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Emeritus Professor Curt Wentrup
Emeritus Professor

Curt Wentrup

Email: 
Phone: 
+61 7 336 53817

Overview

Background

Educated at the University of Copenhagen, Denmark, and the Australian National University, Canberra. Career at the Université de Lausanne, Switzerland, and the Universität Marburg, Germany. Professor and Chair of Organic Chemistry and Head of the Organic Chemistry Section, The University of Queensland from 1985. Emeritus professor from 2008. Chair of the National Committee for Chemistry of the Australian Academy of Science 2009-2014. Editor-in-Chief, Australian Journal of Chemistry 2008-15. Editor, Journal of Analytical and Applied Pyrolysis (Elsevier, IF 3.65) 2016-. Visiting Professor Université de Pau, France, 2011-19; Visiting Professor University of Kuwait 2014-18; Visiting Professor / Special Appointed Professor Hiroshima University 2014-18. Fellow of the Australian Academy of Science. Centenary Medal of the Australian Commonwealth 2003 for research in organic and physical chemistry. David Craig Medal of the Academy of Science 2014 for research in chemistry. JSPS Fellowship (Japan) 2014. Honorary doctorate, University of Pau, France, 2014. A.J. Birch Medal of the Royal Australian Chemical Institute (RACI) for ecellence in research in organic chemistry, 2014. Leighton Medal of the RACI 2018.

Research on Unusual Molecules and Reactive Intermediates: Synthesis and Reaction Mechanism. Heterocyclic chemistry. Pyrolysis reactions. Photochemistry

Research in the Wentrup group is concerned with the discovery of novel types of molecules with new and unusual bonding patterns. Such molecules are mostly highly reactive, and special methods are required both for their generation and for their detection. The group has developed these methods over many years and acquired world-class equipment for these purposes, including flash vacuum thermolysis apparatus, cryostats for matrix isolation of reaction products at cryogenic temperatures (down to 7 K), matrix and solution photochemistry equipment, infrared, UV and mass spectrometers, as well as modern computational facilities.

This research has resulted in the synthesis and characterization of many novel compounds, including extended cumulenes of the types RN=C=C=C=X, which themselves are used in the synthesis of many novel types of molecules, some of them of potential pharmaceutical interest (quinolone antibiotics; diazepines).

The research group has a world reputation in the field of carbene and nitrene chemistry, involving reactive intermediates with sextet carbon or nitrogen. These species are also very useful in synthesis, for example in the preparation of diazepines and diazepinones, a family of pharmaceutically interesting compounds. Numerous mechanistic studies and synthetic applications of ketenes have been carried out in our group.

Active collaborations are ongoing with scientists in Australia (UQ and CSIRO), China (Suzhou), France (Pau), Germany (Oldenburg), Japan (Hiroshima), Spain (Donostia - San Sebastian), and Portugal (Coimbra).

Availability

Emeritus Professor Curt Wentrup is:
Not available for supervision
Media expert

Qualifications

  • Doctor of Philosophy, Australian National University
  • Doctor of Philosophy of Science (Advanced), University of Copenhagen
  • Doctoral Diploma, Institution to be confirmed
  • Australian Academy of Science, Australian Academy of Science
  • Royal Australian Chemical Institute, Royal Australian Chemical Institute

Research interests

  • Organic, physical, and historical chemistry

    Reactive intermediates, pyrolysis, photochemistry, reaction mechanism. History of science.

Research impacts

This research leads to the development of new pharmaceuticals, e.g. new antibiotics (quinolones and naphthyridones) and new leads towards a treatment for scizophrenia (diazepine molecules).

Chemical industry has used our pyrolysis techniques in specialized manufacturing processes.

Our analytical/spectroscopic work has led to cooperation with chemical and energy firms and agencies involved in forensic science, and our research has generated collaborations with many scientists at universities in Australia, Austria, Belgium, China, Denmark, France, Germany, Hungary, Japan, Portugal, Singapore, Switzerland, and USA.

