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Emeritus Professor Curt Wentrup
Emeritus Professor

Curt Wentrup

Email: 
Phone: 
+61 7 336 53817

Overview

Background

Educated at the University of Copenhagen, Denmark, and the Australian National University, Canberra. Career at the Université de Lausanne, Switzerland, and the Universität Marburg, Germany. Professor and Chair of Organic Chemistry and Head of the Organic Chemistry Section, The University of Queensland from 1985. Emeritus professor from 2008. Chair of the National Committee for Chemistry of the Australian Academy of Science 2009-2014. Editor-in-Chief, Australian Journal of Chemistry 2008-15. Editor, Journal of Analytical and Applied Pyrolysis (Elsevier, IF 3.65) 2016-. Visiting Professor Université de Pau, France, 2011-19; Visiting Professor University of Kuwait 2014-18; Visiting Professor / Special Appointed Professor Hiroshima University 2014-18. Fellow of the Australian Academy of Science. Centenary Medal of the Australian Commonwealth 2003 for research in organic and physical chemistry. David Craig Medal of the Academy of Science 2014 for research in chemistry. JSPS Fellowship (Japan) 2014. Honorary doctorate, University of Pau, France, 2014. A.J. Birch Medal of the Royal Australian Chemical Institute (RACI) for ecellence in research in organic chemistry, 2014. Leighton Medal of the RACI 2018.

Research on Unusual Molecules and Reactive Intermediates: Synthesis and Reaction Mechanism. Heterocyclic chemistry. Pyrolysis reactions. Photochemistry

Research in the Wentrup group is concerned with the discovery of novel types of molecules with new and unusual bonding patterns. Such molecules are mostly highly reactive, and special methods are required both for their generation and for their detection. The group has developed these methods over many years and acquired world-class equipment for these purposes, including flash vacuum thermolysis apparatus, cryostats for matrix isolation of reaction products at cryogenic temperatures (down to 7 K), matrix and solution photochemistry equipment, infrared, UV and mass spectrometers, as well as modern computational facilities.

This research has resulted in the synthesis and characterization of many novel compounds, including extended cumulenes of the types RN=C=C=C=X, which themselves are used in the synthesis of many novel types of molecules, some of them of potential pharmaceutical interest (quinolone antibiotics; diazepines).

The research group has a world reputation in the field of carbene and nitrene chemistry, involving reactive intermediates with sextet carbon or nitrogen. These species are also very useful in synthesis, for example in the preparation of diazepines and diazepinones, a family of pharmaceutically interesting compounds. Numerous mechanistic studies and synthetic applications of ketenes have been carried out in our group.

Active collaborations are ongoing with scientists in Australia (UQ and CSIRO), China (Suzhou), France (Pau), Germany (Oldenburg), Japan (Hiroshima), Spain (Donostia - San Sebastian), and Portugal (Coimbra).

Availability

Emeritus Professor Curt Wentrup is:
Not available for supervision
Media expert

Qualifications

  • Doctor of Philosophy, Australian National University
  • Doctor of Philosophy of Science (Advanced), University of Copenhagen
  • Doctoral Diploma, Institution to be confirmed
  • Australian Academy of Science, Australian Academy of Science
  • Royal Australian Chemical Institute, Royal Australian Chemical Institute

Research interests

  • Organic, physical, and historical chemistry

    Reactive intermediates, pyrolysis, photochemistry, reaction mechanism. History of science.

Research impacts

This research leads to the development of new pharmaceuticals, e.g. new antibiotics (quinolones and naphthyridones) and new leads towards a treatment for scizophrenia (diazepine molecules).

Chemical industry has used our pyrolysis techniques in specialized manufacturing processes.

Our analytical/spectroscopic work has led to cooperation with chemical and energy firms and agencies involved in forensic science, and our research has generated collaborations with many scientists at universities in Australia, Austria, Belgium, China, Denmark, France, Germany, Hungary, Japan, Portugal, Singapore, Switzerland, and USA.

