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Emeritus Professor Curt Wentrup
Emeritus Professor

Curt Wentrup

Email: 
Phone: 
+61 7 336 53817

Overview

Background

Educated at the University of Copenhagen, Denmark, and the Australian National University, Canberra. Career at the Université de Lausanne, Switzerland, and the Universität Marburg, Germany. Professor and Chair of Organic Chemistry and Head of the Organic Chemistry Section, The University of Queensland from 1985. Emeritus professor from 2008. Chair of the National Committee for Chemistry of the Australian Academy of Science 2009-2014. Editor-in-Chief, Australian Journal of Chemistry 2008-15. Editor, Journal of Analytical and Applied Pyrolysis (Elsevier, IF 3.65) 2016-. Visiting Professor Université de Pau, France, 2011-19; Visiting Professor University of Kuwait 2014-18; Visiting Professor / Special Appointed Professor Hiroshima University 2014-18. Fellow of the Australian Academy of Science. Centenary Medal of the Australian Commonwealth 2003 for research in organic and physical chemistry. David Craig Medal of the Academy of Science 2014 for research in chemistry. JSPS Fellowship (Japan) 2014. Honorary doctorate, University of Pau, France, 2014. A.J. Birch Medal of the Royal Australian Chemical Institute (RACI) for ecellence in research in organic chemistry, 2014. Leighton Medal of the RACI 2018.

Research on Unusual Molecules and Reactive Intermediates: Synthesis and Reaction Mechanism. Heterocyclic chemistry. Pyrolysis reactions. Photochemistry

Research in the Wentrup group is concerned with the discovery of novel types of molecules with new and unusual bonding patterns. Such molecules are mostly highly reactive, and special methods are required both for their generation and for their detection. The group has developed these methods over many years and acquired world-class equipment for these purposes, including flash vacuum thermolysis apparatus, cryostats for matrix isolation of reaction products at cryogenic temperatures (down to 7 K), matrix and solution photochemistry equipment, infrared, UV and mass spectrometers, as well as modern computational facilities.

This research has resulted in the synthesis and characterization of many novel compounds, including extended cumulenes of the types RN=C=C=C=X, which themselves are used in the synthesis of many novel types of molecules, some of them of potential pharmaceutical interest (quinolone antibiotics; diazepines).

The research group has a world reputation in the field of carbene and nitrene chemistry, involving reactive intermediates with sextet carbon or nitrogen. These species are also very useful in synthesis, for example in the preparation of diazepines and diazepinones, a family of pharmaceutically interesting compounds. Numerous mechanistic studies and synthetic applications of ketenes have been carried out in our group.

Active collaborations are ongoing with scientists in Australia (UQ and CSIRO), China (Suzhou), France (Pau), Germany (Oldenburg), Japan (Hiroshima), Spain (Donostia - San Sebastian), and Portugal (Coimbra).

Availability

Emeritus Professor Curt Wentrup is:
Not available for supervision
Media expert

Qualifications

  • Doctor of Philosophy, Australian National University
  • Doctor of Philosophy of Science (Advanced), University of Copenhagen
  • Doctoral Diploma, unknown
  • Australian Academy of Science, Australian Academy of Science
  • Royal Australian Chemical Institute, Royal Australian Chemical Institute

Research interests

  • Organic, physical, and historical chemistry

    Reactive intermediates, pyrolysis, photochemistry, reaction mechanism. History of science.

Research impacts

This research leads to the development of new pharmaceuticals, e.g. new antibiotics (quinolones and naphthyridones) and new leads towards a treatment for scizophrenia (diazepine molecules).

Chemical industry has used our pyrolysis techniques in specialized manufacturing processes.

Our analytical/spectroscopic work has led to cooperation with chemical and energy firms and agencies involved in forensic science, and our research has generated collaborations with many scientists at universities in Australia, Austria, Belgium, China, Denmark, France, Germany, Hungary, Japan, Portugal, Singapore, Switzerland, and USA.