Works

Search Professor Curt Wentrup’s works on UQ eSpace

433 works between 1966 and 2024

321 - 340 of 433 works

1991

Journal Article

2,5-Dithiacyclopentylideneketene and Ethenedithione, S=C=C=S, Generated by Flash Vacuum Pyrolysis

Wentrup C., Kambouris P., Evans R.A., Owen D., Macfarlane G., Chuche J., Pommelet J.C., Cheikh A.B., Plisnier M. and Flammang R. (1991). 2,5-Dithiacyclopentylideneketene and Ethenedithione, S=C=C=S, Generated by Flash Vacuum Pyrolysis. Journal of the American Chemical Society, 113 (8), 3130-3135. doi: 10.1021/ja00008a048

2,5-Dithiacyclopentylideneketene and Ethenedithione, S=C=C=S, Generated by Flash Vacuum Pyrolysis

1991

Journal Article

Direct observation of α-oxo ketenes formed from 1,3-dioxin-4-ones and the enols of β-keto esters

Freiermuth B. and Wentrup C. (1991). Direct observation of α-oxo ketenes formed from 1,3-dioxin-4-ones and the enols of β-keto esters. Journal of Organic Chemistry, 56 (7), 2286-2289. doi: 10.1021/jo00007a008

Direct observation of α-oxo ketenes formed from 1,3-dioxin-4-ones and the enols of β-keto esters

1990

Journal Article

Identification of the transient benzonitrile n-sulfide by flash-vacuum pyrolysis and neutralization-reionization mass spectrometry

Maquestiau A., Flammang R., Plisnier M., Wentrup C., Kambouris P., Paton M.R. and Terlouw J.K. (1990). Identification of the transient benzonitrile n-sulfide by flash-vacuum pyrolysis and neutralization-reionization mass spectrometry. International Journal of Mass Spectrometry and Ion Processes, 100 (C), 477-488. doi: 10.1016/0168-1176(90)85090-O

Identification of the transient benzonitrile n-sulfide by flash-vacuum pyrolysis and neutralization-reionization mass spectrometry

1990

Journal Article

Flash‐vacuum pyrolysis of 1‐acylbenzotriazole: Direct observation of cyclopenta‐2,4‐dienylidenemethaneimines by tandem mass spectrometry and low‐temperature infrared spectrometry

Maquestiau A., Beugnies D., Flammang R., Freiermuth B. and Wentrup C. (1990). Flash‐vacuum pyrolysis of 1‐acylbenzotriazole: Direct observation of cyclopenta‐2,4‐dienylidenemethaneimines by tandem mass spectrometry and low‐temperature infrared spectrometry. Organic Mass Spectrometry, 25 (4), 197-203. doi: 10.1002/oms.1210250404

Flash‐vacuum pyrolysis of 1‐acylbenzotriazole: Direct observation of cyclopenta‐2,4‐dienylidenemethaneimines by tandem mass spectrometry and low‐temperature infrared spectrometry

1989

Journal Article

CONFIRMATION OF THE ELECTRIC-FIELD GRADIENTS AT THE NITROGEN NUCLEI IN N-CYANOMETHANIMINE, CH2NCN, FROM LOW-J ROTATIONAL TRANSITIONS

STOLZE, WH, SUTTER, DH and WENTRUP, C (1989). CONFIRMATION OF THE ELECTRIC-FIELD GRADIENTS AT THE NITROGEN NUCLEI IN N-CYANOMETHANIMINE, CH2NCN, FROM LOW-J ROTATIONAL TRANSITIONS. Zeitschrift Fur Naturforschung Section A-A Journal of Physical Sciences, 44 (4), 291-294.

CONFIRMATION OF THE ELECTRIC-FIELD GRADIENTS AT THE NITROGEN NUCLEI IN N-CYANOMETHANIMINE, CH2NCN, FROM LOW-J ROTATIONAL TRANSITIONS

1988

Journal Article

A new example of internal oxidation of remote groups in organic nitroaromatic ions

Maquestiau A., Flammang R., Flammang-Barbieux M., Chen L.-Z. and Wentrup C. (1988). A new example of internal oxidation of remote groups in organic nitroaromatic ions. International Journal of Mass Spectrometry and Ion Processes, 86 (C), 235-249. doi: 10.1016/0168-1176(88)80068-5

A new example of internal oxidation of remote groups in organic nitroaromatic ions

