and physical chemistry. David Craig Medal of the Academy of Science 2014 for research in chemistry. JSPS Fellowship (Japan) 2014. Honorary doctorate, University of Pau, France, 2014. A.J. Birch Medal of the Royal Australian Chemical Institute (RACI) for ecellence in research in organic chemistry, 2014. Leighton Medal of the RACI 2018.
Research on Unusual Molecules and Reactive Intermediates: Synthesis and Reaction Mechanism. Heterocyclic chemistry. Pyrolysis reactions. Photochemistry
Research in the Wentrup group is concerned with the discovery of novel types of molecules with new and unusual bonding patterns. Such molecules are mostly highly reactive, and special methods are required both for their generation and for their detection. The group has developed these methods over many years and acquired world-class equipment for these purposes, including flash vacuum thermolysis apparatus, cryostats for matrix isolation of reaction products at cryogenic temperatures (down to 7 K), matrix and solution photochemistry equipment, infrared, UV and mass spectrometers, as well as modern computational facilities.
This research has resulted in the synthesis and characterization of many novel compounds, including extended cumulenes of the types RN=C=C=C=X, which themselves are used in the synthesis of many novel types of molecules, some of them of potential pharmaceutical interest (quinolone antibiotics; diazepines).
The research group has a world reputation in the field of carbene and nitrene chemistry, involving reactive intermediates with sextet carbon or nitrogen. These species are also very useful in synthesis, for example in the preparation of diazepines and diazepinones, a family of pharmaceutically interesting compounds. Numerous mechanistic studies and synthetic applications of ketenes have been carried out in our group.
Active collaborations are ongoing with scientists in Australia (UQ and CSIRO), China (Suzhou), France (Pau), Germany (Oldenburg), Japan (Hiroshima), Spain (Donostia - San Sebastian), and Portugal (Coimbra).
Availability
- Emeritus Professor Curt Wentrup is:
- Not available for supervision
- Media expert
Fields of research
Qualifications
- Doctor of Philosophy, Australian National University
- Doctor of Philosophy of Science (Advanced), University of Copenhagen
- Doctoral Diploma, Institution to be confirmed
- Australian Academy of Science, Australian Academy of Science
- Royal Australian Chemical Institute, Royal Australian Chemical Institute
Research interests
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Organic, physical, and historical chemistry
Reactive intermediates, pyrolysis, photochemistry, reaction mechanism. History of science.
Research impacts
This research leads to the development of new pharmaceuticals, e.g. new antibiotics (quinolones and naphthyridones) and new leads towards a treatment for scizophrenia (diazepine molecules).
Chemical industry has used our pyrolysis techniques in specialized manufacturing processes.
Our analytical/spectroscopic work has led to cooperation with chemical and energy firms and agencies involved in forensic science, and our research has generated collaborations with many scientists at universities in Australia, Austria, Belgium, China, Denmark, France, Germany, Hungary, Japan, Portugal, Singapore, Switzerland, and USA.
Works
Search Professor Curt Wentrup’s works on UQ eSpace
1973
Journal Article
One-Step Syntheses of Fulvene and Fulvenallene - Thermolysis of Alpha-Coumaranone, Phthalide, and Benzocyclopropene
Wentrup, C and Muller, P (1973). One-Step Syntheses of Fulvene and Fulvenallene - Thermolysis of Alpha-Coumaranone, Phthalide, and Benzocyclopropene. Tetrahedron Letters (31), 2915-2918.
