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Emeritus Professor Curt Wentrup
Emeritus Professor

Curt Wentrup

Email: 
Phone: 
+61 7 336 53817

Overview

Background

Educated at the University of Copenhagen, Denmark, and the Australian National University, Canberra. Career at the Université de Lausanne, Switzerland, and the Universität Marburg, Germany. Professor and Chair of Organic Chemistry and Head of the Organic Chemistry Section, The University of Queensland from 1985. Emeritus professor from 2008. Chair of the National Committee for Chemistry of the Australian Academy of Science 2009-2014. Editor-in-Chief, Australian Journal of Chemistry 2008-15. Editor, Journal of Analytical and Applied Pyrolysis (Elsevier, IF 3.65) 2016-. Visiting Professor Université de Pau, France, 2011-19; Visiting Professor University of Kuwait 2014-18; Visiting Professor / Special Appointed Professor Hiroshima University 2014-18. Fellow of the Australian Academy of Science. Centenary Medal of the Australian Commonwealth 2003 for research in organic and physical chemistry. David Craig Medal of the Academy of Science 2014 for research in chemistry. JSPS Fellowship (Japan) 2014. Honorary doctorate, University of Pau, France, 2014. A.J. Birch Medal of the Royal Australian Chemical Institute (RACI) for ecellence in research in organic chemistry, 2014. Leighton Medal of the RACI 2018.

Research on Unusual Molecules and Reactive Intermediates: Synthesis and Reaction Mechanism. Heterocyclic chemistry. Pyrolysis reactions. Photochemistry

Research in the Wentrup group is concerned with the discovery of novel types of molecules with new and unusual bonding patterns. Such molecules are mostly highly reactive, and special methods are required both for their generation and for their detection. The group has developed these methods over many years and acquired world-class equipment for these purposes, including flash vacuum thermolysis apparatus, cryostats for matrix isolation of reaction products at cryogenic temperatures (down to 7 K), matrix and solution photochemistry equipment, infrared, UV and mass spectrometers, as well as modern computational facilities.

This research has resulted in the synthesis and characterization of many novel compounds, including extended cumulenes of the types RN=C=C=C=X, which themselves are used in the synthesis of many novel types of molecules, some of them of potential pharmaceutical interest (quinolone antibiotics; diazepines).

The research group has a world reputation in the field of carbene and nitrene chemistry, involving reactive intermediates with sextet carbon or nitrogen. These species are also very useful in synthesis, for example in the preparation of diazepines and diazepinones, a family of pharmaceutically interesting compounds. Numerous mechanistic studies and synthetic applications of ketenes have been carried out in our group.

Active collaborations are ongoing with scientists in Australia (UQ and CSIRO), China (Suzhou), France (Pau), Germany (Oldenburg), Japan (Hiroshima), Spain (Donostia - San Sebastian), and Portugal (Coimbra).

Availability

Emeritus Professor Curt Wentrup is:
Not available for supervision
Media expert

Qualifications

  • Doctor of Philosophy, Australian National University
  • Doctor of Philosophy of Science (Advanced), University of Copenhagen
  • Doctoral Diploma, Institution to be confirmed
  • Australian Academy of Science, Australian Academy of Science
  • Royal Australian Chemical Institute, Royal Australian Chemical Institute

Research interests

  • Organic, physical, and historical chemistry

    Reactive intermediates, pyrolysis, photochemistry, reaction mechanism. History of science.

Research impacts

This research leads to the development of new pharmaceuticals, e.g. new antibiotics (quinolones and naphthyridones) and new leads towards a treatment for scizophrenia (diazepine molecules).

Chemical industry has used our pyrolysis techniques in specialized manufacturing processes.

Our analytical/spectroscopic work has led to cooperation with chemical and energy firms and agencies involved in forensic science, and our research has generated collaborations with many scientists at universities in Australia, Austria, Belgium, China, Denmark, France, Germany, Hungary, Japan, Portugal, Singapore, Switzerland, and USA.

