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Emeritus Professor Curt Wentrup
Emeritus Professor

Curt Wentrup

Email: 
Phone: 
+61 7 336 53817

Overview

Background

Educated at the University of Copenhagen, Denmark, and the Australian National University, Canberra. Career at the Université de Lausanne, Switzerland, and the Universität Marburg, Germany. Professor and Chair of Organic Chemistry and Head of the Organic Chemistry Section, The University of Queensland from 1985. Emeritus professor from 2008. Chair of the National Committee for Chemistry of the Australian Academy of Science 2009-2014. Editor-in-Chief, Australian Journal of Chemistry 2008-15. Editor, Journal of Analytical and Applied Pyrolysis (Elsevier, IF 3.65) 2016-. Visiting Professor Université de Pau, France, 2011-19; Visiting Professor University of Kuwait 2014-18; Visiting Professor / Special Appointed Professor Hiroshima University 2014-18. Fellow of the Australian Academy of Science. Centenary Medal of the Australian Commonwealth 2003 for research in organic and physical chemistry. David Craig Medal of the Academy of Science 2014 for research in chemistry. JSPS Fellowship (Japan) 2014. Honorary doctorate, University of Pau, France, 2014. A.J. Birch Medal of the Royal Australian Chemical Institute (RACI) for ecellence in research in organic chemistry, 2014. Leighton Medal of the RACI 2018.

Research on Unusual Molecules and Reactive Intermediates: Synthesis and Reaction Mechanism. Heterocyclic chemistry. Pyrolysis reactions. Photochemistry

Research in the Wentrup group is concerned with the discovery of novel types of molecules with new and unusual bonding patterns. Such molecules are mostly highly reactive, and special methods are required both for their generation and for their detection. The group has developed these methods over many years and acquired world-class equipment for these purposes, including flash vacuum thermolysis apparatus, cryostats for matrix isolation of reaction products at cryogenic temperatures (down to 7 K), matrix and solution photochemistry equipment, infrared, UV and mass spectrometers, as well as modern computational facilities.

This research has resulted in the synthesis and characterization of many novel compounds, including extended cumulenes of the types RN=C=C=C=X, which themselves are used in the synthesis of many novel types of molecules, some of them of potential pharmaceutical interest (quinolone antibiotics; diazepines).

The research group has a world reputation in the field of carbene and nitrene chemistry, involving reactive intermediates with sextet carbon or nitrogen. These species are also very useful in synthesis, for example in the preparation of diazepines and diazepinones, a family of pharmaceutically interesting compounds. Numerous mechanistic studies and synthetic applications of ketenes have been carried out in our group.

Active collaborations are ongoing with scientists in Australia (UQ and CSIRO), China (Suzhou), France (Pau), Germany (Oldenburg), Japan (Hiroshima), Spain (Donostia - San Sebastian), and Portugal (Coimbra).

Availability

Emeritus Professor Curt Wentrup is:
Not available for supervision
Media expert

Qualifications

  • Doctor of Philosophy, Australian National University
  • Doctor of Philosophy of Science (Advanced), University of Copenhagen
  • Doctoral Diploma, Institution to be confirmed
  • Australian Academy of Science, Australian Academy of Science
  • Royal Australian Chemical Institute, Royal Australian Chemical Institute

Research interests

  • Organic, physical, and historical chemistry

    Reactive intermediates, pyrolysis, photochemistry, reaction mechanism. History of science.

Research impacts

This research leads to the development of new pharmaceuticals, e.g. new antibiotics (quinolones and naphthyridones) and new leads towards a treatment for scizophrenia (diazepine molecules).

Chemical industry has used our pyrolysis techniques in specialized manufacturing processes.

Our analytical/spectroscopic work has led to cooperation with chemical and energy firms and agencies involved in forensic science, and our research has generated collaborations with many scientists at universities in Australia, Austria, Belgium, China, Denmark, France, Germany, Hungary, Japan, Portugal, Singapore, Switzerland, and USA.

