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Emeritus Professor Curt Wentrup
Emeritus Professor

Curt Wentrup

Email: 
Phone: 
+61 7 336 53817

Overview

Background

Educated at the University of Copenhagen, Denmark, and the Australian National University, Canberra. Career at the Université de Lausanne, Switzerland, and the Universität Marburg, Germany. Professor and Chair of Organic Chemistry and Head of the Organic Chemistry Section, The University of Queensland from 1985. Emeritus professor from 2008. Chair of the National Committee for Chemistry of the Australian Academy of Science 2009-2014. Editor-in-Chief, Australian Journal of Chemistry 2008-15. Editor, Journal of Analytical and Applied Pyrolysis (Elsevier, IF 3.65) 2016-. Visiting Professor Université de Pau, France, 2011-19; Visiting Professor University of Kuwait 2014-18; Visiting Professor / Special Appointed Professor Hiroshima University 2014-18. Fellow of the Australian Academy of Science. Centenary Medal of the Australian Commonwealth 2003 for research in organic and physical chemistry. David Craig Medal of the Academy of Science 2014 for research in chemistry. JSPS Fellowship (Japan) 2014. Honorary doctorate, University of Pau, France, 2014. A.J. Birch Medal of the Royal Australian Chemical Institute (RACI) for ecellence in research in organic chemistry, 2014. Leighton Medal of the RACI 2018.

Research on Unusual Molecules and Reactive Intermediates: Synthesis and Reaction Mechanism. Heterocyclic chemistry. Pyrolysis reactions. Photochemistry

Research in the Wentrup group is concerned with the discovery of novel types of molecules with new and unusual bonding patterns. Such molecules are mostly highly reactive, and special methods are required both for their generation and for their detection. The group has developed these methods over many years and acquired world-class equipment for these purposes, including flash vacuum thermolysis apparatus, cryostats for matrix isolation of reaction products at cryogenic temperatures (down to 7 K), matrix and solution photochemistry equipment, infrared, UV and mass spectrometers, as well as modern computational facilities.

This research has resulted in the synthesis and characterization of many novel compounds, including extended cumulenes of the types RN=C=C=C=X, which themselves are used in the synthesis of many novel types of molecules, some of them of potential pharmaceutical interest (quinolone antibiotics; diazepines).

The research group has a world reputation in the field of carbene and nitrene chemistry, involving reactive intermediates with sextet carbon or nitrogen. These species are also very useful in synthesis, for example in the preparation of diazepines and diazepinones, a family of pharmaceutically interesting compounds. Numerous mechanistic studies and synthetic applications of ketenes have been carried out in our group.

Active collaborations are ongoing with scientists in Australia (UQ and CSIRO), China (Suzhou), France (Pau), Germany (Oldenburg), Japan (Hiroshima), Spain (Donostia - San Sebastian), and Portugal (Coimbra).

Availability

Emeritus Professor Curt Wentrup is:
Not available for supervision
Media expert

Qualifications

  • Doctor of Philosophy, Australian National University
  • Doctor of Philosophy of Science (Advanced), University of Copenhagen
  • Doctoral Diploma, Institution to be confirmed
  • Australian Academy of Science, Australian Academy of Science
  • Royal Australian Chemical Institute, Royal Australian Chemical Institute

Research interests

  • Organic, physical, and historical chemistry

    Reactive intermediates, pyrolysis, photochemistry, reaction mechanism. History of science.

Research impacts

This research leads to the development of new pharmaceuticals, e.g. new antibiotics (quinolones and naphthyridones) and new leads towards a treatment for scizophrenia (diazepine molecules).

Chemical industry has used our pyrolysis techniques in specialized manufacturing processes.

Our analytical/spectroscopic work has led to cooperation with chemical and energy firms and agencies involved in forensic science, and our research has generated collaborations with many scientists at universities in Australia, Austria, Belgium, China, Denmark, France, Germany, Hungary, Japan, Portugal, Singapore, Switzerland, and USA.