Works

Search Professor Curt Wentrup’s works on UQ eSpace

433 works between 1966 and 2024

301 - 320 of 433 works

1992

Journal Article

Characterization of Iminopropadienone Ions and Neutrals in a Tandem Mass-Spectrometer

Flammang, R, Laurent, S, Flammangbarbieux, M and Wentrup, C (1992). Characterization of Iminopropadienone Ions and Neutrals in a Tandem Mass-Spectrometer. Rapid Communications in Mass Spectrometry, 6 (11), 667-670. doi: 10.1002/rcm.1290061108

Characterization of Iminopropadienone Ions and Neutrals in a Tandem Mass-Spectrometer

1992

Journal Article

Flash Vacuum Pyrolysis of Tert-Butyl Beta-Ketoesters - Sterically Protected Alpha-Oxoketenes

Leungtoung, R and Wentrup, C (1992). Flash Vacuum Pyrolysis of Tert-Butyl Beta-Ketoesters - Sterically Protected Alpha-Oxoketenes. Tetrahedron, 48 (36), 7641-7654. doi: 10.1016/S0040-4020(01)90376-X

Flash Vacuum Pyrolysis of Tert-Butyl Beta-Ketoesters - Sterically Protected Alpha-Oxoketenes

1992

Journal Article

A NOVEL AND CONVENIENT APPROACH TO FUNCTIONALIZED 2,6,9-TRIOXABICYCLO[3.3.1]NONA-3,7-DIENES (BRIDGED BIS-DIOXINES)

KAPPE, CO, FARBER, G, WENTRUP, C and KOLLENZ, G (1992). A NOVEL AND CONVENIENT APPROACH TO FUNCTIONALIZED 2,6,9-TRIOXABICYCLO[3.3.1]NONA-3,7-DIENES (BRIDGED BIS-DIOXINES). Tetrahedron Letters, 33 (32), 4553-4556. doi: 10.1016/S0040-4039(00)61310-2

A NOVEL AND CONVENIENT APPROACH TO FUNCTIONALIZED 2,6,9-TRIOXABICYCLO[3.3.1]NONA-3,7-DIENES (BRIDGED BIS-DIOXINES)

1992

Journal Article

DIRECT OBSERVATION OF BENZOYLKETENES

ANDREICHIKOV, YS, KOLLENZ, G, KAPPE, CO, LEUNGTOUNG, R and WENTRUP, C (1992). DIRECT OBSERVATION OF BENZOYLKETENES. Acta Chemica Scandinavica, 46 (7), 683-685. doi: 10.3891/acta.chem.scand.46-0683

DIRECT OBSERVATION OF BENZOYLKETENES

1992

Journal Article

HCN DIMERS - PHOTOELECTRON-SPECTRUM OF IMINOACETONITRILE

EVANS, RA, LACOMBE, SM, SIMON, MJ, PFISTERGUILLOUZO, G and WENTRUP, C (1992). HCN DIMERS - PHOTOELECTRON-SPECTRUM OF IMINOACETONITRILE. Journal of Physical Chemistry, 96 (12), 4801-4804. doi: 10.1021/j100191a015

HCN DIMERS - PHOTOELECTRON-SPECTRUM OF IMINOACETONITRILE

1992

Journal Article

An ab Initio Study of a Retro-Wolff Rearrangement: From Diazafulvenone to Cyanovinyl Isocyanate without a Singlet α-Oxocarbene Intermediate

Nguyen M.T., Hajnal M.R., Tae-Kyu H., Vanquickenborne L.G. and Wentrup C. (1992). An ab Initio Study of a Retro-Wolff Rearrangement: From Diazafulvenone to Cyanovinyl Isocyanate without a Singlet α-Oxocarbene Intermediate. Journal of the American Chemical Society, 114 (11), 4387-4390. doi: 10.1021/ja00037a054

An ab Initio Study of a Retro-Wolff Rearrangement: From Diazafulvenone to Cyanovinyl Isocyanate without a Singlet α-Oxocarbene Intermediate