Works

Search Professor Curt Wentrup’s works on UQ eSpace

432 works between 1966 and 2024

341 - 360 of 432 works

1986

Journal Article

Nitrile Ylides and Azirines: Gas‐Phase Generation from 2,3‐Dihydro‐1,4,λ5‐oxazaphospholes and Matrix Isolation

Wentrup C., Fischer S., Berstermann H.-M., Kuzaj M., Luerssen H. and Burger K. (1986). Nitrile Ylides and Azirines: Gas‐Phase Generation from 2,3‐Dihydro‐1,4,λ5‐oxazaphospholes and Matrix Isolation. Angewandte Chemie-International Edition in English, 25 (1), 85-86. doi: 10.1002/anie.198600851

Nitrile Ylides and Azirines: Gas‐Phase Generation from 2,3‐Dihydro‐1,4,λ5‐oxazaphospholes and Matrix Isolation

1985

Journal Article

GEOMETRICAL-ISOMERS OF A BRIDGEHEAD IMINE - (E)-2-AZABICYCLO[3.2.1]OCT-1-ENE AND (Z)-2-AZABICYCLO[3.2.1]OCT-1-ENE AND 2-AZABICYCLO[2.2.2]OCT-1-ENE

RADZISZEWSKI, JG, DOWNING, JW, WENTRUP, C, KASZYNSKI, P, JAWDOSIUK, M, KOVACIC, P and MICHL, J (1985). GEOMETRICAL-ISOMERS OF A BRIDGEHEAD IMINE - (E)-2-AZABICYCLO[3.2.1]OCT-1-ENE AND (Z)-2-AZABICYCLO[3.2.1]OCT-1-ENE AND 2-AZABICYCLO[2.2.2]OCT-1-ENE. Journal of the American Chemical Society, 107 (9), 2799-2801. doi: 10.1021/ja00295a038

GEOMETRICAL-ISOMERS OF A BRIDGEHEAD IMINE - (E)-2-AZABICYCLO[3.2.1]OCT-1-ENE AND (Z)-2-AZABICYCLO[3.2.1]OCT-1-ENE AND 2-AZABICYCLO[2.2.2]OCT-1-ENE

1985

Journal Article

MECHANISM OF FRAGMENTATION OF ALKYLIDENE-MELDRUMS ACIDS - CARBOXYKETENE, VINYLKETENE, AND METHYLENEKETENE INTERMEDIATES FROM 5-CYCLOPENTYLIDENE-2,2-DIMETHYL-1,3-DIOXANE-4,6-DIONE

WENTRUP, C, GROSS, G, BERSTERMANN, HM and LORENCAK, P (1985). MECHANISM OF FRAGMENTATION OF ALKYLIDENE-MELDRUMS ACIDS - CARBOXYKETENE, VINYLKETENE, AND METHYLENEKETENE INTERMEDIATES FROM 5-CYCLOPENTYLIDENE-2,2-DIMETHYL-1,3-DIOXANE-4,6-DIONE. Journal of Organic Chemistry, 50 (16), 2877-2881. doi: 10.1021/jo00216a015

MECHANISM OF FRAGMENTATION OF ALKYLIDENE-MELDRUMS ACIDS - CARBOXYKETENE, VINYLKETENE, AND METHYLENEKETENE INTERMEDIATES FROM 5-CYCLOPENTYLIDENE-2,2-DIMETHYL-1,3-DIOXANE-4,6-DIONE

1985

Journal Article

NITRILE IMINES - THERMAL GENERATION, DIRECT OBSERVATION, AND SUBSEQUENT TRAPPING

WENTRUP, C, FISCHER, S, MAQUESTIAU, A and FLAMMANG, R (1985). NITRILE IMINES - THERMAL GENERATION, DIRECT OBSERVATION, AND SUBSEQUENT TRAPPING. Angewandte Chemie-International Edition in English, 24 (1), 56-57. doi: 10.1002/anie.198500561

NITRILE IMINES - THERMAL GENERATION, DIRECT OBSERVATION, AND SUBSEQUENT TRAPPING

1985

Journal Article

4-Alkylideneisoxazol-5-Ones - Synthesis, Tautomerism, and Rearrangement to Pyrroles

