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Emeritus Professor Curt Wentrup
Emeritus Professor

Curt Wentrup

Email: 
Phone: 
+61 7 336 53817

Overview

Background

Educated at the University of Copenhagen, Denmark, and the Australian National University, Canberra. Career at the Université de Lausanne, Switzerland, and the Universität Marburg, Germany. Professor and Chair of Organic Chemistry and Head of the Organic Chemistry Section, The University of Queensland from 1985. Emeritus professor from 2008. Chair of the National Committee for Chemistry of the Australian Academy of Science 2009-2014. Editor-in-Chief, Australian Journal of Chemistry 2008-15. Editor, Journal of Analytical and Applied Pyrolysis (Elsevier, IF 3.65) 2016-. Visiting Professor Université de Pau, France, 2011-19; Visiting Professor University of Kuwait 2014-18; Visiting Professor / Special Appointed Professor Hiroshima University 2014-18. Fellow of the Australian Academy of Science. Centenary Medal of the Australian Commonwealth 2003 for research in organic and physical chemistry. David Craig Medal of the Academy of Science 2014 for research in chemistry. JSPS Fellowship (Japan) 2014. Honorary doctorate, University of Pau, France, 2014. A.J. Birch Medal of the Royal Australian Chemical Institute (RACI) for ecellence in research in organic chemistry, 2014. Leighton Medal of the RACI 2018.

Research on Unusual Molecules and Reactive Intermediates: Synthesis and Reaction Mechanism. Heterocyclic chemistry. Pyrolysis reactions. Photochemistry

Research in the Wentrup group is concerned with the discovery of novel types of molecules with new and unusual bonding patterns. Such molecules are mostly highly reactive, and special methods are required both for their generation and for their detection. The group has developed these methods over many years and acquired world-class equipment for these purposes, including flash vacuum thermolysis apparatus, cryostats for matrix isolation of reaction products at cryogenic temperatures (down to 7 K), matrix and solution photochemistry equipment, infrared, UV and mass spectrometers, as well as modern computational facilities.

This research has resulted in the synthesis and characterization of many novel compounds, including extended cumulenes of the types RN=C=C=C=X, which themselves are used in the synthesis of many novel types of molecules, some of them of potential pharmaceutical interest (quinolone antibiotics; diazepines).

The research group has a world reputation in the field of carbene and nitrene chemistry, involving reactive intermediates with sextet carbon or nitrogen. These species are also very useful in synthesis, for example in the preparation of diazepines and diazepinones, a family of pharmaceutically interesting compounds. Numerous mechanistic studies and synthetic applications of ketenes have been carried out in our group.

Active collaborations are ongoing with scientists in Australia (UQ and CSIRO), China (Suzhou), France (Pau), Germany (Oldenburg), Japan (Hiroshima), Spain (Donostia - San Sebastian), and Portugal (Coimbra).

Availability

Emeritus Professor Curt Wentrup is:
Not available for supervision
Media expert

Qualifications

  • Doctor of Philosophy, Australian National University
  • Doctor of Philosophy of Science (Advanced), University of Copenhagen
  • Doctoral Diploma, Institution to be confirmed
  • Australian Academy of Science, Australian Academy of Science
  • Royal Australian Chemical Institute, Royal Australian Chemical Institute

Research interests

  • Organic, physical, and historical chemistry

    Reactive intermediates, pyrolysis, photochemistry, reaction mechanism. History of science.

Research impacts

This research leads to the development of new pharmaceuticals, e.g. new antibiotics (quinolones and naphthyridones) and new leads towards a treatment for scizophrenia (diazepine molecules).

Chemical industry has used our pyrolysis techniques in specialized manufacturing processes.

Our analytical/spectroscopic work has led to cooperation with chemical and energy firms and agencies involved in forensic science, and our research has generated collaborations with many scientists at universities in Australia, Austria, Belgium, China, Denmark, France, Germany, Hungary, Japan, Portugal, Singapore, Switzerland, and USA.

Works

Search Professor Curt Wentrup’s works on UQ eSpace

433 works between 1966 and 2024

221 - 240 of 433 works

2000

Journal Article

Mesoions and ketene valence isomers. Pyrrolo[1,2-a]pyridinium olates and (2-pyridyl)carbonylketenes

Ye, X., Andraos, J., Bibas, H., Wong, M. W. and Wentrup, C. (2000). Mesoions and ketene valence isomers. Pyrrolo[1,2-a]pyridinium olates and (2-pyridyl)carbonylketenes. Journal of The Chemical Society- Perkin Transactions I (1), 401-406.