Works

Search Professor Curt Wentrup’s works on UQ eSpace

433 works between 1966 and 2024

161 - 180 of 433 works

2006

Journal Article

Nitrenes, diradicals, and ylides. Ring expansion and ring opening in 2-quinazolylnitrenes

Kvaskoff, D., Bednarek, P., George, L., Waich, K. and Wentrup, C. (2006). Nitrenes, diradicals, and ylides. Ring expansion and ring opening in 2-quinazolylnitrenes. Journal of Organic Chemistry, 71 (11), 4049-4058. doi: 10.1021/jo052541i

Nitrenes, diradicals, and ylides. Ring expansion and ring opening in 2-quinazolylnitrenes

2005

Journal Article

Ketene-ketenimine rearrangements in the gas phase and in polar media. 1,3-migration intermediates and sequential transition states

Finnerty, Justin J. and Wentrup, Curt (2005). Ketene-ketenimine rearrangements in the gas phase and in polar media. 1,3-migration intermediates and sequential transition states. Journal of Organic Chemistry, 70 (24), 9735-9739. doi: 10.1021/jo051389h

Ketene-ketenimine rearrangements in the gas phase and in polar media. 1,3-migration intermediates and sequential transition states

2005

Journal Article

Erratum: Different behavior of nitrenes and carbenes on photolysis and thermolysis: Formation of azirine, ylidic cumulene, and cyclic ketenimine and the rearrangement of 6-phenanthridylcarbene to 9-phenanthrylnitrene (Journal of Organic Chemistry (2005) 7

Kvaskoff, David, Bednarek, Pawel, George, Lisa, Pankajakshan, Sreekumar and Wentrup, Curt (2005). Erratum: Different behavior of nitrenes and carbenes on photolysis and thermolysis: Formation of azirine, ylidic cumulene, and cyclic ketenimine and the rearrangement of 6-phenanthridylcarbene to 9-phenanthrylnitrene (Journal of Organic Chemistry (2005) 7. Journal of Organic Chemistry, 70 (23), 9666-9666. doi: 10.1021/jo052043

Erratum: Different behavior of nitrenes and carbenes on photolysis and thermolysis: Formation of azirine, ylidic cumulene, and cyclic ketenimine and the rearrangement of 6-phenanthridylcarbene to 9-phenanthrylnitrene (Journal of Organic Chemistry (2005) 7

2005

Journal Article

N-(3,5-dichloro-2-pyridyl) formamide

Reisinger, Ales, Wentrup, Curt, Byriel, Karl A. and Kennard, Colin H. L. (2005). N-(3,5-dichloro-2-pyridyl) formamide. Acta Crystallographica Section E-Structure Reports Online, 61 (7), o2053-o2054. doi: 10.1107/S1600536805017605

N-(3,5-dichloro-2-pyridyl) formamide

2005

Journal Article

N,N-Dialkyl-N'-(2-pyridyl)formamidines and N-(3,5-dichloro-2-pyridyl) formamide. Reactions of azides, tetrazoles and nitrenes with nucleophiles. Part 1

Reisinger, Ales and Wentrup, Curt (2005). N,N-Dialkyl-N'-(2-pyridyl)formamidines and N-(3,5-dichloro-2-pyridyl) formamide. Reactions of azides, tetrazoles and nitrenes with nucleophiles. Part 1. Arkivoc, 2005 (xiv), 131-134. doi: 10.3998/ark.5550190.0006.e15

N,N-Dialkyl-N'-(2-pyridyl)formamidines and N-(3,5-dichloro-2-pyridyl) formamide. Reactions of azides, tetrazoles and nitrenes with nucleophiles. Part 1

2005

Journal Article

A cyclopropabenzenylidenethenone (Propadienone) via a new route to alkylidenecycloproparenes

Halton, B., Dixon, G., Jones, C. M., Parkin, C. T., Naduvile Veedu, R., Bornemann, H. and Wentrup, C. (2005). A cyclopropabenzenylidenethenone (Propadienone) via a new route to alkylidenecycloproparenes. Organic Letters, 7 (5), 949-952. doi: 10.1021/ol050095f

A cyclopropabenzenylidenethenone (Propadienone) via a new route to alkylidenecycloproparenes

2005

Journal Article

Energy profiles for ketene cyclizations. interconversion of 1,3-oxazin-6-ones, mesoionic 1,3-oxazinium olates and acylketenes, imidoylketenes, oxoketenimines, and cyclization products

