
Overview
Background
Educated at the University of Copenhagen, Denmark, and the Australian National University, Canberra. Career at the Université de Lausanne, Switzerland, and the Universität Marburg, Germany. Professor and Chair of Organic Chemistry and Head of the Organic Chemistry Section, The University of Queensland from 1985. Emeritus professor from 2008. Chair of the National Committee for Chemistry of the Australian Academy of Science 2009-2014. Editor-in-Chief, Australian Journal of Chemistry 2008-15. Editor, Journal of Analytical and Applied Pyrolysis (Elsevier, IF 3.65) 2016-. Visiting Professor Université de Pau, France, 2011-19; Visiting Professor University of Kuwait 2014-18; Visiting Professor / Special Appointed Professor Hiroshima University 2014-18. Fellow of the Australian Academy of Science. Centenary Medal of the Australian Commonwealth 2003 for research in organic and physical chemistry. David Craig Medal of the Academy of Science 2014 for research in chemistry. JSPS Fellowship (Japan) 2014. Honorary doctorate, University of Pau, France, 2014. A.J. Birch Medal of the Royal Australian Chemical Institute (RACI) for ecellence in research in organic chemistry, 2014. Leighton Medal of the RACI 2018.
Research on Unusual Molecules and Reactive Intermediates: Synthesis and Reaction Mechanism. Heterocyclic chemistry. Pyrolysis reactions. Photochemistry
Research in the Wentrup group is concerned with the discovery of novel types of molecules with new and unusual bonding patterns. Such molecules are mostly highly reactive, and special methods are required both for their generation and for their detection. The group has developed these methods over many years and acquired world-class equipment for these purposes, including flash vacuum thermolysis apparatus, cryostats for matrix isolation of reaction products at cryogenic temperatures (down to 7 K), matrix and solution photochemistry equipment, infrared, UV and mass spectrometers, as well as modern computational facilities.
This research has resulted in the synthesis and characterization of many novel compounds, including extended cumulenes of the types RN=C=C=C=X, which themselves are used in the synthesis of many novel types of molecules, some of them of potential pharmaceutical interest (quinolone antibiotics; diazepines).
The research group has a world reputation in the field of carbene and nitrene chemistry, involving reactive intermediates with sextet carbon or nitrogen. These species are also very useful in synthesis, for example in the preparation of diazepines and diazepinones, a family of pharmaceutically interesting compounds. Numerous mechanistic studies and synthetic applications of ketenes have been carried out in our group.
Active collaborations are ongoing with scientists in Australia (UQ and CSIRO), China (Suzhou), France (Pau), Germany (Oldenburg), Japan (Hiroshima), Spain (Donostia - San Sebastian), and Portugal (Coimbra).
Availability
- Emeritus Professor Curt Wentrup is:
- Not available for supervision
- Media expert
Fields of research
Qualifications
- Doctor of Philosophy, Australian National University
- Doctor of Philosophy of Science (Advanced), University of Copenhagen
- Doctoral Diploma, Institution to be confirmed
- Australian Academy of Science, Australian Academy of Science
- Royal Australian Chemical Institute, Royal Australian Chemical Institute
Research interests
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Organic, physical, and historical chemistry
Reactive intermediates, pyrolysis, photochemistry, reaction mechanism. History of science.
Research impacts
This research leads to the development of new pharmaceuticals, e.g. new antibiotics (quinolones and naphthyridones) and new leads towards a treatment for scizophrenia (diazepine molecules).
Chemical industry has used our pyrolysis techniques in specialized manufacturing processes.
Our analytical/spectroscopic work has led to cooperation with chemical and energy firms and agencies involved in forensic science, and our research has generated collaborations with many scientists at universities in Australia, Austria, Belgium, China, Denmark, France, Germany, Hungary, Japan, Portugal, Singapore, Switzerland, and USA.
Works
Search Professor Curt Wentrup’s works on UQ eSpace
1982
Journal Article
Direct Observation of 1-Azafulven-6-One and Annelated Derivatives
Gross, G and Wentrup, C (1982). Direct Observation of 1-Azafulven-6-One and Annelated Derivatives. Journal of the Chemical Society-Chemical Communications (6), 360-361. doi: 10.1039/c39820000360
1982
Journal Article
COLLISIONAL ACTIVATION OF BENZONITRILIMINE RADICAL CATION AND SOME OF ITS ISOMERS
MAQUESTIAU, A, FLAMMANG, R, PAUWELS, P, BOUCHOUX, G, FISCHER, S and WENTRUP, C (1982). COLLISIONAL ACTIVATION OF BENZONITRILIMINE RADICAL CATION AND SOME OF ITS ISOMERS. Bulletin Des Societes Chimiques Belges, 91 (6), 565-567.