Works

Search Professor Curt Wentrup’s works on UQ eSpace

433 works between 1966 and 2024

201 - 220 of 433 works

2002

Journal Article

Chemistry of stable iminopropadienones, RN=C=C=C=O

Bibas, H., Moloney, D. W. J., Neumann, R., Shtaiwi, M., Bernhardt, P. V. and Wentrup, C. (2002). Chemistry of stable iminopropadienones, RN=C=C=C=O. Journal of Organic Chemistry, 67 (8), 2619-2631. doi: 10.1021/jo0110552

Chemistry of stable iminopropadienones, RN=C=C=C=O

2002

Journal Article

Synthesis and chemical reactivity of methoxycarbonyl-1,3-dioxinyl(pivaloyl)ketene - a persistent alpha-oxoketene

Wallfisch, B. C., Belaj, F., Wentrup, C., Kappe, C. O. and Kollenz, G. (2002). Synthesis and chemical reactivity of methoxycarbonyl-1,3-dioxinyl(pivaloyl)ketene - a persistent alpha-oxoketene. Journal of The Chemical Society-perkin Transactions 1, 2 (5), 599-605. doi: 10.1039/b111143d

Synthesis and chemical reactivity of methoxycarbonyl-1,3-dioxinyl(pivaloyl)ketene - a persistent alpha-oxoketene

2002

Journal Article

Iminopropadienones from dioxanediones, isoxazolopyrimidinones, pyridopyrimidinones, and pyridopyrimidinium olates

Shtaiwi, M. and Wentrup, C. (2002). Iminopropadienones from dioxanediones, isoxazolopyrimidinones, pyridopyrimidinones, and pyridopyrimidinium olates. Journal of Organic Chemistry, 67 (24), 8558-8565. doi: 10.1021/jo026275+

Iminopropadienones from dioxanediones, isoxazolopyrimidinones, pyridopyrimidinones, and pyridopyrimidinium olates

2002

Journal Article

From reactive intermediates to stable compounds

Wentrup, C (2002). From reactive intermediates to stable compounds. Science, 295 (5561), 1846-1847. doi: 10.1126/science.1070364

From reactive intermediates to stable compounds

2001

Journal Article

On the chemistry of stable alpha-oxoketenes

Kollenz, Gert, Heilmayer, Werner, Kappe, C. Oliver, Wallfisch, Bianca and Wentrup, Curl (2001). On the chemistry of stable alpha-oxoketenes. Croatica Chemica Acta, 74 (4), 815-823.

On the chemistry of stable alpha-oxoketenes

2001

Journal Article

Properties of triplet tetrachloro-4-pyridylnitrene isolated in inert matrices

Chapyshev S.V. and Wentrup C. (2001). Properties of triplet tetrachloro-4-pyridylnitrene isolated in inert matrices. Chemistry of Heterocyclic Compounds, 37 (9), 1119-1129. doi: 10.1023/A:1013283817500

Properties of triplet tetrachloro-4-pyridylnitrene isolated in inert matrices

2001

Journal Article

Reactions of dipivaloylketene and its dimer with NH(2)-nucleophiles. Formation of amides, hydrazides, ureides and pyrimidine-2,4-diones

Kollenz, Gert, Kappe, C. Oliver, Dalvi, Turkaram S. and Wentrup, Curt (2001). Reactions of dipivaloylketene and its dimer with NH(2)-nucleophiles. Formation of amides, hydrazides, ureides and pyrimidine-2,4-diones. Arkivoc, 2001 (vi), 30-41. doi: 10.3998/ark.5550190.0002.603

Reactions of dipivaloylketene and its dimer with NH(2)-nucleophiles. Formation of amides, hydrazides, ureides and pyrimidine-2,4-diones

2001

Journal Article

Preparation and chemistry of an unexpectedly stable alpha-oxoketene-pyridine zwitterion, 2,2-bis(tert-butylcarbonyl)-1-[4-(dimethylamino)pyridinio]ethen-1-olate

Kollenz, G., Holzer, S., Kappe, C. O., Dalvi, T. S., Fabian, W. M. F., Sterk, H., Wong, M. W. and Wentrup, C. (2001). Preparation and chemistry of an unexpectedly stable alpha-oxoketene-pyridine zwitterion, 2,2-bis(tert-butylcarbonyl)-1-[4-(dimethylamino)pyridinio]ethen-1-olate. European Journal of Organic Chemistry, 2001 (7), 1315-1322. doi: 10.1002/1099-0690(200104)2001:73.0.CO;2-2

Preparation and chemistry of an unexpectedly stable alpha-oxoketene-pyridine zwitterion, 2,2-bis(tert-butylcarbonyl)-1-[4-(dimethylamino)pyridinio]ethen-1-olate

2001

Journal Article

Chemistry - Fleeting molecules extend their stay

Wentrup, C (2001). Chemistry - Fleeting molecules extend their stay. Science, 292 (5523), 1846-1847. doi: 10.1126/science.1062316

Chemistry - Fleeting molecules extend their stay

2001

Journal Article

Characterization of C2S4 center dot+ isomers by mass spectrometry and ab initio molecular orbital calculations