1972
Journal Article
HETARYLNITRENES .5. REACTIONS OF TETRAZOLOPYRAZINE RING CONTRACTION OF NITRENODIAZINES IN SOLUTION
WENTRUP, C (1972). HETARYLNITRENES .5. REACTIONS OF TETRAZOLOPYRAZINE RING CONTRACTION OF NITRENODIAZINES IN SOLUTION. Helvetica Chimica Acta, 55 (2), 565-&. doi: 10.1002/hlca.19720550228
1972
Journal Article
Ring Expansion - Ring Contraction Dichotomy in Aromatic Nitrene and Carbene Reactions .2. Hetarylnitrenes
Wentrup, C, Thetaz, C and Gleiter, R (1972). Ring Expansion - Ring Contraction Dichotomy in Aromatic Nitrene and Carbene Reactions .2. Hetarylnitrenes. Helvetica Chimica Acta, 55 (7), 2633-&. doi: 10.1002/hlca.19720550742
1972
Journal Article
RELATIONSHIP BETWEEN C6H5N ISOMERS - PYROLYSIS OF ISATINS
WENTRUP, C (1972). RELATIONSHIP BETWEEN C6H5N ISOMERS - PYROLYSIS OF ISATINS. Helvetica Chimica Acta, 55 (5), 1613-&. doi: 10.1002/hlca.19720550523
1972
Journal Article
CORRECTION
WENTRUP, C (1972). CORRECTION. Helvetica Chimica Acta, 55 (8), 3066-&.
1971
Journal Article
Hetarylnitrenes .3. Thermal Rearrangements On C4H3N3 Energy Surface - Role of 1-Substituted Pyrazoles
Wentrup, C and Crow, WD (1971). Hetarylnitrenes .3. Thermal Rearrangements On C4H3N3 Energy Surface - Role of 1-Substituted Pyrazoles. Tetrahedron, 27 (2), 361-&. doi: 10.1016/S0040-4020(01)90705-7
1971
Journal Article
HETARYLNITRENES .4. ANNELATED NITRENOAZINES
WENTRUP, C (1971). HETARYLNITRENES .4. ANNELATED NITRENOAZINES. Tetrahedron, 27 (2), 367-&. doi: 10.1016/S0040-4020(01)90706-9
1971
Journal Article
CORRECTION
WENTRUP, C (1971). CORRECTION. Tetrahedron, 27 (5), 880-&. doi: 10.1016/S0040-4020(01)92486-X
1971
Journal Article
MECHANISM OF THERMAL AND PHOTOLYTIC CYCLIZATION OF DIPHENYLAMINES TO CARBAZOLES
WENTRUP, C and GAUGAZ, M (1971). MECHANISM OF THERMAL AND PHOTOLYTIC CYCLIZATION OF DIPHENYLAMINES TO CARBAZOLES. Helvetica Chimica Acta, 54 (7), 2108-&. doi: 10.1002/hlca.19710540743
1971
Journal Article
NITRENES DERIVED FROM POLYMETHYLENETETRAZOLES
WENTRUP, C (1971). NITRENES DERIVED FROM POLYMETHYLENETETRAZOLES. Tetrahedron, 27 (6), 1281-&. doi: 10.1016/S0040-4020(01)90877-4
1971
Journal Article
CORRECTION
WENTRUP, C (1971). CORRECTION. Tetrahedron, 27 (5), 880-&. doi: 10.1016/S0040-4020(01)92485-8
1971
Journal Article
PHENYLNITRENE FROM PHENYLSULPHINYLAMINE - CORRELATION OF THERMOLYSIS WITH ELECTRON IMPACT
WENTRUP, C (1971). PHENYLNITRENE FROM PHENYLSULPHINYLAMINE - CORRELATION OF THERMOLYSIS WITH ELECTRON IMPACT. Tetrahedron, 27 (5), 1027-&. doi: 10.1016/S0040-4020(01)92504-9
1971
Journal Article
PYROLYSIS OF N-SULFINYLANILINE MICROWAVE DETECTION OF SO MOLECULE .1.