1981
Journal Article
ISOCYANOAMINES, R-NH-NC
WENTRUP, C and WINTER, HW (1981). ISOCYANOAMINES, R-NH-NC. Journal of Organic Chemistry, 46 (5), 1045-1046. doi: 10.1021/jo00318a049
1981
Journal Article
Dissociation of the Diphenylnitrile Imine Radical Cation Into Benzonitrile and [Phenylnitrene]+
Wentrup, C, Maquestiau, A and Flammang, R (1981). Dissociation of the Diphenylnitrile Imine Radical Cation Into Benzonitrile and [Phenylnitrene]+. Organic Mass Spectrometry, 16 (3), 115-117. doi: 10.1002/oms.1210160303
1981
Journal Article
CORRECTION
WENTRUP, C (1981). CORRECTION. Journal of Organic Chemistry, 46 (26), 5459-5459. doi: 10.1021/jo00339a609
1981
Journal Article
ORGANIC FULMINATES, R-O-NC .2.
WENTRUP, C, GERECHT, B, LAQUA, D, BRIEHL, H, WINTER, HW, REISENAUER, HP and WINNEWISSER, M (1981). ORGANIC FULMINATES, R-O-NC .2.. Journal of Organic Chemistry, 46 (5), 1046-1048. doi: 10.1021/jo00318a050
1981
Journal Article
THEORY AND APPLICATION OF PHOTO-ELECTRON SPECTROSCOPY .94. ISOBENZOFULVENE
GROSS, G, SCHULZ, R, SCHWEIG, A and WENTRUP, C (1981). THEORY AND APPLICATION OF PHOTO-ELECTRON SPECTROSCOPY .94. ISOBENZOFULVENE. Angewandte Chemie-International Edition in English, 20 (12), 1021-1023. doi: 10.1002/anie.198110212
1980
Journal Article
HETARYLNITRENES .8. ISOLATION OF DIAZACYCLOHEPTATETRAENES FROM THERMAL NITRENE-NITRENE REARRANGEMENTS
WENTRUP, C and WINTER, HW (1980). HETARYLNITRENES .8. ISOLATION OF DIAZACYCLOHEPTATETRAENES FROM THERMAL NITRENE-NITRENE REARRANGEMENTS. Journal of the American Chemical Society, 102 (19), 6159-6161. doi: 10.1021/ja00539a039
1980
Journal Article
NITRILE IMINE AND CARBENE REARRANGEMENTS - FROM FURFURAL TO BENZOFULVENE-8-CARBOXALDEHYDE, 8-BENZOFULVENYLCARBENE, AND 1-VINYLIDENEINDENE
WENTRUP, C and BENEDIKT, J (1980). NITRILE IMINE AND CARBENE REARRANGEMENTS - FROM FURFURAL TO BENZOFULVENE-8-CARBOXALDEHYDE, 8-BENZOFULVENYLCARBENE, AND 1-VINYLIDENEINDENE. Journal of Organic Chemistry, 45 (8), 1407-1409. doi: 10.1021/jo01296a012
1980
Journal Article
HETARYLNITRENES .7. CYCLIC CARBODIIMIDES IN NITRENE REARRANGEMENTS
WENTRUP, C, THETAZ, C, TAGLIAFERRI, E, LINDNER, HJ, KITSCHKE, B, WINTER, HW and REISENAUER, HP (1980). HETARYLNITRENES .7. CYCLIC CARBODIIMIDES IN NITRENE REARRANGEMENTS. Angewandte Chemie-International Edition in English, 19 (7), 566-567. doi: 10.1002/anie.198005661
1980
Journal Article
Nitrile Imide-Imidoylnitrene-Carbodi-Imide Rearrangement
Fischer, S and Wentrup, C (1980). Nitrile Imide-Imidoylnitrene-Carbodi-Imide Rearrangement. Journal of the Chemical Society-Chemical Communications, 45 (11), 502-503. doi: 10.1039/c39800000502
1980
Journal Article
ISOMERIZATION OF 1-NAPHTHYLCARBENE AND 2-NAPHTHYLCARBENE TO CYCLOBUTA[DE]NAPHTHALENE
BECKER, J and WENTRUP, C (1980). ISOMERIZATION OF 1-NAPHTHYLCARBENE AND 2-NAPHTHYLCARBENE TO CYCLOBUTA[DE]NAPHTHALENE. Journal of the Chemical Society-Chemical Communications (4), 190-191. doi: 10.1039/c39800000190
1980
Journal Article
THE 1,4-HYDROGEN SHIFT IN NITRILE YLIDES
BERSTERMANN, HM, NETSCH, KP and WENTRUP, C (1980). THE 1,4-HYDROGEN SHIFT IN NITRILE YLIDES. Journal of the Chemical Society-Chemical Communications (11), 503-504. doi: 10.1039/c39800000503
1980
Journal Article
CARBENE REACTIONS .14. GENERATION OF CYCLOHEPTATRIENYLIDENE BY VAPOR-PHASE THERMOLYSIS OF C7H7-ACETATES
HOFFMANN, RW, LOOF, IH and WENTRUP, C (1980). CARBENE REACTIONS .14. GENERATION OF CYCLOHEPTATRIENYLIDENE BY VAPOR-PHASE THERMOLYSIS OF C7H7-ACETATES. Liebigs Annalen der Chemie (8), 1198-1206.