Works

Search Professor Curt Wentrup’s works on UQ eSpace

433 works between 1966 and 2024

261 - 280 of 433 works

1996

Journal Article

Novel heterocumulene (RN=C=C=C=X) and ketene rearrangements

Wentrup C., Fulloon B.E., Moloney D.W.J., Bibas H. and Wong M.W. (1996). Novel heterocumulene (RN=C=C=C=X) and ketene rearrangements. Pure and Applied Chemistry, 68 (4), 891-894. doi: 10.1351/pac199668040891

Novel heterocumulene (RN=C=C=C=X) and ketene rearrangements

1996

Journal Article

(Cyanovinyl)ketenes from azafulvenones. An apparent retro-Wolff rearrangement

Qiao, GGH, Meutermans, W, Wong, MW, Traubel, M and Wentrup, C (1996). (Cyanovinyl)ketenes from azafulvenones. An apparent retro-Wolff rearrangement. Journal of the American Chemical Society, 118 (16), 3852-3861. doi: 10.1021/ja954226r

(Cyanovinyl)ketenes from azafulvenones. An apparent retro-Wolff rearrangement

1996

Journal Article

Synthesis of 1H- and 5H-1,3-diazepines from azido- and tetrazolo-pyridines

Reisinger, A and Wentrup, C (1996). Synthesis of 1H- and 5H-1,3-diazepines from azido- and tetrazolo-pyridines. Chemical Communications (7), 813-814. doi: 10.1039/cc9960000813

Synthesis of 1H- and 5H-1,3-diazepines from azido- and tetrazolo-pyridines

1996

Journal Article

The cheletropic trapping of nitric oxide by the bis-ketene 1,2-dicarbonylcyclohexa-3,5-diene and the diene 3,4-diphenyl-2,5-dimethyl-2,4-hexadiene.

Adam, W, Bottle, SE, Grice, ID, Pfeiler, D and Wentrup, C (1996). The cheletropic trapping of nitric oxide by the bis-ketene 1,2-dicarbonylcyclohexa-3,5-diene and the diene 3,4-diphenyl-2,5-dimethyl-2,4-hexadiene.. Tetrahedron Letters, 37 (12), 2113-2116. doi: 10.1016/0040-4039(96)00206-7

The cheletropic trapping of nitric oxide by the bis-ketene 1,2-dicarbonylcyclohexa-3,5-diene and the diene 3,4-diphenyl-2,5-dimethyl-2,4-hexadiene.

1996

Journal Article

Photochemistry of deuterated acetylketenes: Matrix isolation infrared spectroscopic and ab initio studies

Zuhse, RH, Wong, MW and Wentrup, C (1996). Photochemistry of deuterated acetylketenes: Matrix isolation infrared spectroscopic and ab initio studies. Journal of Physical Chemistry, 100 (10), 3917-3922. doi: 10.1021/jp9529026

Photochemistry of deuterated acetylketenes: Matrix isolation infrared spectroscopic and ab initio studies

1996

Journal Article

Imidoylketene-oxoketenimine interconversion. Rearrangement of a carbomethoxyketenimine to a methoxyimidoylketene and 2-methoxy-4-quinolone

Fulloon B.E. and Wentrup C. (1996). Imidoylketene-oxoketenimine interconversion. Rearrangement of a carbomethoxyketenimine to a methoxyimidoylketene and 2-methoxy-4-quinolone. Journal of Organic Chemistry, 61 (4), 1363-1367. doi: 10.1021/jo951832w

Imidoylketene-oxoketenimine interconversion. Rearrangement of a carbomethoxyketenimine to a methoxyimidoylketene and 2-methoxy-4-quinolone

1995

Journal Article

Polycarbon Disulfides Scns (N=1-3) and Their Protonated and Methylated Forms (Hcns2+ and Ch3Cns2+) - Tandem Mass-Spectrometry and Ab-Initio Mo Study

Wong, MW, Wentrup, C and Flammang, R (1995). Polycarbon Disulfides Scns (N=1-3) and Their Protonated and Methylated Forms (Hcns2+ and Ch3Cns2+) - Tandem Mass-Spectrometry and Ab-Initio Mo Study. Journal of Physical Chemistry, 99 (46), 16849-16856. doi: 10.1021/j100046a010

Polycarbon Disulfides Scns (N=1-3) and Their Protonated and Methylated Forms (Hcns2+ and Ch3Cns2+) - Tandem Mass-Spectrometry and Ab-Initio Mo Study

1995

Journal Article

IMIDOYLKETENE OXOKETENIMINE REARRANGEMENT - FACILE 1,3-SHIFT OF AN ALKOXY GROUP

FULLOON, B, ELNABI, HAA, KOLLENZ, G and WENTRUP, C (1995). IMIDOYLKETENE OXOKETENIMINE REARRANGEMENT - FACILE 1,3-SHIFT OF AN ALKOXY GROUP. Tetrahedron Letters, 36 (36), 6547-6550. doi: 10.1016/0040-4039(95)01283-N

IMIDOYLKETENE OXOKETENIMINE REARRANGEMENT - FACILE 1,3-SHIFT OF AN ALKOXY GROUP

1995

Journal Article

Vinylketene-Acylallene Rearrangement

Bibas, H, Wong, MW and Wentrup, C (1995). Vinylketene-Acylallene Rearrangement. Journal of the American Chemical Society, 117 (37), 9582-9583. doi: 10.1021/ja00142a034