1992

Journal Article

Electron-Impact and Chemical Ionization Mass-Spectrometry of Heterocumulenes Produced by Flash Vacuum Pyrolysis

Brown, J, Flammang, R, Govaert, Y, Plisnier, M, Wentrup, C and Vanhaverbeke, Y (1992). Electron-Impact and Chemical Ionization Mass-Spectrometry of Heterocumulenes Produced by Flash Vacuum Pyrolysis. Rapid Communications in Mass Spectrometry, 6 (4), 249-253. doi: 10.1002/rcm.1290060405

Electron-Impact and Chemical Ionization Mass-Spectrometry of Heterocumulenes Produced by Flash Vacuum Pyrolysis

1992

Journal Article

INFRARED-SPECTRUM OF DINITROGEN SULFIDE

KAMBOURIS, P, HA, TK and WENTRUP, C (1992). INFRARED-SPECTRUM OF DINITROGEN SULFIDE. Journal of Physical Chemistry, 96 (5), 2065-2068. doi: 10.1021/j100184a010

INFRARED-SPECTRUM OF DINITROGEN SULFIDE

1992

Journal Article

Methyleneketene Imidoylketene Oxoketenimine Rearrangements

Kappe, CO, Kollenz, G, Regis, LT and Wentrup, C (1992). Methyleneketene Imidoylketene Oxoketenimine Rearrangements. Journal of the Chemical Society-Chemical Communications (6), 487-488. doi: 10.1039/c39920000487

Methyleneketene Imidoylketene Oxoketenimine Rearrangements

1992

Journal Article

Imidoylketene Azetin-2-One Oxoketenimine Rearrangement

Kappe, CO, Kollenz, G, Netsch, KP, Regis, LT and Wentrup, C (1992). Imidoylketene Azetin-2-One Oxoketenimine Rearrangement. Journal of the Chemical Society-Chemical Communications (6), 488-490. doi: 10.1039/c39920000488

Imidoylketene Azetin-2-One Oxoketenimine Rearrangement

1992

Journal Article

A Nitroketene to Nitrile Oxide Transformation

Kappe, CO, Kollenz, G and Wentrup, C (1992). A Nitroketene to Nitrile Oxide Transformation. Journal of the Chemical Society-Chemical Communications, 23 (6), 485-486. doi: 10.1039/c39920000485

A Nitroketene to Nitrile Oxide Transformation

1992

Journal Article

UNIMOLECULAR CHEMISTRY OF OXAZOLE AND ISOXAZOLE RADICAL CATIONS IN THE GAS-PHASE - COMBINED EXPERIMENTAL AND MOLECULAR-ORBITAL STUDY

FLAMMANG, R, PLISNIER, M, BOUCHOUX, G, HOPPILLIARD, Y, HUMBERT, S and WENTRUP, C (1992). UNIMOLECULAR CHEMISTRY OF OXAZOLE AND ISOXAZOLE RADICAL CATIONS IN THE GAS-PHASE - COMBINED EXPERIMENTAL AND MOLECULAR-ORBITAL STUDY. Organic Mass Spectrometry, 27 (3), 317-325. doi: 10.1002/oms.1210270326

UNIMOLECULAR CHEMISTRY OF OXAZOLE AND ISOXAZOLE RADICAL CATIONS IN THE GAS-PHASE - COMBINED EXPERIMENTAL AND MOLECULAR-ORBITAL STUDY

1992

Journal Article

Direct observation of α-oxo ketenes from the photolysis of α-diazo β-diketones

Leung-Toung R. and Wentrup C. (1992). Direct observation of α-oxo ketenes from the photolysis of α-diazo β-diketones. Journal of Organic Chemistry, 57 (18), 4850-4858. doi: 10.1021/jo00044a019