Wollweber, HJ and Wentrup, C (1985). 4-Alkylideneisoxazol-5-Ones - Synthesis, Tautomerism, and Rearrangement to Pyrroles. Journal of Organic Chemistry, 50 (12), 2041-2047. doi: 10.1021/jo00212a007

4-Alkylideneisoxazol-5-Ones - Synthesis, Tautomerism, and Rearrangement to Pyrroles

1985

Conference Publication

2-Azaadamant-1-Ene and Other Matrix-Isolated Strained Bridgehead Imines - Bridgehead Syn-Anti Isomerism

Michl, J, Radziszewski, JG, Downing, JW, Wentrup, C, Kaszynski, P, Jawdosiuk, M and Kovacic, P (1985). 2-Azaadamant-1-Ene and Other Matrix-Isolated Strained Bridgehead Imines - Bridgehead Syn-Anti Isomerism. WASHINGTON: AMER CHEMICAL SOC.

2-Azaadamant-1-Ene and Other Matrix-Isolated Strained Bridgehead Imines - Bridgehead Syn-Anti Isomerism

1985

Journal Article

FORCE FIELD-SCF CALCULATIONS ON CYCLOPROPENE INTERMEDIATES IN CARBENE REARRANGEMENTS - COMPARISON WITH EXPERIMENT

WENTRUP, C, MAYOR, C, BECKER, J and LINDNER, HJ (1985). FORCE FIELD-SCF CALCULATIONS ON CYCLOPROPENE INTERMEDIATES IN CARBENE REARRANGEMENTS - COMPARISON WITH EXPERIMENT. Tetrahedron, 41 (8), 1601-1612. doi: 10.1016/S0040-4020(01)96400-2

FORCE FIELD-SCF CALCULATIONS ON CYCLOPROPENE INTERMEDIATES IN CARBENE REARRANGEMENTS - COMPARISON WITH EXPERIMENT

1984

Journal Article

SYNTHESIS OF 1-AZAAZULENE AND BENZ[A]AZULENE BY CARBENE REARRANGEMENT

WENTRUP, C and BECKER, J (1984). SYNTHESIS OF 1-AZAAZULENE AND BENZ[A]AZULENE BY CARBENE REARRANGEMENT. Journal of the American Chemical Society, 106 (12), 3705-3706. doi: 10.1021/ja00324a070

SYNTHESIS OF 1-AZAAZULENE AND BENZ[A]AZULENE BY CARBENE REARRANGEMENT

1984

Journal Article

A NOVEL KETOKETENE KETOKETENE REARRANGEMENT

WENTRUP, C and NETSCH, KP (1984). A NOVEL KETOKETENE KETOKETENE REARRANGEMENT. Angewandte Chemie-International Edition in English, 23 (10), 802-802. doi: 10.1002/anie.198408021

A NOVEL KETOKETENE KETOKETENE REARRANGEMENT

1984

Journal Article

ACYLKETENES AND THIOACYLKETENES - SYNTHESIS OF 3-BENZOYL-4-PHENYLTHIET-2-ONE

WENTRUP, C, WINTER, HW, GROSS, G, NETSCH, KP, KOLLENZ, G, OTT, W and BIEDERMANN, AG (1984). ACYLKETENES AND THIOACYLKETENES - SYNTHESIS OF 3-BENZOYL-4-PHENYLTHIET-2-ONE. Angewandte Chemie-International Edition in English, 23 (10), 800-802. doi: 10.1002/anie.198408001

ACYLKETENES AND THIOACYLKETENES - SYNTHESIS OF 3-BENZOYL-4-PHENYLTHIET-2-ONE

1984

Journal Article

2-AZAADAMANT-1-ENE AND 4-AZAPROTOADAMANT-3-ENE

RADZISZEWSKI, JG, DOWNING, JW, WENTRUP, C, KASZYNSKI, P, JAWDOSIUK, M, KOVACIC, P and MICHL, J (1984). 2-AZAADAMANT-1-ENE AND 4-AZAPROTOADAMANT-3-ENE. Journal of the American Chemical Society, 106 (25), 7996-7998. doi: 10.1021/ja00337a072