Mesoions and ketene valence isomers. Pyrrolo[1,2-a]pyridinium olates and (2-pyridyl)carbonylketenes

2000

Journal Article

Mesoions and ketene valence isomers. Three types of rearrangement of mesoionic pyridopyrimidinylium olates involving ketene intermediates

Fiksdahl, A., Plug, C. and Wentrup, C. (2000). Mesoions and ketene valence isomers. Three types of rearrangement of mesoionic pyridopyrimidinylium olates involving ketene intermediates. Perkin Transactions II, 31 (2), 1841-1845. doi: 10.1039/b003662p

Mesoions and ketene valence isomers. Three types of rearrangement of mesoionic pyridopyrimidinylium olates involving ketene intermediates

2000

Journal Article

Mesoionic pyridopyrimidinylium and pyrisooxazinylium olates and non-mesoionic pyridopyrimidinones. Structures in the solid state, solution and matrices

Plug, C., Wallfisch, B., Andersen, H. G., Bernhardt, P. V., Baker, L., Clark, G. R., Wong, M. W. and Wentrup, C. (2000). Mesoionic pyridopyrimidinylium and pyrisooxazinylium olates and non-mesoionic pyridopyrimidinones. Structures in the solid state, solution and matrices. Perkin Transactions II (2), 2096-2108.

Mesoionic pyridopyrimidinylium and pyrisooxazinylium olates and non-mesoionic pyridopyrimidinones. Structures in the solid state, solution and matrices

2000

Journal Article

Acylthioketene-thioacylketene-thiet-2-one rearrangements

Ammann, J., Flammang, R., Wong, M. W. and Wentrup, C. (2000). Acylthioketene-thioacylketene-thiet-2-one rearrangements. Journal of Organic Chemistry, 65 (9), 2706-2710. doi: 10.1021/jo991776p

Acylthioketene-thioacylketene-thiet-2-one rearrangements

2000

Journal Article

Mono-, Di, and Tri-Nitrenes in the Pyridine series

Chapyshev, S., Kuhn, A., Wong, M. W. and Wentrup, C. (2000). Mono-, Di, and Tri-Nitrenes in the Pyridine series. Journal of the American Chemical Society, 122 (8), 1572-1579. doi: 10.1021/ja9931067

Mono-, Di, and Tri-Nitrenes in the Pyridine series

2000

Journal Article

The thioacyl isocyanate-acyl isothiocyanate rearrangement

Koch, R. and Wentrup, C. (2000). The thioacyl isocyanate-acyl isothiocyanate rearrangement. Perkin Transactions II (2), 1846-1850.

The thioacyl isocyanate-acyl isothiocyanate rearrangement

2000

Journal Article

The thioacyl isocyanate-acyl isothiocyanate rearrangement

Koch, R and Wentrup, C (2000). The thioacyl isocyanate-acyl isothiocyanate rearrangement. Journal of the Chemical Society-Perkin Transactions 2 (9), 1846-1850. doi: 10.1039/b003534n

The thioacyl isocyanate-acyl isothiocyanate rearrangement

2000

Journal Article

Monomer, dimers and trimers of cyanogens N-oxide, NC-CN

Barbieux-Flammang, M., Vandevoorde, S., Flammang, R., Wong, M. W., Bibas, H., Kennard, C. H. and Wentrup, C. (2000). Monomer, dimers and trimers of cyanogens N-oxide, NC-CN. Journal of The Chemical Society-Perkin Transactions II (2), 473-478.

Monomer, dimers and trimers of cyanogens N-oxide, NC-CN

2000

Journal Article

Mesoionic pyridopyrimidinylium and pyridooxazinylium olates and non-mesoionic pyridopyrimidinones. Structures in the solid state, solution, and matrices

Plug, C., Wallfisch, B., Andersen, H. G., Bernhardt, P. V., Baker, L. J., Clark, G. R., Wong, M. W. and Wentrup, C. (2000). Mesoionic pyridopyrimidinylium and pyridooxazinylium olates and non-mesoionic pyridopyrimidinones. Structures in the solid state, solution, and matrices. Journal of The Chemical Society-perkin Transactions 2 (10), 2096-2108. doi: 10.1039/b003933k

Mesoionic pyridopyrimidinylium and pyridooxazinylium olates and non-mesoionic pyridopyrimidinones. Structures in the solid state, solution, and matrices

2000

Journal Article

Mesoions and ketene valence isomers. Pyrrolo[1,2-alpha]pyridinylium olates and (2-pyridyl)carbonylketenes