Bornemann, Holger and Wentrup, Curt (2005). Energy profiles for ketene cyclizations. interconversion of 1,3-oxazin-6-ones, mesoionic 1,3-oxazinium olates and acylketenes, imidoylketenes, oxoketenimines, and cyclization products. Journal of Organic Chemistry, 70 (15), 5862-5868. doi: 10.1021/jo050429e

Energy profiles for ketene cyclizations. interconversion of 1,3-oxazin-6-ones, mesoionic 1,3-oxazinium olates and acylketenes, imidoylketenes, oxoketenimines, and cyclization products

2005

Journal Article

Different behavior of nitrenes and carbenes on photolysis and thermolysis: Formation of azirine, ylidic cumulene, and cyclic ketenimine and the rearrangement of 6-phenanthridylcarbene to 9-phenanthrylnitrene

Kvaskoff, David, Bednarek, Pawel, George, Lisa, Pankajakshan, Sreekumar and Wentrup, Curt (2005). Different behavior of nitrenes and carbenes on photolysis and thermolysis: Formation of azirine, ylidic cumulene, and cyclic ketenimine and the rearrangement of 6-phenanthridylcarbene to 9-phenanthrylnitrene. Journal of Organic Chemistry, 70 (20), 7947-7955. doi: 10.1021/jo050898g

Different behavior of nitrenes and carbenes on photolysis and thermolysis: Formation of azirine, ylidic cumulene, and cyclic ketenimine and the rearrangement of 6-phenanthridylcarbene to 9-phenanthrylnitrene

2005

Journal Article

Imidoylketene-alpha-oxoketenimine and alpha-oxoketene-alpha-oxoketene rearrangements. 1,3-Shifts of substituted phenyl groups

George, Lisa and Wentrup, Curt (2005). Imidoylketene-alpha-oxoketenimine and alpha-oxoketene-alpha-oxoketene rearrangements. 1,3-Shifts of substituted phenyl groups. Organic & Biomolecular Chemistry, 3 (16), 2998-3000. doi: 10.1039/B504260G

Imidoylketene-alpha-oxoketenimine and alpha-oxoketene-alpha-oxoketene rearrangements. 1,3-Shifts of substituted phenyl groups

2005

Journal Article

The curtius rearrangement of acyl azides revisited - formation of cyanate (R-O-CN)

Wentrup, C. and Bornemann, H. (2005). The curtius rearrangement of acyl azides revisited - formation of cyanate (R-O-CN). European Journal of Organic Chemistry, 2005 (21), 4521-4524. doi: 10.1002/ejoc.200500545

The curtius rearrangement of acyl azides revisited - formation of cyanate (R-O-CN)

2005

Journal Article

Mesoionic 1,3-oxazinium olates. Rearrangement to acylketenes and 3-azabicyclo[3.1.1]heptanetriones

Sheibani, H., Bernhardt, P. V. and Wentrup, C. (2005). Mesoionic 1,3-oxazinium olates. Rearrangement to acylketenes and 3-azabicyclo[3.1.1]heptanetriones. Journal of Organic Chemistry, 70 (15), 5859-5861. doi: 10.1021/jo050428m

Mesoionic 1,3-oxazinium olates. Rearrangement to acylketenes and 3-azabicyclo[3.1.1]heptanetriones

2004

Journal Article

2,6,9-Trioxabicyclo[3.3.1]nona-3,7-dien-4-oyl and tetraoxaadamantan-9-oyl functionalized aromatic di- and triamines: Synthesis, stereochemistry and complexation

Heilmayer, W., Smounig, R., Gruber, K., Fabian, W. M. F., Reidlinger, C., Kappe, C. O., Wentrup, C. and Kollenz, G. (2004). 2,6,9-Trioxabicyclo[3.3.1]nona-3,7-dien-4-oyl and tetraoxaadamantan-9-oyl functionalized aromatic di- and triamines: Synthesis, stereochemistry and complexation. Tetrahedron, 60 (12), 2857-2867. doi: 10.1016/j.tet.2004.01.058