2-AZAADAMANT-1-ENE AND 4-AZAPROTOADAMANT-3-ENE

1984

Journal Article

REACTIVE NITROGENOUS MOLECULES FROM MELDRUMS ACID-DERIVATIVES, PYRROLE-2,3-DIONES, AND ISOXAZOLONES

BRIEHL, H, LUKOSCH, A and WENTRUP, C (1984). REACTIVE NITROGENOUS MOLECULES FROM MELDRUMS ACID-DERIVATIVES, PYRROLE-2,3-DIONES, AND ISOXAZOLONES. Journal of Organic Chemistry, 49 (15), 2772-2779. doi: 10.1021/jo00189a025

REACTIVE NITROGENOUS MOLECULES FROM MELDRUMS ACID-DERIVATIVES, PYRROLE-2,3-DIONES, AND ISOXAZOLONES

1984

Journal Article

The Millimeter Wave Rotational Spectrum of N-Cyanomethanimine, Ch2Ncn

Winnewisser, M, Winnewisser, BP and Wentrup, C (1984). The Millimeter Wave Rotational Spectrum of N-Cyanomethanimine, Ch2Ncn. Journal of Molecular Spectroscopy, 105 (1), 193-205. doi: 10.1016/0022-2852(84)90111-5

The Millimeter Wave Rotational Spectrum of N-Cyanomethanimine, Ch2Ncn

1984

Conference Publication

Twisting the C=N Double-Bond - Bridgehead Imines

Radziszewski, JG, Jawdosiuk, M, Downing, JW, Kaszynski, P, Wentrup, C, Kovacic, P and Michl, J (1984). Twisting the C=N Double-Bond - Bridgehead Imines. WASHINGTON: AMER CHEMICAL SOC.

Twisting the C=N Double-Bond - Bridgehead Imines

1983

Journal Article

THIETONES, OXETONES, AND AZETONES

WENTRUP, C and GROSS, G (1983). THIETONES, OXETONES, AND AZETONES. Angewandte Chemie-International Edition in English, 22 (7), 543-543. doi: 10.1002/anie.198305431

THIETONES, OXETONES, AND AZETONES

1983

Journal Article

(IMINOMETHYLIDENE)PHOSPHINES (RP=C=NR)

WENTRUP, C, BRIEHL, H, BECKER, G, UHL, G, WESSELY, HJ, MAQUESTIAU, A and FLAMMANG, R (1983). (IMINOMETHYLIDENE)PHOSPHINES (RP=C=NR). Journal of the American Chemical Society, 105 (24), 7194-7195. doi: 10.1021/ja00362a042

(IMINOMETHYLIDENE)PHOSPHINES (RP=C=NR)

1983

Journal Article

THERMAL AZULENE REARRANGEMENTS - SYNTHESIS AND THERMOLYSIS OF [6-C-13]AZULENE

GUGEL, H, ZELLER, KP and WENTRUP, C (1983). THERMAL AZULENE REARRANGEMENTS - SYNTHESIS AND THERMOLYSIS OF [6-C-13]AZULENE. Chemische Berichte-Recueil, 116 (8), 2775-2784. doi: 10.1002/cber.19831160806

THERMAL AZULENE REARRANGEMENTS - SYNTHESIS AND THERMOLYSIS OF [6-C-13]AZULENE

1983

Journal Article

1,2-CYCLOHEXADIENE

WENTRUP, C, GROSS, G, MAQUESTIAU, A and FLAMMANG, R (1983). 1,2-CYCLOHEXADIENE. Angewandte Chemie-International Edition in English, 22 (7), 542-543. doi: 10.1002/anie.198305421

1,2-CYCLOHEXADIENE

1982

Journal Article

COLLISIONAL ACTIVATION OF BENZONITRILIMINE RADICAL CATION AND SOME OF ITS ISOMERS

MAQUESTIAU, A, FLAMMANG, R, PAUWELS, P, BOUCHOUX, G, FISCHER, S and WENTRUP, C (1982). COLLISIONAL ACTIVATION OF BENZONITRILIMINE RADICAL CATION AND SOME OF ITS ISOMERS. Bulletin Des Societes Chimiques Belges, 91 (6), 565-567.