1988

Journal Article

Dinitrogen sulfide, N2S, revealed by photoelectron spectroscopy

Bender, Harald, Carnovale, Frank, Barrie, Peel J. and Wentrup, Curt (1988). Dinitrogen sulfide, N2S, revealed by photoelectron spectroscopy. Journal of the American Chemical Society, 110 (11), 3458-3461. doi: 10.1021/ja00219a019

Dinitrogen sulfide, N2S, revealed by photoelectron spectroscopy

1988

Journal Article

PRIMARY ETHYNAMINES (HC=CNH2, PHC=CNH2), AMINOPROPADIENONE (H2NCH=C=C=O), AND IMIDOYLKETENE (HN=CHCH=C=O) - PREPARATION AND IDENTIFICATION OF MOLECULES OF COSMOCHEMICAL INTEREST

WENTRUP, C, BRIEHL, H, LORENCAK, P, VOGELBACHER, UJ, WINTER, HW, MAQUESTIAU, A and FLAMMANG, R (1988). PRIMARY ETHYNAMINES (HC=CNH2, PHC=CNH2), AMINOPROPADIENONE (H2NCH=C=C=O), AND IMIDOYLKETENE (HN=CHCH=C=O) - PREPARATION AND IDENTIFICATION OF MOLECULES OF COSMOCHEMICAL INTEREST. Journal of the American Chemical Society, 110 (5), 1337-1343. doi: 10.1021/ja00213a002

PRIMARY ETHYNAMINES (HC=CNH2, PHC=CNH2), AMINOPROPADIENONE (H2NCH=C=C=O), AND IMIDOYLKETENE (HN=CHCH=C=O) - PREPARATION AND IDENTIFICATION OF MOLECULES OF COSMOCHEMICAL INTEREST

1988

Journal Article

Interrelationship between carboxy(vinyl)ketenes, methyleneketenes, vinylketenes, and hydroxyacetylenes

Wentrup C. and Lorencak P. (1988). Interrelationship between carboxy(vinyl)ketenes, methyleneketenes, vinylketenes, and hydroxyacetylenes. Journal of the American Chemical Society, 110 (6), 1880-1883. doi: 10.1021/ja00214a035

Interrelationship between carboxy(vinyl)ketenes, methyleneketenes, vinylketenes, and hydroxyacetylenes

1988

Journal Article

Benzyne, cyclohexyne, and 3-azacyclohexyne and the problem of cycloalkyne versus cycloalkylideneketene genesis

Wentrup C., Blanch R., Briehl H. and Gross G. (1988). Benzyne, cyclohexyne, and 3-azacyclohexyne and the problem of cycloalkyne versus cycloalkylideneketene genesis. Journal of the American Chemical Society, 110 (6), 1874-1880. doi: 10.1021/ja00214a034

Benzyne, cyclohexyne, and 3-azacyclohexyne and the problem of cycloalkyne versus cycloalkylideneketene genesis

1987

Journal Article

CORRECTION

WENTRUP, C (1987). CORRECTION. Chemical Physics Letters, 139 (6), 613-613. doi: 10.1016/0009-2614(87)87353-0

CORRECTION

1987

Journal Article

Benzothiet-2-ones: Synthesis, Reactions, and Comparison with Benzoxet-2-ones and Benzazetin-2-ones

Wentrup C., Bender H. and Gross G. (1987). Benzothiet-2-ones: Synthesis, Reactions, and Comparison with Benzoxet-2-ones and Benzazetin-2-ones. Journal of Organic Chemistry, 52 (17), 3838-3847. doi: 10.1021/jo00226a022

Benzothiet-2-ones: Synthesis, Reactions, and Comparison with Benzoxet-2-ones and Benzazetin-2-ones

1987

Journal Article

C2H2N2 Isomers in the Gas-Phase - Characterization of Ch2=N-Cn and Hn=Ch-Cn by Collisional Activation Mass-Spectrometry

Wentrup, C, Lorencak, P, Maquestiau, A and Flammang, R (1987). C2H2N2 Isomers in the Gas-Phase - Characterization of Ch2=N-Cn and Hn=Ch-Cn by Collisional Activation Mass-Spectrometry. Chemical Physics Letters, 137 (3), 241-244. doi: 10.1016/0009-2614(87)80212-9