Vinylketene-Acylallene Rearrangement

1995

Journal Article

A Remarkably Stable Linear Ketenimine

Wolf, R, Wong, MW, Kennard, Chl and Wentrup, C (1995). A Remarkably Stable Linear Ketenimine. Journal of the American Chemical Society, 117 (25), 6789-6790. doi: 10.1021/ja00130a023

A Remarkably Stable Linear Ketenimine

1995

Journal Article

3-carbonyl-3H-indole: Direct observation and tetramerization to a tetrabenzoporphyrin analogue

Qiao G.G. and Wentrup C. (1995). 3-carbonyl-3H-indole: Direct observation and tetramerization to a tetrabenzoporphyrin analogue. Tetrahedron Letters, 36 (22), 3913-3916. doi: 10.1016/0040-4039(95)00640-X

3-carbonyl-3H-indole: Direct observation and tetramerization to a tetrabenzoporphyrin analogue

1995

Journal Article

(ALPHA)-OXOKETENES - PREPARATION AND CHEMISTRY (DEC, PG 1219, 1994)

WENTRUP, C, HEILMAYER, W and KOLLENZ, G (1995). (ALPHA)-OXOKETENES - PREPARATION AND CHEMISTRY (DEC, PG 1219, 1994). Synthesis-Stuttgart (3), 343-343. doi: 10.1055/s-1994-25673

(ALPHA)-OXOKETENES - PREPARATION AND CHEMISTRY (DEC, PG 1219, 1994)

1995

Conference Publication

Ketene rearrangements and 1,3-shifts

Wentrup, C and Wong, MW (1995). Ketene rearrangements and 1,3-shifts. 3rd Latin-American Conference on Organic Physical Chemistry, Florianopolis Brazil, Apr 09-14, 1995. 88040-900 FLORIANOPOLIS: UNIVERSIDADE FEDERAL SANTA CATARINA.

Ketene rearrangements and 1,3-shifts

1995

Journal Article

A convenient de novo synthesis of functionalised 2,4,6,8- tetraoxaadamantanes

Heilmayer W., Dalvi T.S., Kappe C.O., Wentrup C., Gruber K., Sterk H. and Kollenz G. (1995). A convenient de novo synthesis of functionalised 2,4,6,8- tetraoxaadamantanes. Journal of the Chemical Society-Chemical Communications (7), 797-798. doi: 10.1039/C39950000797

A convenient de novo synthesis of functionalised 2,4,6,8- tetraoxaadamantanes

1995

Journal Article

The use of 1, 2-shifts in carbenes and nitrenes in the generation of novel heterocumulenes

Wentrup, Curt, Kappe, C. Oliver and Wong, Ming Wah (1995). The use of 1, 2-shifts in carbenes and nitrenes in the generation of novel heterocumulenes. Pure and Applied Chemistry, 67 (5), 749-754. doi: 10.1351/pac199567050749

The use of 1, 2-shifts in carbenes and nitrenes in the generation of novel heterocumulenes

1995

Journal Article

Polycarbon Sulfides Cns (N=2-6) and Corresponding Hydrides Hcns - Neutralization-Reionization Mass-Spectrometry and Ab-Initio Molecular-Orbital Study

Flammang, R, Vanhaverbeke, Y, Wong, MW and Wentrup, C (1995). Polycarbon Sulfides Cns (N=2-6) and Corresponding Hydrides Hcns - Neutralization-Reionization Mass-Spectrometry and Ab-Initio Molecular-Orbital Study. Rapid Communications in Mass Spectrometry, 9 (3), 203-208. doi: 10.1002/rcm.1290090305

Polycarbon Sulfides Cns (N=2-6) and Corresponding Hydrides Hcns - Neutralization-Reionization Mass-Spectrometry and Ab-Initio Molecular-Orbital Study

1995

Conference Publication

The use of 1, 2-shifts in carbenes and nitrenes in the generation of novel heterocumulenes

Wentrup, C., Kappe, C. O. and Wong, M. W. (1995). The use of 1, 2-shifts in carbenes and nitrenes in the generation of novel heterocumulenes. 12th International Conference on Physical Organic Chemistry, Padua Italy, 28 August -9 September 1994. Oxford United Kingdom: Wiley-Blackwell. doi: 10.1351/pac199567050749

The use of 1, 2-shifts in carbenes and nitrenes in the generation of novel heterocumulenes