2,6,9-Trioxabicyclo[3.3.1]nona-3,7-dien-4-oyl and tetraoxaadamantan-9-oyl functionalized aromatic di- and triamines: Synthesis, stereochemistry and complexation

2004

Journal Article

2-benzyl-1-hydroxy-5,6,-dihydro-3H-naptho[2,1-b]pyran-3-one

Wentrup, Curt, Buchanan, Jeff, Byriel, Karl A. and Kennard, Colin H. L. (2004). 2-benzyl-1-hydroxy-5,6,-dihydro-3H-naptho[2,1-b]pyran-3-one. Acta Crystallographica Section E, 60 (3), o471-o472. doi: 10.1107/S1600536804003848

2-benzyl-1-hydroxy-5,6,-dihydro-3H-naptho[2,1-b]pyran-3-one

2004

Journal Article

Synthesis of 1,3-diazepines and ring contraction to cyanopyrroles

Reisinger, Ales, Bernhardt, Paul V. and Wentrup, Curt (2004). Synthesis of 1,3-diazepines and ring contraction to cyanopyrroles. Organic & Biomolecular Chemistry, 2 (2), 246-256. doi: 10.1039/b311247k

Synthesis of 1,3-diazepines and ring contraction to cyanopyrroles

2004

Journal Article

Facile ketene-ketene and ketene-ketenimine rearrangements: A study of the 1,3-migration of alpha-substituents interconverting alpha-imidoylketenes and alpha-oxoketenimines, a pseudopericyclic reaction

Finnerty, J. J. and Wentrup, C. (2004). Facile ketene-ketene and ketene-ketenimine rearrangements: A study of the 1,3-migration of alpha-substituents interconverting alpha-imidoylketenes and alpha-oxoketenimines, a pseudopericyclic reaction. Journal of Organic Chemistry, 69 (6), 1909-1918. doi: 10.1021/jo035419x

Facile ketene-ketene and ketene-ketenimine rearrangements: A study of the 1,3-migration of alpha-substituents interconverting alpha-imidoylketenes and alpha-oxoketenimines, a pseudopericyclic reaction

2004

Journal Article

Ketene-acetylene [2+2] cycloadditions: cyclobutenone and/or oxete formation?

Koch, R. and Wentrup, C. (2004). Ketene-acetylene [2+2] cycloadditions: cyclobutenone and/or oxete formation?. Organic & Biomolecular Chemistry, 2 (2), 195-199. doi: 10.1039/b309549e

Ketene-acetylene [2+2] cycloadditions: cyclobutenone and/or oxete formation?

2004

Journal Article

Imidoylketene dimerization and rearrangement

George, L., Bernhardt, P. V., Netsch, K. P. and Wentrup, C. (2004). Imidoylketene dimerization and rearrangement. Organic & Biomolecular Chemistry, 2 (23), 3518-3523. doi: 10.1039/b412530d

Imidoylketene dimerization and rearrangement

2004

Journal Article

The rearrangements of naphthyinitrenes: UV/Vis and IR spectra of azirines, cyclic ketenimines, and cyclic nitrile ylides

Maltsev, A., Bally, T., Tsao, M. L., Platz, M. S., Kuhn, A., Vosswinkel, M. and Wentrup, C. (2004). The rearrangements of naphthyinitrenes: UV/Vis and IR spectra of azirines, cyclic ketenimines, and cyclic nitrile ylides. Journal of The American Chemical Society, 126 (1), 237-249. doi: 10.1021/ja038458z

The rearrangements of naphthyinitrenes: UV/Vis and IR spectra of azirines, cyclic ketenimines, and cyclic nitrile ylides

2004

Journal Article

Macrocyclic systems containing 2,6,9-trioxabicyclo[3.3.1]-nona-3,7-dienes as chiral spacer groups: Synthesis, stereochemical features and preliminary complexation properties

Chebanov, V. A., Reidlinger, C., Kanaani, H., Wentrup, C., Kappe, C. O. and Kollenz, G. (2004). Macrocyclic systems containing 2,6,9-trioxabicyclo[3.3.1]-nona-3,7-dienes as chiral spacer groups: Synthesis, stereochemical features and preliminary complexation properties. Supramolecular Chemistry, 16 (2), 121-127. doi: 10.1080/10610270310001614197