COLLISIONAL ACTIVATION OF BENZONITRILIMINE RADICAL CATION AND SOME OF ITS ISOMERS

1982

Journal Article

HETEROCYCLIC REARRANGEMENTS - NEW CUMULENES AND ACETYLENES

WENTRUP, C (1982). HETEROCYCLIC REARRANGEMENTS - NEW CUMULENES AND ACETYLENES. Bulletin Des Societes Chimiques Belges, 91 (12), 997-1002.

HETEROCYCLIC REARRANGEMENTS - NEW CUMULENES AND ACETYLENES

Funding

Past funding

  • 2012 - 2013
    Heron Island Conference on reactive intermediate and unusual molecules
    Ian Potter Foundation
    Open grant
  • 2010
    UQ Travel Awards Category 1, Fabian Borget
    UQ Travel Grants Scheme
    Open grant
  • 2007 - 2009
    Reactive intermediates and microwave-assisted organic reactions
    ARC Discovery Projects
    Open grant
  • 2007
    Research in pre-biotic chemistry
    UQ Travel Grants Scheme
    Open grant
  • 2004
    Research conference grant for Prof Josef Michl, University of Colorado, Boulder, to attend Heron Island Conference on reactive intermediates and unusual molecules, 17-23 July 2004
    Potter Foundation
    Open grant
  • 2004 - 2006
    New mechanisms and methods in carbene and nitrene chemistry
    ARC Discovery Projects
    Open grant
  • 2003 - 2005
    Bimolecular chemistry at very low temperature
    ARC Linkage International
    Open grant
  • 2002
    To expand work on cryogenic matrix isolation research.
    UQ Travel Grants Scheme
    Open grant
  • 2001 - 2003
    Chemistry of Iminopropadienones and Related Compounds.
    ARC Australian Research Council (Large grants)
    Open grant
  • 2000
    Novel approaches to heterocyclic synthesis.
    ARC Australian Research Council (Small grants)
    Open grant
  • 1997
    Brisbane Advanced Mass Spectrometry Facility
    Research Infrastructure (Equip & Fac) Program
    Open grant
  • 1997
    Synthesis of 1,3-diazepines
    ARC Australian Research Council (Small grants)
    Open grant
  • 1996 - 1997
    International Network in Advanced Techniques of Applied Molecular Science
    Quality Funds Round 3
    Open grant
  • 1996
    Pulsed pyrolysis
    ARC Australian Research Council (Small grants)
    Open grant

Supervision

Availability

Emeritus Professor Curt Wentrup is:
Not available for supervision

Supervision history

Completed supervision

  • 2006

    Doctor Philosophy

    SYNTHESES AND REACTIONS OF IMINOPROPADIENONES, SYDNONES AND OXAZINONES

    Principal Advisor

    Other advisors: Professor Craig Williams

  • 2002

    Doctor Philosophy

    HETEROCYCLIC SYNTHESIS BASED ON IMINOPROPADIENONES

    Principal Advisor

  • 2002

    Doctor Philosophy

    SYNTHESIS AND CHARACTERISATION OF 1,3- and 1,4- DIAZEPINES AND DERIVATIVES

    Principal Advisor

  • Doctor Philosophy

    NITRENES REARRANGEMENTS: FORMATION OF REACTIVE INTERMEDIATES AND UNUSUAL MOLECULES

    Principal Advisor

    Other advisors: Professor Craig Williams

Media

Enquiries

Contact Emeritus Professor Curt Wentrup directly for media enquiries about:

  • Organic reaction mechanisms
  • Photochemistry
  • Pyrolysis
  • Reactive intermediates

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