1980
Journal Article
AZULENE-NAPHTHALENE REARRANGEMENT - INVOLVEMENT OF 1-PHENYLBUTEN-3-YNES AND 4-PHENYL-1,3-BUTADIENYLIDENE
BECKER, J, WENTRUP, C, KATZ, E and ZELLER, KP (1980). AZULENE-NAPHTHALENE REARRANGEMENT - INVOLVEMENT OF 1-PHENYLBUTEN-3-YNES AND 4-PHENYL-1,3-BUTADIENYLIDENE. Journal of the American Chemical Society, 102 (15), 5110-5112. doi: 10.1021/ja00535a056
1980
Journal Article
N-Ethynylamines of the Type R-Nh-C=C-H
Winter, HW and Wentrup, C (1980). N-Ethynylamines of the Type R-Nh-C=C-H. Angewandte Chemie-International Edition in English, 19 (9), 720-721. doi: 10.1002/anie.198007201
1980
Journal Article
ACYLATED KETENIMINES AND ALLENES FROM OXAZOL-5(4H)-ONES AND FURAN-2(3H)-ONES
BERSTERMANN, HM, HARDER, R, WINTER, HW and WENTRUP, C (1980). ACYLATED KETENIMINES AND ALLENES FROM OXAZOL-5(4H)-ONES AND FURAN-2(3H)-ONES. Angewandte Chemie-International Edition in English, 19 (7), 564-566. doi: 10.1002/anie.198005641
1980
Journal Article
C118H INTERMEDIATES .4. 2-VINYLIDENE-2H-INDENE
SCHULZ, R, SCHWEIG, A, WENTRUP, C and WINTER, HW (1980). C118H INTERMEDIATES .4. 2-VINYLIDENE-2H-INDENE. Angewandte Chemie-International Edition in English, 19 (10), 821-822. doi: 10.1002/anie.198008211
1979
Journal Article
FULMINATES .1. NEW SYNTHESIS OF FULMINIC ACID
WENTRUP, C, GERECHT, B and BRIEHL, H (1979). FULMINATES .1. NEW SYNTHESIS OF FULMINIC ACID. Angewandte Chemie-International Edition in English, 18 (6), 467-468. doi: 10.1002/anie.197904671
1979
Journal Article
2-ETHYNYLINDENE BY REARRANGEMENT OF 2-VINYLIDENE-2H-INDENE AND 2-INDENYLVINYLIDENE
WENTRUP, C, WENTRUPBYRNE, E, MULLER, P and BECKER, J (1979). 2-ETHYNYLINDENE BY REARRANGEMENT OF 2-VINYLIDENE-2H-INDENE AND 2-INDENYLVINYLIDENE. Tetrahedron Letters (44), 4249-4252.
Funding
Supervision
Availability
- Emeritus Professor Curt Wentrup is:
- Not available for supervision
Supervision history
Completed supervision
-
2006
Doctor Philosophy
SYNTHESES AND REACTIONS OF IMINOPROPADIENONES, SYDNONES AND OXAZINONES
Principal Advisor
Other advisors: Professor Craig Williams
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2002
Doctor Philosophy
HETEROCYCLIC SYNTHESIS BASED ON IMINOPROPADIENONES
Principal Advisor
-
2002
Doctor Philosophy
SYNTHESIS AND CHARACTERISATION OF 1,3- and 1,4- DIAZEPINES AND DERIVATIVES
Principal Advisor
-
Doctor Philosophy
NITRENES REARRANGEMENTS: FORMATION OF REACTIVE INTERMEDIATES AND UNUSUAL MOLECULES
Principal Advisor
Other advisors: Professor Craig Williams
Media
Enquiries
Contact Emeritus Professor Curt Wentrup directly for media enquiries about:
- Organic reaction mechanisms
- Photochemistry
- Pyrolysis
- Reactive intermediates
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