C2H2N2 Isomers in the Gas-Phase - Characterization of Ch2=N-Cn and Hn=Ch-Cn by Collisional Activation Mass-Spectrometry

1987

Journal Article

FLASH PYROLYSIS OF 1,4-BIS(5-TETRAZOLYL)BENZENE - ENTRY TO THE C8H6 ENERGY SURFACE

BAUM, MW, FONT, JL, MEISLICH, ME, WENTRUP, C and JONES, M (1987). FLASH PYROLYSIS OF 1,4-BIS(5-TETRAZOLYL)BENZENE - ENTRY TO THE C8H6 ENERGY SURFACE. Journal of the American Chemical Society, 109 (8), 2534-2536. doi: 10.1021/ja00242a060

FLASH PYROLYSIS OF 1,4-BIS(5-TETRAZOLYL)BENZENE - ENTRY TO THE C8H6 ENERGY SURFACE

1987

Journal Article

GAS-PHASE REACTIONS .61. NITRILE IMINES RC=+N--N-SI(CH3)3 - OPTIMIZATION OF GAS-PHASE SYNTHESIS AND ASSIGNMENT OF THEIR PHOTOELECTRON-SPECTRA

BOCK, H, DAMMEL, R, FISCHER, S and WENTRUP, C (1987). GAS-PHASE REACTIONS .61. NITRILE IMINES RC=+N--N-SI(CH3)3 - OPTIMIZATION OF GAS-PHASE SYNTHESIS AND ASSIGNMENT OF THEIR PHOTOELECTRON-SPECTRA. Tetrahedron Letters, 28 (6), 617-620. doi: 10.1016/S0040-4039(00)95795-2

GAS-PHASE REACTIONS .61. NITRILE IMINES RC=+N--N-SI(CH3)3 - OPTIMIZATION OF GAS-PHASE SYNTHESIS AND ASSIGNMENT OF THEIR PHOTOELECTRON-SPECTRA

1986

Journal Article

Iminoacetonitrile, An Hcn Dimer - Ir Identification in An Argon Matrix

Lorencak, P, Raabe, G, Radziszewski, JJ and Wentrup, C (1986). Iminoacetonitrile, An Hcn Dimer - Ir Identification in An Argon Matrix. Journal of the Chemical Society-Chemical Communications, 96 (12), 916-918. doi: 10.1039/c39860000916

Iminoacetonitrile, An Hcn Dimer - Ir Identification in An Argon Matrix

1986

Journal Article

Dinitrogen Sulfide

Wentrup, C, Fischer, S, Maquestiau, A and Flammang, R (1986). Dinitrogen Sulfide. Journal of Organic Chemistry, 51 (10), 1908-1910. doi: 10.1021/jo00360a051

Dinitrogen Sulfide

1986

Journal Article

Unsaturated Ketenes - a Study of Their Formation and Rearrangement by Tandem Mass-Spectrometry and Low-Temperature Infrared-Spectroscopy

Maquestiau, A, Pauwels, P, Flammang, R, Lorencak, P and Wentrup, C (1986). Unsaturated Ketenes - a Study of Their Formation and Rearrangement by Tandem Mass-Spectrometry and Low-Temperature Infrared-Spectroscopy. Organic Mass Spectrometry, 21 (5), 259-265. doi: 10.1002/oms.1210210505

Unsaturated Ketenes - a Study of Their Formation and Rearrangement by Tandem Mass-Spectrometry and Low-Temperature Infrared-Spectroscopy

1986

Journal Article

A STABLE METHYLENEKETENE AND THE STEPWISE FRAGMENTATION OF MELDRUMS ACIDS

LORENCAK, P, POMMELET, JC, CHUCHE, J and WENTRUP, C (1986). A STABLE METHYLENEKETENE AND THE STEPWISE FRAGMENTATION OF MELDRUMS ACIDS. Journal of the Chemical Society-Chemical Communications (5), 369-370. doi: 10.1039/c39860000369