Macrocyclic systems containing 2,6,9-trioxabicyclo[3.3.1]-nona-3,7-dienes as chiral spacer groups: Synthesis, stereochemical features and preliminary complexation properties

2004

Journal Article

1H-1,3-Diazepines, 5H-1,3-diazepines, 1,3-diazepinones, and 2,4-diazabicyclo[3.2.0]heptenes

Reisinger, A., Koch, R., Bernhardt, P. V. and Wentrup, C. (2004). 1H-1,3-Diazepines, 5H-1,3-diazepines, 1,3-diazepinones, and 2,4-diazabicyclo[3.2.0]heptenes. Organic & Biomolecular Chemistry, 2 (8), 1227-1238. doi: 10.1039/b317099c

1H-1,3-Diazepines, 5H-1,3-diazepines, 1,3-diazepinones, and 2,4-diazabicyclo[3.2.0]heptenes

Funding

Past funding

  • 2012 - 2013
    Heron Island Conference on reactive intermediate and unusual molecules
    Ian Potter Foundation
    Open grant
  • 2010
    UQ Travel Awards Category 1, Fabian Borget
    UQ Travel Grants Scheme
    Open grant
  • 2007 - 2008
    An X-Ray Diffraction Facility for Molecular Structure Determination
    ARC Linkage Infrastructure, Equipment and Facilities
    Open grant
  • 2007 - 2009
    Reactive intermediates and microwave-assisted organic reactions
    ARC Discovery Projects
    Open grant
  • 2007
    Research in pre-biotic chemistry
    UQ Travel Grants Scheme
    Open grant
  • 2004
    Research conference grant for Prof Josef Michl, University of Colorado, Boulder, to attend Heron Island Conference on reactive intermediates and unusual molecules, 17-23 July 2004
    Potter Foundation
    Open grant
  • 2004 - 2006
    New mechanisms and methods in carbene and nitrene chemistry
    ARC Discovery Projects
    Open grant
  • 2003 - 2005
    Bimolecular chemistry at very low temperature
    ARC Linkage International
    Open grant
  • 2002
    To expand work on cryogenic matrix isolation research.
    UQ Travel Grants Scheme
    Open grant
  • 2001 - 2003
    Chemistry of Iminopropadienones and Related Compounds.
    ARC Australian Research Council (Large grants)
    Open grant
  • 2000
    Novel approaches to heterocyclic synthesis.
    ARC Australian Research Council (Small grants)
    Open grant
  • 1997
    Brisbane Advanced Mass Spectrometry Facility
    Research Infrastructure (Equip & Fac) Program
    Open grant
  • 1997
    Synthesis of 1,3-diazepines
    ARC Australian Research Council (Small grants)
    Open grant
  • 1996 - 1997
    International Network in Advanced Techniques of Applied Molecular Science
    Quality Funds Round 3
    Open grant
  • 1996
    Pulsed pyrolysis
    ARC Australian Research Council (Small grants)
    Open grant

Supervision

Availability

Emeritus Professor Curt Wentrup is:
Not available for supervision

Supervision history

Completed supervision

  • 2006

    Doctor Philosophy

    SYNTHESES AND REACTIONS OF IMINOPROPADIENONES, SYDNONES AND OXAZINONES

    Principal Advisor

    Other advisors: Professor Craig Williams

  • 2002

    Doctor Philosophy

    HETEROCYCLIC SYNTHESIS BASED ON IMINOPROPADIENONES

    Principal Advisor

  • 2002

    Doctor Philosophy

    SYNTHESIS AND CHARACTERISATION OF 1,3- and 1,4- DIAZEPINES AND DERIVATIVES

    Principal Advisor

  • Doctor Philosophy

    NITRENES REARRANGEMENTS: FORMATION OF REACTIVE INTERMEDIATES AND UNUSUAL MOLECULES

    Principal Advisor

    Other advisors: Professor Craig Williams

Media

Enquiries

Contact Emeritus Professor Curt Wentrup directly for media enquiries about:

  • Organic reaction mechanisms
  • Photochemistry
  • Pyrolysis
  • Reactive intermediates

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