Direct observation of α-oxo ketenes from the photolysis of α-diazo β-diketones

1992

Journal Article

Iminopropadienones, RN=C=C=C=O: Syntheses and reactions

Mosandl T., Kappe C.O., Flammang R. and Wentrup C. (1992). Iminopropadienones, RN=C=C=C=O: Syntheses and reactions. Journal of the Chemical Society-Chemical Communications, 24 (21), 1571-1573. doi: 10.1039/C39920001571

Iminopropadienones, RN=C=C=C=O: Syntheses and reactions

1992

Journal Article

Trifluoromethyl-substituted dehydrodiazepines and cyanopyrroles from azido-/tetrazolo-pyridines

Evans R.A. and Wentrup C. (1992). Trifluoromethyl-substituted dehydrodiazepines and cyanopyrroles from azido-/tetrazolo-pyridines. Journal of the Chemical Society, Chemical Communications, 23 (15), 1062-1064. doi: 10.1039/C39920001062

Trifluoromethyl-substituted dehydrodiazepines and cyanopyrroles from azido-/tetrazolo-pyridines

1991

Journal Article

HCN DIMERS - IMINOACETONITRILE AND N-CYANOMETHANIMINE

EVANS, RA, LORENCAK, P, HA, TK and WENTRUP, C (1991). HCN DIMERS - IMINOACETONITRILE AND N-CYANOMETHANIMINE. Journal of the American Chemical Society, 113 (19), 7261-7276. doi: 10.1021/ja00019a026

HCN DIMERS - IMINOACETONITRILE AND N-CYANOMETHANIMINE

1991

Journal Article

N-SULFIDES - DINITROGEN SULFIDE, THIOFULMINIC ACID, AND NITRILE SULFIDES

WENTRUP, C and KAMBOURIS, P (1991). N-SULFIDES - DINITROGEN SULFIDE, THIOFULMINIC ACID, AND NITRILE SULFIDES. Chemical Reviews, 91 (3), 363-373. doi: 10.1021/cr00003a004

N-SULFIDES - DINITROGEN SULFIDE, THIOFULMINIC ACID, AND NITRILE SULFIDES

1991

Journal Article

THIOFULMINIC ACID (H-C=N-]S) AND NITRILE SULFIDES (R-C=N-]S) IN THE GAS-PHASE

KAMBOURIS, P, PLISNIER, M, FLAMMANG, R, TERLOUW, JK and WENTRUP, C (1991). THIOFULMINIC ACID (H-C=N-]S) AND NITRILE SULFIDES (R-C=N-]S) IN THE GAS-PHASE. Tetrahedron Letters, 32 (11), 1487-1490. doi: 10.1016/0040-4039(91)80365-D

THIOFULMINIC ACID (H-C=N-]S) AND NITRILE SULFIDES (R-C=N-]S) IN THE GAS-PHASE

1991

Journal Article

SYNTHESIS OF ALPHA-CYANO CARBONYL-COMPOUNDS BY FLASH VACUUM THERMOLYSIS OF (ALKYLAMINO)METHYLENE DERIVATIVES OF MELDRUMS ACID - EVIDENCE FOR FACILE 1,3-SHIFTS OF ALKYLAMINO AND ALKYLTHIO GROUPS IN IMIDOYLKETENE INTERMEDIATES

BENCHEIKH, A, CHUCHE, J, MANISSE, N, POMMELET, JC, NETSCH, KP, LORENCAK, P and WENTRUP, C (1991). SYNTHESIS OF ALPHA-CYANO CARBONYL-COMPOUNDS BY FLASH VACUUM THERMOLYSIS OF (ALKYLAMINO)METHYLENE DERIVATIVES OF MELDRUMS ACID - EVIDENCE FOR FACILE 1,3-SHIFTS OF ALKYLAMINO AND ALKYLTHIO GROUPS IN IMIDOYLKETENE INTERMEDIATES. Journal of Organic Chemistry, 56 (3), 970-975. doi: 10.1021/jo00003a014