Gerbaux, P., Flammang, R., Wentrup, C. and Wong, M. W. (2001). Characterization of C2S4 center dot+ isomers by mass spectrometry and ab initio molecular orbital calculations. International Journal of Mass Spectrometry, 210 (1-3), 31-42. doi: 10.1016/S1387-3806(01)00406-7

Characterization of C2S4 center dot+ isomers by mass spectrometry and ab initio molecular orbital calculations

2001

Journal Article

Preparation and chemistry of an unexpectedly stabe a-Oxoketene-Pyridine Zwitterion, 2,2-Bis(tert-butylcarbonyl)-1-[4-(dimethylamino)pyrdiinio]ethen-1-olate

Kollenz, G., Holzer, S., Kappe, O., Dalvi, T. S., Fabian, W.M.F., Sterk, H., Wong, M.W. and Wentrup, C. (2001). Preparation and chemistry of an unexpectedly stabe a-Oxoketene-Pyridine Zwitterion, 2,2-Bis(tert-butylcarbonyl)-1-[4-(dimethylamino)pyrdiinio]ethen-1-olate. European Journal of Organic Chemistry, 2001, 1315-1322.

Preparation and chemistry of an unexpectedly stabe a-Oxoketene-Pyridine Zwitterion, 2,2-Bis(tert-butylcarbonyl)-1-[4-(dimethylamino)pyrdiinio]ethen-1-olate

2001

Journal Article

Iminopropadienethiones, Ar-N=C=C=C=S

Kappe, C. O., Kvaskoff, D., Moloney, D. W. J., Flammang, R. and Wentrup, C. (2001). Iminopropadienethiones, Ar-N=C=C=C=S. Journal of Organic Chemistry, 66 (5), 1827-1831. doi: 10.1021/jo001595j

Iminopropadienethiones, Ar-N=C=C=C=S

2001

Journal Article

Ketenes and mesoions. Interconversion of mesoionic pyridopyrimidinium olates and pyridopyrimidinones. (2-Pyridyl)iminopropadienone. Part 2

Andersen, H. G., Mitschke, U. and Wentrup, C. (2001). Ketenes and mesoions. Interconversion of mesoionic pyridopyrimidinium olates and pyridopyrimidinones. (2-Pyridyl)iminopropadienone. Part 2. Journal of The Chemical Society-perkin Transactions 2 (4), 602-607. doi: 10.1039/b007298m

Ketenes and mesoions. Interconversion of mesoionic pyridopyrimidinium olates and pyridopyrimidinones. (2-Pyridyl)iminopropadienone. Part 2

2001

Journal Article

Formation of cumulenes, triple-bonded, and related compounds by flash vacuum thermolysis of five-membered heterocycles

Yranzo, G.I., Elguero, J., Flammang, R. and Wentrup, C. (2001). Formation of cumulenes, triple-bonded, and related compounds by flash vacuum thermolysis of five-membered heterocycles. European Journal of Organic Chemistry, 2001 (12), 2209-2220. doi: 10.1002/1099-0690(200106)2001:123.0.co;2-x

Formation of cumulenes, triple-bonded, and related compounds by flash vacuum thermolysis of five-membered heterocycles

2001

Journal Article

Ketenes and mesoions. Interconversion of mesoionic pyridopyrimidinium olates and pyridopyrimidinones. (2-Pyridyl) iminopropadienone

Andersen, H., Mitschke, U. and Wentrup, C. (2001). Ketenes and mesoions. Interconversion of mesoionic pyridopyrimidinium olates and pyridopyrimidinones. (2-Pyridyl) iminopropadienone. Journal of the Chemical Society Perkin Transactions II, 1 (4), 602-607.

Ketenes and mesoions. Interconversion of mesoionic pyridopyrimidinium olates and pyridopyrimidinones. (2-Pyridyl) iminopropadienone

2001

Journal Article

Properties of isolated in inert matrices triplet tetrachloropyridyl-4-nitrene

Chapyshev, S. V. and Wentrup, C. (2001). Properties of isolated in inert matrices triplet tetrachloropyridyl-4-nitrene. Khimiya Geterotsiklicheskikh Soedinenii (9), 1219-1231.

Properties of isolated in inert matrices triplet tetrachloropyridyl-4-nitrene

2001

Journal Article

Characterization of C2S4.+ isomers by mass spectrometry and ab initio molecular orbital calculations

Gerbaux, P., Flammang, R., Wentrup, C. and Wong, M. W. (2001). Characterization of C2S4.+ isomers by mass spectrometry and ab initio molecular orbital calculations. International Journal of Mass Spectrometry, 210/211, 31-42.