A STABLE METHYLENEKETENE AND THE STEPWISE FRAGMENTATION OF MELDRUMS ACIDS

1986

Journal Article

DIAZAFULVENONES - THERMAL ISOMERIZATIONS AND ELIMINATIONS IN ALKOXYCARBONYL AND ANILINOCARBONYL DERIVATIVES OF IMIDAZOLE

MAQUESTIAU, A, TOMMASETTI, A, PEDREGALFREIRE, C, ELGUERO, J, FLAMMANG, R, WIERSUM, UE, BENDER, H and WENTRUP, C (1986). DIAZAFULVENONES - THERMAL ISOMERIZATIONS AND ELIMINATIONS IN ALKOXYCARBONYL AND ANILINOCARBONYL DERIVATIVES OF IMIDAZOLE. Journal of Organic Chemistry, 51 (3), 306-309. doi: 10.1021/jo00353a006

DIAZAFULVENONES - THERMAL ISOMERIZATIONS AND ELIMINATIONS IN ALKOXYCARBONYL AND ANILINOCARBONYL DERIVATIVES OF IMIDAZOLE

Funding

Past funding

  • 2012 - 2013
    Heron Island Conference on reactive intermediate and unusual molecules
    Ian Potter Foundation
    Open grant
  • 2010
    UQ Travel Awards Category 1, Fabian Borget
    UQ Travel Grants Scheme
    Open grant
  • 2007 - 2008
    An X-Ray Diffraction Facility for Molecular Structure Determination
    ARC Linkage Infrastructure, Equipment and Facilities
    Open grant
  • 2007 - 2009
    Reactive intermediates and microwave-assisted organic reactions
    ARC Discovery Projects
    Open grant
  • 2007
    Research in pre-biotic chemistry
    UQ Travel Grants Scheme
    Open grant
  • 2004
    Research conference grant for Prof Josef Michl, University of Colorado, Boulder, to attend Heron Island Conference on reactive intermediates and unusual molecules, 17-23 July 2004
    Potter Foundation
    Open grant
  • 2004 - 2006
    New mechanisms and methods in carbene and nitrene chemistry
    ARC Discovery Projects
    Open grant
  • 2003 - 2005
    Bimolecular chemistry at very low temperature
    ARC Linkage International
    Open grant
  • 2002
    To expand work on cryogenic matrix isolation research.
    UQ Travel Grants Scheme
    Open grant
  • 2001 - 2003
    Chemistry of Iminopropadienones and Related Compounds.
    ARC Australian Research Council (Large grants)
    Open grant
  • 2000
    Novel approaches to heterocyclic synthesis.
    ARC Australian Research Council (Small grants)
    Open grant
  • 1997
    Brisbane Advanced Mass Spectrometry Facility
    Research Infrastructure (Equip & Fac) Program
    Open grant
  • 1997
    Synthesis of 1,3-diazepines
    ARC Australian Research Council (Small grants)
    Open grant
  • 1996 - 1997
    International Network in Advanced Techniques of Applied Molecular Science
    Quality Funds Round 3
    Open grant
  • 1996
    Pulsed pyrolysis
    ARC Australian Research Council (Small grants)
    Open grant

Supervision

Availability

Emeritus Professor Curt Wentrup is:
Not available for supervision

Supervision history

Completed supervision

  • 2006

    Doctor Philosophy

    SYNTHESES AND REACTIONS OF IMINOPROPADIENONES, SYDNONES AND OXAZINONES

    Principal Advisor

    Other advisors: Professor Craig Williams

  • 2002

    Doctor Philosophy

    HETEROCYCLIC SYNTHESIS BASED ON IMINOPROPADIENONES

    Principal Advisor

  • 2002

    Doctor Philosophy

    SYNTHESIS AND CHARACTERISATION OF 1,3- and 1,4- DIAZEPINES AND DERIVATIVES

    Principal Advisor

  • Doctor Philosophy

    NITRENES REARRANGEMENTS: FORMATION OF REACTIVE INTERMEDIATES AND UNUSUAL MOLECULES

    Principal Advisor

    Other advisors: Professor Craig Williams

Media

Enquiries

Contact Emeritus Professor Curt Wentrup directly for media enquiries about:

  • Organic reaction mechanisms
  • Photochemistry
  • Pyrolysis
  • Reactive intermediates

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