Ye, X, Andraos, J, Bibas, H, Wong, MW and Wentrup, C (2000). Mesoions and ketene valence isomers. Pyrrolo[1,2-alpha]pyridinylium olates and (2-pyridyl)carbonylketenes. Journal of the Chemical Society-Perkin Transactions 1 (3), 401-406. doi: 10.1039/a906831g

Mesoions and ketene valence isomers. Pyrrolo[1,2-alpha]pyridinylium olates and (2-pyridyl)carbonylketenes

2000

Journal Article

Direct observation of a carbene-pyridine ylide by matrix IR spectroscopy. Rearrangements of 2-pyridylacylcarbenes

Kuhn, A., Plug, C. and Wentrup, C. (2000). Direct observation of a carbene-pyridine ylide by matrix IR spectroscopy. Rearrangements of 2-pyridylacylcarbenes. Journal of the American Chemical Society, 122 (9), 1945-1948. doi: 10.1021/ja993859t

Direct observation of a carbene-pyridine ylide by matrix IR spectroscopy. Rearrangements of 2-pyridylacylcarbenes

2000

Journal Article

Mass spectrometric studies of dipolar systems containing an N+-X- bond

Gerbaux, P., Wentrup, C. and Flammang, R. (2000). Mass spectrometric studies of dipolar systems containing an N+-X- bond. Mass Spectrometry Review, 19 (6), 367-389. doi: 10.1002/1098-2787(2000)19:63.0.CO;2-N

Mass spectrometric studies of dipolar systems containing an N+-X- bond

1999

Journal Article

Aryliminopropadienone-C-amidoketenimine-amidinoketene-2-aminoquinolone cascades and the ynamine-isocyanate reaction

Wentrup, C., Rao, R. V. V., Frank, W., Fulloon, B. E., Moloney, D. W. J. and Mosandl, T. (1999). Aryliminopropadienone-C-amidoketenimine-amidinoketene-2-aminoquinolone cascades and the ynamine-isocyanate reaction. Journal of Organic Chemistry, 64 (10), 3608-3619. doi: 10.1021/jo982471y

Aryliminopropadienone-C-amidoketenimine-amidinoketene-2-aminoquinolone cascades and the ynamine-isocyanate reaction

1999

Journal Article

Formation and characterization of methoxy isothiocyanate (CH3ON=C=S) and methyl cyanate N-sulfide (CH3OC=N+-S-) as radical cations and neutrals in the gas phase

Flammang, R., Gerbaux, P., Barbieux-Flammang, M., Pedersen, C. T., Bech, A. T., Morkved, E. H., Wong, M. W. and Wentrup, C. (1999). Formation and characterization of methoxy isothiocyanate (CH3ON=C=S) and methyl cyanate N-sulfide (CH3OC=N+-S-) as radical cations and neutrals in the gas phase. Journal of the Chemical Society, Perkin Transactions 2 (8), 1683-1688. doi: 10.1039/a903057c

Formation and characterization of methoxy isothiocyanate (CH3ON=C=S) and methyl cyanate N-sulfide (CH3OC=N+-S-) as radical cations and neutrals in the gas phase

1999

Journal Article

Mass spectrometry of S=C=(C)n=C=X cumulenes

Flammang, R., Frank, W. and Wentrup, C. (1999). Mass spectrometry of S=C=(C)n=C=X cumulenes. Sulfur Reports, 21, 357-371.

Mass spectrometry of S=C=(C)n=C=X cumulenes

1999

Journal Article

Alkoxy isothiocyanates, RO-N=C=S

Bech, A. T., Flammang, R., Pedersen, C. T., Wong, M. W. and Wentrup, C. (1999). Alkoxy isothiocyanates, RO-N=C=S. Journal of the Chemical Society, Perkin Transactions 2 (9), 1869-1873. doi: 10.1039/a903865e

Alkoxy isothiocyanates, RO-N=C=S

1999

Journal Article

(2-Pyridyl)iminopropadienone

Plüg, Carsten, Frank, Wilhelm and Wentrup, Curt (1999). (2-Pyridyl)iminopropadienone. Journal of the Chemical Society, Perkin Transactions 2 (6), 1087-1093. doi: 10.1039/a901632e

(2-Pyridyl)iminopropadienone

1998

Journal Article

On the di-1-naphthylcarbene-dibenzofluorene rearrangement and the ethylenization of diarylcarbinols

Regimbald-Krnel M. and Wentrup C. (1998). On the di-1-naphthylcarbene-dibenzofluorene rearrangement and the ethylenization of diarylcarbinols. Journal of Organic Chemistry, 63 (23), 8417-8423. doi: 10.1021/jo981397g

On the di-1-naphthylcarbene-dibenzofluorene rearrangement and the ethylenization of diarylcarbinols