Characterization of C2S4.+ isomers by mass spectrometry and ab initio molecular orbital calculations

2000

Journal Article

3-Diphenylmethylpyrido[1,2-alpha][1,3,5]triazine-2,4-dione

Fiksdahl, Anne and Wentrup, Curt (2000). 3-Diphenylmethylpyrido[1,2-alpha][1,3,5]triazine-2,4-dione. Arkivoc, 2000 (iii), 438-444. doi: 10.3998/ark.5550190.0001.325

3-Diphenylmethylpyrido[1,2-alpha][1,3,5]triazine-2,4-dione

2000

Journal Article

Reactions of dipivaloylketene and its dimer with C-nucleophiles

Kollenz, Gert, Dalvi, Turkaram S., Kappe, Oliver and Wentrup, Curt (2000). Reactions of dipivaloylketene and its dimer with C-nucleophiles. Arkivoc, 2000 (i), 74-79. doi: 10.3998/ark.5550190.0001.111

Reactions of dipivaloylketene and its dimer with C-nucleophiles

2000

Journal Article

Mono-, Di, and Tri-Nitrenes in the Pyridine series

Chapyshev, S., Kuhn, A., Wong, M. W. and Wentrup, C. (2000). Mono-, Di, and Tri-Nitrenes in the Pyridine series. Journal of the American Chemical Society, 122 (8), 1572-1579. doi: 10.1021/ja9931067

Mono-, Di, and Tri-Nitrenes in the Pyridine series

Funding

Past funding

  • 2012 - 2013
    Heron Island Conference on reactive intermediate and unusual molecules
    Ian Potter Foundation
    Open grant
  • 2010
    UQ Travel Awards Category 1, Fabian Borget
    UQ Travel Grants Scheme
    Open grant
  • 2007 - 2008
    An X-Ray Diffraction Facility for Molecular Structure Determination
    ARC Linkage Infrastructure, Equipment and Facilities
    Open grant
  • 2007 - 2009
    Reactive intermediates and microwave-assisted organic reactions
    ARC Discovery Projects
    Open grant
  • 2007
    Research in pre-biotic chemistry
    UQ Travel Grants Scheme
    Open grant
  • 2004
    Research conference grant for Prof Josef Michl, University of Colorado, Boulder, to attend Heron Island Conference on reactive intermediates and unusual molecules, 17-23 July 2004
    Potter Foundation
    Open grant
  • 2004 - 2006
    New mechanisms and methods in carbene and nitrene chemistry
    ARC Discovery Projects
    Open grant
  • 2003 - 2005
    Bimolecular chemistry at very low temperature
    ARC Linkage International
    Open grant
  • 2002
    To expand work on cryogenic matrix isolation research.
    UQ Travel Grants Scheme
    Open grant
  • 2001 - 2003
    Chemistry of Iminopropadienones and Related Compounds.
    ARC Australian Research Council (Large grants)
    Open grant
  • 2000
    Novel approaches to heterocyclic synthesis.
    ARC Australian Research Council (Small grants)
    Open grant
  • 1997
    Brisbane Advanced Mass Spectrometry Facility
    Research Infrastructure (Equip & Fac) Program
    Open grant
  • 1997
    Synthesis of 1,3-diazepines
    ARC Australian Research Council (Small grants)
    Open grant
  • 1996 - 1997
    International Network in Advanced Techniques of Applied Molecular Science
    Quality Funds Round 3
    Open grant
  • 1996
    Pulsed pyrolysis
    ARC Australian Research Council (Small grants)
    Open grant

Supervision

Availability

Emeritus Professor Curt Wentrup is:
Not available for supervision

Supervision history

Completed supervision

  • 2006

    Doctor Philosophy

    SYNTHESES AND REACTIONS OF IMINOPROPADIENONES, SYDNONES AND OXAZINONES

    Principal Advisor

    Other advisors: Professor Craig Williams

  • 2002

    Doctor Philosophy

    HETEROCYCLIC SYNTHESIS BASED ON IMINOPROPADIENONES

    Principal Advisor

  • 2002

    Doctor Philosophy

    SYNTHESIS AND CHARACTERISATION OF 1,3- and 1,4- DIAZEPINES AND DERIVATIVES

    Principal Advisor

  • Doctor Philosophy

    NITRENES REARRANGEMENTS: FORMATION OF REACTIVE INTERMEDIATES AND UNUSUAL MOLECULES

    Principal Advisor

    Other advisors: Professor Craig Williams

Media

Enquiries

Contact Emeritus Professor Curt Wentrup directly for media enquiries about:

  • Organic reaction mechanisms
  • Photochemistry
  • Pyrolysis
  • Reactive intermediates

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