SAITO, S and WENTRUP, C (1971). PYROLYSIS OF N-SULFINYLANILINE MICROWAVE DETECTION OF SO MOLECULE .1.. Helvetica Chimica Acta, 54 (1), 273-&. doi: 10.1002/hlca.19710540123
1970
Journal Article
O-PROTONATION OF ALPHA-DIAZOKETONES IN SUPER-STRONG ACIDS
WENTRUP, C and DAHN, H (1970). O-PROTONATION OF ALPHA-DIAZOKETONES IN SUPER-STRONG ACIDS. Helvetica Chimica Acta, 53 (7), 1637-&. doi: 10.1002/hlca.19700530711
1970
Journal Article
HETARYLNITRENES .1. RING CONTRACTION AND FRAGMENTATION IN NITRENODIAZINES
WENTRUP, C and CROW, WD (1970). HETARYLNITRENES .1. RING CONTRACTION AND FRAGMENTATION IN NITRENODIAZINES. Tetrahedron, 26 (20), 4915-&. doi: 10.1016/S0040-4020(01)93143-6
1970
Journal Article
PYROLYSIS OF 1(H)-TRIAZOLOARENES RING CONTRACTION TO 5-RING NITRILES, AND CN-GROUP MIGRATION
WENTRUP, C and CROW, WD (1970). PYROLYSIS OF 1(H)-TRIAZOLOARENES RING CONTRACTION TO 5-RING NITRILES, AND CN-GROUP MIGRATION. Tetrahedron, 26 (16), 3965-&. doi: 10.1016/S0040-4020(01)93037-6
1970
Journal Article
Thermal Interconversion of Phenylcarbene and Tropylidene - Preliminary Communication
Wentrup, C and Wilczek, K (1970). Thermal Interconversion of Phenylcarbene and Tropylidene - Preliminary Communication. Helvetica Chimica Acta, 53 (6), 1459-&. doi: 10.1002/hlca.19700530628
1970
Journal Article
STRUCTURES OF CYANOCYCLOPENTADIENES AND RELATED COMPOUNDS
WENTRUP, C and CROW, WD (1970). STRUCTURES OF CYANOCYCLOPENTADIENES AND RELATED COMPOUNDS. Tetrahedron, 26 (18), 4375-&. doi: 10.1016/S0040-4020(01)93084-4
1970
Journal Article
HETARYLNITRENES .2. AZIDO/TETRAZOLOAZINE TAUTOMERISATION, AND EVIDENCE FOR NITRENE FORMATION IN GAS-PHASE
WENTRUP, C (1970). HETARYLNITRENES .2. AZIDO/TETRAZOLOAZINE TAUTOMERISATION, AND EVIDENCE FOR NITRENE FORMATION IN GAS-PHASE. Tetrahedron, 26 (21), 4969-&. doi: 10.1016/S0040-4020(01)93149-7
1969
Journal Article
AROMATIC NITRENE-CARBENE INTERCONVERSION
WENTRUP, C (1969). AROMATIC NITRENE-CARBENE INTERCONVERSION. Journal of the Chemical Society D-Chemical Communications (23), 1386-&. doi: 10.1039/c29690001386
Funding
Supervision
Availability
- Emeritus Professor Curt Wentrup is:
- Not available for supervision
Supervision history
Completed supervision
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2006
Doctor Philosophy
SYNTHESES AND REACTIONS OF IMINOPROPADIENONES, SYDNONES AND OXAZINONES
Principal Advisor
Other advisors: Professor Craig Williams
-
2002
Doctor Philosophy
HETEROCYCLIC SYNTHESIS BASED ON IMINOPROPADIENONES
Principal Advisor
-
2002
Doctor Philosophy
SYNTHESIS AND CHARACTERISATION OF 1,3- and 1,4- DIAZEPINES AND DERIVATIVES
Principal Advisor
-
Doctor Philosophy
NITRENES REARRANGEMENTS: FORMATION OF REACTIVE INTERMEDIATES AND UNUSUAL MOLECULES
Principal Advisor
Other advisors: Professor Craig Williams
Media
Enquiries
Contact Emeritus Professor Curt Wentrup directly for media enquiries about:
- Organic reaction mechanisms
- Photochemistry
- Pyrolysis
- Reactive intermediates
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