1995

Journal Article

Acetylketene: Conformational isomerism and photochemistry. Matrix isolation infrared and ab initio studies

Kappe C.O., Wong M.W. and Wentrup C. (1995). Acetylketene: Conformational isomerism and photochemistry. Matrix isolation infrared and ab initio studies. Journal of Organic Chemistry, 60 (6), 1686-1695. doi: 10.1021/jo00111a029

Acetylketene: Conformational isomerism and photochemistry. Matrix isolation infrared and ab initio studies

1994

Journal Article

ALPHA-OXOKETENES - PREPARATION AND CHEMISTRY

WENTRUP, C, HEILMAYER, W and KOLLENZ, G (1994). ALPHA-OXOKETENES - PREPARATION AND CHEMISTRY. Synthesis-Stuttgart, 1219-1248. doi: 10.1055/s-1994-25673

ALPHA-OXOKETENES - PREPARATION AND CHEMISTRY

1994

Journal Article

Ketene-Ketene Rearrangement - Substituent Effects An the 1,3-Migration in Alpha-Oxo Ketenes

Wong, MW and Wentrup, C (1994). Ketene-Ketene Rearrangement - Substituent Effects An the 1,3-Migration in Alpha-Oxo Ketenes. Journal of Organic Chemistry, 59 (18), 5279-5285. doi: 10.1021/jo00097a033

Ketene-Ketene Rearrangement - Substituent Effects An the 1,3-Migration in Alpha-Oxo Ketenes

Funding

Past funding

  • 2012 - 2013
    Heron Island Conference on reactive intermediate and unusual molecules
    Ian Potter Foundation
    Open grant
  • 2010
    UQ Travel Awards Category 1, Fabian Borget
    UQ Travel Grants Scheme
    Open grant
  • 2007 - 2008
    An X-Ray Diffraction Facility for Molecular Structure Determination
    ARC Linkage Infrastructure, Equipment and Facilities
    Open grant
  • 2007 - 2009
    Reactive intermediates and microwave-assisted organic reactions
    ARC Discovery Projects
    Open grant
  • 2007
    Research in pre-biotic chemistry
    UQ Travel Grants Scheme
    Open grant
  • 2004
    Research conference grant for Prof Josef Michl, University of Colorado, Boulder, to attend Heron Island Conference on reactive intermediates and unusual molecules, 17-23 July 2004
    Potter Foundation
    Open grant
  • 2004 - 2006
    New mechanisms and methods in carbene and nitrene chemistry
    ARC Discovery Projects
    Open grant
  • 2003 - 2005
    Bimolecular chemistry at very low temperature
    ARC Linkage International
    Open grant
  • 2002
    To expand work on cryogenic matrix isolation research.
    UQ Travel Grants Scheme
    Open grant
  • 2001 - 2003
    Chemistry of Iminopropadienones and Related Compounds.
    ARC Australian Research Council (Large grants)
    Open grant
  • 2000
    Novel approaches to heterocyclic synthesis.
    ARC Australian Research Council (Small grants)
    Open grant
  • 1997
    Brisbane Advanced Mass Spectrometry Facility
    Research Infrastructure (Equip & Fac) Program
    Open grant
  • 1997
    Synthesis of 1,3-diazepines
    ARC Australian Research Council (Small grants)
    Open grant
  • 1996 - 1997
    International Network in Advanced Techniques of Applied Molecular Science
    Quality Funds Round 3
    Open grant
  • 1996
    Pulsed pyrolysis
    ARC Australian Research Council (Small grants)
    Open grant

Supervision

Availability

Emeritus Professor Curt Wentrup is:
Not available for supervision

Supervision history

Completed supervision

  • 2006

    Doctor Philosophy

    SYNTHESES AND REACTIONS OF IMINOPROPADIENONES, SYDNONES AND OXAZINONES

    Principal Advisor

    Other advisors: Professor Craig Williams

  • 2002

    Doctor Philosophy

    HETEROCYCLIC SYNTHESIS BASED ON IMINOPROPADIENONES

    Principal Advisor

  • 2002

    Doctor Philosophy

    SYNTHESIS AND CHARACTERISATION OF 1,3- and 1,4- DIAZEPINES AND DERIVATIVES

    Principal Advisor

  • Doctor Philosophy

    NITRENES REARRANGEMENTS: FORMATION OF REACTIVE INTERMEDIATES AND UNUSUAL MOLECULES

    Principal Advisor

    Other advisors: Professor Craig Williams

Media

Enquiries

Contact Emeritus Professor Curt Wentrup directly for media enquiries about:

  • Organic reaction mechanisms
  • Photochemistry
  • Pyrolysis
  • Reactive intermediates

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