SYNTHESIS OF ALPHA-CYANO CARBONYL-COMPOUNDS BY FLASH VACUUM THERMOLYSIS OF (ALKYLAMINO)METHYLENE DERIVATIVES OF MELDRUMS ACID - EVIDENCE FOR FACILE 1,3-SHIFTS OF ALKYLAMINO AND ALKYLTHIO GROUPS IN IMIDOYLKETENE INTERMEDIATES

1991

Journal Article

Direct observation of α-oxo ketenes formed from 1,3-dioxin-4-ones and the enols of β-keto esters

Freiermuth B. and Wentrup C. (1991). Direct observation of α-oxo ketenes formed from 1,3-dioxin-4-ones and the enols of β-keto esters. Journal of Organic Chemistry, 56 (7), 2286-2289. doi: 10.1021/jo00007a008

Direct observation of α-oxo ketenes formed from 1,3-dioxin-4-ones and the enols of β-keto esters

Funding

Past funding

  • 2012 - 2013
    Heron Island Conference on reactive intermediate and unusual molecules
    Ian Potter Foundation
    Open grant
  • 2010
    UQ Travel Awards Category 1, Fabian Borget
    UQ Travel Grants Scheme
    Open grant
  • 2007 - 2008
    An X-Ray Diffraction Facility for Molecular Structure Determination
    ARC Linkage Infrastructure, Equipment and Facilities
    Open grant
  • 2007 - 2009
    Reactive intermediates and microwave-assisted organic reactions
    ARC Discovery Projects
    Open grant
  • 2007
    Research in pre-biotic chemistry
    UQ Travel Grants Scheme
    Open grant
  • 2004
    Research conference grant for Prof Josef Michl, University of Colorado, Boulder, to attend Heron Island Conference on reactive intermediates and unusual molecules, 17-23 July 2004
    Potter Foundation
    Open grant
  • 2004 - 2006
    New mechanisms and methods in carbene and nitrene chemistry
    ARC Discovery Projects
    Open grant
  • 2003 - 2005
    Bimolecular chemistry at very low temperature
    ARC Linkage International
    Open grant
  • 2002
    To expand work on cryogenic matrix isolation research.
    UQ Travel Grants Scheme
    Open grant
  • 2001 - 2003
    Chemistry of Iminopropadienones and Related Compounds.
    ARC Australian Research Council (Large grants)
    Open grant
  • 2000
    Novel approaches to heterocyclic synthesis.
    ARC Australian Research Council (Small grants)
    Open grant
  • 1997
    Brisbane Advanced Mass Spectrometry Facility
    Research Infrastructure (Equip & Fac) Program
    Open grant
  • 1997
    Synthesis of 1,3-diazepines
    ARC Australian Research Council (Small grants)
    Open grant
  • 1996 - 1997
    International Network in Advanced Techniques of Applied Molecular Science
    Quality Funds Round 3
    Open grant
  • 1996
    Pulsed pyrolysis
    ARC Australian Research Council (Small grants)
    Open grant

Supervision

Availability

Emeritus Professor Curt Wentrup is:
Not available for supervision

Supervision history

Completed supervision

  • 2006

    Doctor Philosophy

    SYNTHESES AND REACTIONS OF IMINOPROPADIENONES, SYDNONES AND OXAZINONES

    Principal Advisor

    Other advisors: Professor Craig Williams

  • 2002

    Doctor Philosophy

    HETEROCYCLIC SYNTHESIS BASED ON IMINOPROPADIENONES

    Principal Advisor

  • 2002

    Doctor Philosophy

    SYNTHESIS AND CHARACTERISATION OF 1,3- and 1,4- DIAZEPINES AND DERIVATIVES

    Principal Advisor

  • Doctor Philosophy

    NITRENES REARRANGEMENTS: FORMATION OF REACTIVE INTERMEDIATES AND UNUSUAL MOLECULES

    Principal Advisor

    Other advisors: Professor Craig Williams

Media

Enquiries

Contact Emeritus Professor Curt Wentrup directly for media enquiries about:

  • Organic reaction mechanisms
  • Photochemistry
  • Pyrolysis
  • Reactive intermediates

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