1998

Journal Article

Nitrile N-selenide (RC=NSe) and isoselenocyanate (RN=C=Se) neutrals and radical cations by selenation of nitriles and isonitriles: Tandem mass spectrometry and ab initio studies

Gerbaux, Pascal, Flammang, Robert, Mørkved, Eva H., Wong, Ming Wah and Wentrup, Curt (1998). Nitrile N-selenide (RC=NSe) and isoselenocyanate (RN=C=Se) neutrals and radical cations by selenation of nitriles and isonitriles: Tandem mass spectrometry and ab initio studies. Journal of Physical Chemistry A, 102 (45), 9021-9030. doi: 10.1021/jp9824454

Nitrile N-selenide (RC=NSe) and isoselenocyanate (RN=C=Se) neutrals and radical cations by selenation of nitriles and isonitriles: Tandem mass spectrometry and ab initio studies

1998

Journal Article

Dihydro-1,3-diazepinones and diazabicyclo[3.2.0]heptenones from pyridyl azides

Reisinger, Ales, Koch, Rainer and Wentrup, Curt (1998). Dihydro-1,3-diazepinones and diazabicyclo[3.2.0]heptenones from pyridyl azides. Journal of the Chemical Society - Perkin Transactions 1, 29 (15), 2247-2249. doi: 10.1039/a804831b

Dihydro-1,3-diazepinones and diazabicyclo[3.2.0]heptenones from pyridyl azides

Funding

Past funding

  • 2012 - 2013
    Heron Island Conference on reactive intermediate and unusual molecules
    Ian Potter Foundation
    Open grant
  • 2010
    UQ Travel Awards Category 1, Fabian Borget
    UQ Travel Grants Scheme
    Open grant
  • 2007 - 2008
    An X-Ray Diffraction Facility for Molecular Structure Determination
    ARC Linkage Infrastructure, Equipment and Facilities
    Open grant
  • 2007 - 2009
    Reactive intermediates and microwave-assisted organic reactions
    ARC Discovery Projects
    Open grant
  • 2007
    Research in pre-biotic chemistry
    UQ Travel Grants Scheme
    Open grant
  • 2004
    Research conference grant for Prof Josef Michl, University of Colorado, Boulder, to attend Heron Island Conference on reactive intermediates and unusual molecules, 17-23 July 2004
    Potter Foundation
    Open grant
  • 2004 - 2006
    New mechanisms and methods in carbene and nitrene chemistry
    ARC Discovery Projects
    Open grant
  • 2003 - 2005
    Bimolecular chemistry at very low temperature
    ARC Linkage International
    Open grant
  • 2002
    To expand work on cryogenic matrix isolation research.
    UQ Travel Grants Scheme
    Open grant
  • 2001 - 2003
    Chemistry of Iminopropadienones and Related Compounds.
    ARC Australian Research Council (Large grants)
    Open grant
  • 2000
    Novel approaches to heterocyclic synthesis.
    ARC Australian Research Council (Small grants)
    Open grant
  • 1997
    Brisbane Advanced Mass Spectrometry Facility
    Research Infrastructure (Equip & Fac) Program
    Open grant
  • 1997
    Synthesis of 1,3-diazepines
    ARC Australian Research Council (Small grants)
    Open grant
  • 1996 - 1997
    International Network in Advanced Techniques of Applied Molecular Science
    Quality Funds Round 3
    Open grant
  • 1996
    Pulsed pyrolysis
    ARC Australian Research Council (Small grants)
    Open grant

Supervision

Availability

Emeritus Professor Curt Wentrup is:
Not available for supervision

Supervision history

Completed supervision

  • 2006

    Doctor Philosophy

    SYNTHESES AND REACTIONS OF IMINOPROPADIENONES, SYDNONES AND OXAZINONES

    Principal Advisor

    Other advisors: Professor Craig Williams

  • 2002

    Doctor Philosophy

    HETEROCYCLIC SYNTHESIS BASED ON IMINOPROPADIENONES

    Principal Advisor

  • 2002

    Doctor Philosophy

    SYNTHESIS AND CHARACTERISATION OF 1,3- and 1,4- DIAZEPINES AND DERIVATIVES

    Principal Advisor

  • Doctor Philosophy

    NITRENES REARRANGEMENTS: FORMATION OF REACTIVE INTERMEDIATES AND UNUSUAL MOLECULES

    Principal Advisor

    Other advisors: Professor Craig Williams

Media

Enquiries

Contact Emeritus Professor Curt Wentrup directly for media enquiries about:

  • Organic reaction mechanisms
  • Photochemistry
  • Pyrolysis
  • Reactive intermediates

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